The molecular formula C 21 H 44 is straight-chain as an alkane, an alkene or alkynes have to be classified. Concept Introduction: The formulas of alkanes are C n H 2n+2 , for n = 1 and higher. Each multiple bond removes two electrons. The formulas of alkenes are C n H 2n , for n = 2 and higher. The formulas Covalent Bonding of alkynes are C n H 2n-2 , for n = 2 and higher.
The molecular formula C 21 H 44 is straight-chain as an alkane, an alkene or alkynes have to be classified. Concept Introduction: The formulas of alkanes are C n H 2n+2 , for n = 1 and higher. Each multiple bond removes two electrons. The formulas of alkenes are C n H 2n , for n = 2 and higher. The formulas Covalent Bonding of alkynes are C n H 2n-2 , for n = 2 and higher.
Solution Summary: The author explains the formulas of alkanes and alkynes.
Definition Definition Simplest organic compounds that contain only single bonds between carbon – carbon atoms and carbon – hydrogen bonds. This means they are a series of saturated compounds with a general molecular formula, C n H 2n+2 .
Chapter 6, Problem 26QRT
(a)
Interpretation Introduction
Interpretation:
The molecular formula C21H44 is straight-chain as an alkane, an alkene or alkynes have to be classified.
Concept Introduction:
The formulas of alkanes are CnH2n+2, for n = 1 and higher. Each multiple bond removes two electrons.
The formulas of alkenes are CnH2n, for n = 2 and higher.
The formulas Covalent Bonding of alkynes are CnH2n-2, for n = 2 and higher.
(b)
Interpretation Introduction
Interpretation:
The molecular formula C4H6 is straight-chain as an alkane, an alkene or alkynes have to be classified.
Concept Introduction:
Refer to part (a).
(c)
Interpretation Introduction
Interpretation:
The molecular formula C8H16 is straight-chain as an alkane, an alkene or alkynes have to be classified.
Protecting Groups and Carbonyls
6) The synthesis generates allethrolone that exhibits high insect toxicity but low mammalian toxicity. They are used in pet
shampoo, human lice shampoo, and industrial sprays for insects and mosquitos. Propose detailed mechanistic steps to
generate the allethrolone label the different types of reagents (Grignard, acid/base protonation, acid/base deprotonation,
reduction, oxidation, witting, aldol condensation, Robinson annulation, etc.)
III + VI
HS
HS
H+
CH,CH,Li
III
I
II
IV
CI + P(Ph)3
V
༼
Hint: no strong base added
VI
S
VII
IX
HO
VIII
-MgBr
HgCl2,HgO
HO.
isomerization
aqeuous solution
H,SO,
༽༽༤༽༽
X
MeOH
Hint: enhances selectivity for reaction at the S
X
☑
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