Principles of Chemistry: A Molecular Approach (3rd Edition)
3rd Edition
ISBN: 9780321971944
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 6, Problem 86E
Interpretation Introduction
Interpretation:
The heat flow in the given process of expansion and contraction of the gas is to be calculated.
Concept Introduction: The enthalpy change of the given reaction is calculated by the formula,
To determine: The heat flow in the given process.
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Write structural formulas for the major products by
doing addition reactions
1. You must add H2 as Pt is catalyst it does not take part in reactions
only speed up the process
H₂
CH2=CH-CH3
Pt
2. Add HCI break it into H and Cl
CH3
HCI
3. Add Br2 only CC14 is catalyst
CH3-CH=CH2
B12
CCl4
4. Add water to this and draw major product, H2SO4 is catalyst you have add
water H20 in both the reaction below
H₂SO4
CH3-CH=CH2
CH3
H2SO4/H₂O
CH3-C=CH2
reflux
?
Plan the synthesis of the following compound using the starting
material provided and any other reagents needed as long as
carbon based reagents have 3 carbons or less. Either the
retrosynthesis or the forward synthesis (mechanisms are not
required but will be graded if provided) will be accepted if all
necessary reagents and intermediates are shown (solvents and
temperature requirements are not needed unless specifically
involved in the reaction, i.e. DMSO in the Swern oxidation or
heat in the KMnO4 oxidation).
H
H
Hint These are benzene substitution reactions.
ALCI3 and UV light are catalyst no part in reactions and triangle A means
heating.
A. Add ethyl for Et in benzene ring alkylation reaction EtCl =
CH3CH2CL
1) EtC1 / AlCl3 / A
?
B: Add Br to benzene ring ( substitution)
2) Br₂ / uv light
?
C Add (CH3)2 CHCH2 in benzene ring ( substitution)
(CH3)2CHCH,C1 / AICI,
?
Chapter 6 Solutions
Principles of Chemistry: A Molecular Approach (3rd Edition)
Ch. 6 - Prob. 6.1PCh. 6 - Prob. 6.2PCh. 6 - Prob. 6.2MPCh. 6 - Prob. 6.3PCh. 6 - Prob. 6.4PCh. 6 - Prob. 6.4MPCh. 6 - Prob. 6.5PCh. 6 - Prob. 6.5MPCh. 6 - Prob. 6.6PCh. 6 - Ammonia reacts with oxygen according to the...
Ch. 6 - Prob. 6.7MPCh. 6 - Prob. 6.8PCh. 6 - Prob. 6.9PCh. 6 - Prob. 6.9MPCh. 6 - Prob. 6.10PCh. 6 - Prob. 6.11PCh. 6 - Prob. 6.12PCh. 6 - Prob. 1SAQCh. 6 - Prob. 2SAQCh. 6 - Prob. 3SAQCh. 6 - Prob. 4SAQCh. 6 - Prob. 5SAQCh. 6 - Prob. 6SAQCh. 6 - Prob. 7SAQCh. 6 - Prob. 8SAQCh. 6 - Prob. 9SAQCh. 6 - Prob. 10SAQCh. 6 - Prob. 11SAQCh. 6 - Prob. 12SAQCh. 6 - Prob. 13SAQCh. 6 - Prob. 14SAQCh. 6 - Prob. 1ECh. 6 - Prob. 2ECh. 6 - Prob. 3ECh. 6 - Prob. 4ECh. 6 - Prob. 5ECh. 6 - Prob. 6ECh. 6 - Prob. 7ECh. 6 - Prob. 8ECh. 6 - Prob. 9ECh. 6 - Prob. 10ECh. 6 - Prob. 11ECh. 6 - Prob. 12ECh. 6 - Prob. 13ECh. 6 - Prob. 14ECh. 6 - Prob. 15ECh. 6 - Prob. 16ECh. 6 - Prob. 17ECh. 6 - Prob. 18ECh. 6 - Prob. 19ECh. 6 - Prob. 20ECh. 6 - Prob. 21ECh. 6 - Prob. 22ECh. 6 - Prob. 23ECh. 6 - 24. The change in internal energy for the...Ch. 6 - Prob. 25ECh. 6 - Prob. 26ECh. 6 - Prob. 27ECh. 6 - Prob. 28ECh. 6 - Prob. 29ECh. 6 - Prob. 30ECh. 6 - Prob. 31ECh. 6 - Prob. 32ECh. 6 - Prob. 33ECh. 6 - Prob. 34ECh. 6 - Prob. 35ECh. 6 - Prob. 36ECh. 6 - Prob. 37ECh. 6 - Prob. 38ECh. 6 - Prob. 39ECh. 6 - Prob. 40ECh. 6 - Prob. 41ECh. 6 - Prob. 42ECh. 6 - Prob. 43ECh. 6 - Prob. 44ECh. 6 - Prob. 45ECh. 6 - Prob. 46ECh. 6 - Prob. 47ECh. 6 - Prob. 48ECh. 6 - Prob. 49ECh. 6 - Prob. 50ECh. 6 - Prob. 51ECh. 6 - Write an equation for the formation of each...Ch. 6 - Prob. 53ECh. 6 - Prob. 54ECh. 6 - Use standard enthalpies of formation to calculate...Ch. 6 - Use standard enthalpies of formation to calculate...Ch. 6 - Prob. 57ECh. 6 - Prob. 58ECh. 6 - Prob. 59ECh. 6 - Prob. 60ECh. 6 - Prob. 61ECh. 6 - Prob. 62ECh. 6 - Prob. 63ECh. 6 - Prob. 64ECh. 6 - Use standard enthalpies of formation to calculate...Ch. 6 - Prob. 66ECh. 6 - Prob. 67ECh. 6 - Prob. 68ECh. 6 - Prob. 69ECh. 6 - Hydrogen and methanol have both been proposed as...Ch. 6 - Prob. 71ECh. 6 - Under certain nonstandard conditions, oxidatin by...Ch. 6 - Prob. 73ECh. 6 - Prob. 74ECh. 6 - Prob. 75ECh. 6 - Prob. 76ECh. 6 - Prob. 77ECh. 6 - Prob. 78ECh. 6 - 79. A typical frostless refrigerator uses 655 kWh...Ch. 6 - Prob. 80ECh. 6 - Prob. 81ECh. 6 - Prob. 82ECh. 6 - Prob. 83ECh. 6 - Prob. 84ECh. 6 - Prob. 85ECh. 6 - Prob. 86ECh. 6 - The heat of vaporization of water at 373 K is 40.7...Ch. 6 - Prob. 88ECh. 6 - Which statement is true of the internal energy of...Ch. 6 - Prob. 90ECh. 6 - Prob. 91ECh. 6 - Prob. 92ECh. 6 - Prob. 93ECh. 6 - Prob. 94ECh. 6 - Prob. 95ECh. 6 - Prob. 96ECh. 6 - Which statements if true of a reaction in which V...
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