Principles of Chemistry: A Molecular Approach (3rd Edition)
3rd Edition
ISBN: 9780321971944
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 6, Problem 19E
Interpretation Introduction
Interpretation:
The work done in the given expansion of the gas is to be calculated.
Concept Introduction: The work done of the system is calculated by the formula,
To determine: The work done for the given expansion of gas in joules units.
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Relative Intensity
Part VI. consider the multi-step reaction below for compounds
A, B, and C.
These compounds were subjected to mass spectrometric analysis and
the following spectra for A, B, and C was obtained.
Draw the structure of B and C and match all three compounds
to the correct spectra.
Relative Intensity
Relative Intensity
100
HS-NJ-0547
80
60
31
20
S1
84
M+
absent
10
30
40
50
60
70
80
90
100
100-
MS2016-05353CM
80-
60
40
20
135 137
S2
164 166
0-m
25
50
75
100
125
150
m/z
60
100
MS-NJ-09-43
40
20
20
80
45
S3
25
50
75
100
125
150
175
m/z
Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass
spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained.
Draw the structures of these fragments.
Chapter 6 Solutions
Principles of Chemistry: A Molecular Approach (3rd Edition)
Ch. 6 - Prob. 6.1PCh. 6 - Prob. 6.2PCh. 6 - Prob. 6.2MPCh. 6 - Prob. 6.3PCh. 6 - Prob. 6.4PCh. 6 - Prob. 6.4MPCh. 6 - Prob. 6.5PCh. 6 - Prob. 6.5MPCh. 6 - Prob. 6.6PCh. 6 - Ammonia reacts with oxygen according to the...
Ch. 6 - Prob. 6.7MPCh. 6 - Prob. 6.8PCh. 6 - Prob. 6.9PCh. 6 - Prob. 6.9MPCh. 6 - Prob. 6.10PCh. 6 - Prob. 6.11PCh. 6 - Prob. 6.12PCh. 6 - Prob. 1SAQCh. 6 - Prob. 2SAQCh. 6 - Prob. 3SAQCh. 6 - Prob. 4SAQCh. 6 - Prob. 5SAQCh. 6 - Prob. 6SAQCh. 6 - Prob. 7SAQCh. 6 - Prob. 8SAQCh. 6 - Prob. 9SAQCh. 6 - Prob. 10SAQCh. 6 - Prob. 11SAQCh. 6 - Prob. 12SAQCh. 6 - Prob. 13SAQCh. 6 - Prob. 14SAQCh. 6 - Prob. 1ECh. 6 - Prob. 2ECh. 6 - Prob. 3ECh. 6 - Prob. 4ECh. 6 - Prob. 5ECh. 6 - Prob. 6ECh. 6 - Prob. 7ECh. 6 - Prob. 8ECh. 6 - Prob. 9ECh. 6 - Prob. 10ECh. 6 - Prob. 11ECh. 6 - Prob. 12ECh. 6 - Prob. 13ECh. 6 - Prob. 14ECh. 6 - Prob. 15ECh. 6 - Prob. 16ECh. 6 - Prob. 17ECh. 6 - Prob. 18ECh. 6 - Prob. 19ECh. 6 - Prob. 20ECh. 6 - Prob. 21ECh. 6 - Prob. 22ECh. 6 - Prob. 23ECh. 6 - 24. The change in internal energy for the...Ch. 6 - Prob. 25ECh. 6 - Prob. 26ECh. 6 - Prob. 27ECh. 6 - Prob. 28ECh. 6 - Prob. 29ECh. 6 - Prob. 30ECh. 6 - Prob. 31ECh. 6 - Prob. 32ECh. 6 - Prob. 33ECh. 6 - Prob. 34ECh. 6 - Prob. 35ECh. 6 - Prob. 36ECh. 6 - Prob. 37ECh. 6 - Prob. 38ECh. 6 - Prob. 39ECh. 6 - Prob. 40ECh. 6 - Prob. 41ECh. 6 - Prob. 42ECh. 6 - Prob. 43ECh. 6 - Prob. 44ECh. 6 - Prob. 45ECh. 6 - Prob. 46ECh. 6 - Prob. 47ECh. 6 - Prob. 48ECh. 6 - Prob. 49ECh. 6 - Prob. 50ECh. 6 - Prob. 51ECh. 6 - Write an equation for the formation of each...Ch. 6 - Prob. 53ECh. 6 - Prob. 54ECh. 6 - Use standard enthalpies of formation to calculate...Ch. 6 - Use standard enthalpies of formation to calculate...Ch. 6 - Prob. 57ECh. 6 - Prob. 58ECh. 6 - Prob. 59ECh. 6 - Prob. 60ECh. 6 - Prob. 61ECh. 6 - Prob. 62ECh. 6 - Prob. 63ECh. 6 - Prob. 64ECh. 6 - Use standard enthalpies of formation to calculate...Ch. 6 - Prob. 66ECh. 6 - Prob. 67ECh. 6 - Prob. 68ECh. 6 - Prob. 69ECh. 6 - Hydrogen and methanol have both been proposed as...Ch. 6 - Prob. 71ECh. 6 - Under certain nonstandard conditions, oxidatin by...Ch. 6 - Prob. 73ECh. 6 - Prob. 74ECh. 6 - Prob. 75ECh. 6 - Prob. 76ECh. 6 - Prob. 77ECh. 6 - Prob. 78ECh. 6 - 79. A typical frostless refrigerator uses 655 kWh...Ch. 6 - Prob. 80ECh. 6 - Prob. 81ECh. 6 - Prob. 82ECh. 6 - Prob. 83ECh. 6 - Prob. 84ECh. 6 - Prob. 85ECh. 6 - Prob. 86ECh. 6 - The heat of vaporization of water at 373 K is 40.7...Ch. 6 - Prob. 88ECh. 6 - Which statement is true of the internal energy of...Ch. 6 - Prob. 90ECh. 6 - Prob. 91ECh. 6 - Prob. 92ECh. 6 - Prob. 93ECh. 6 - Prob. 94ECh. 6 - Prob. 95ECh. 6 - Prob. 96ECh. 6 - Which statements if true of a reaction in which V...
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