PHYSICAL CHEMISTRY-WEBASSIGN
PHYSICAL CHEMISTRY-WEBASSIGN
11th Edition
ISBN: 9780357087411
Author: ATKINS
Publisher: CENGAGE L
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Chapter 6, Problem 6A.12AE
Interpretation Introduction

Interpretation: The Gibbs free energy of the given reaction has to be calculated.

Concept introduction: The Gibbs free energy of the reaction is the key factor of the identification of the direction of spontaneity of the reaction.  For the reaction to be spontaneous the Gibbs free energy of the reaction must be negative.

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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following: (a) match structures of isomers given their mass spectra below (spectra A and spectra B) (b) Draw the fragments given the following prominent peaks from each spectrum: Spectra A m/2 =43 and 1/2-57 spectra B m/2 = 43 (c) why is 1/2=57 peak in spectrum A more intense compared to the same peak in spectrum B. Relative abundance Relative abundance 100 A 50 29 29 0 10 -0 -0 100 B 50 720 30 41 43 57 71 4-0 40 50 60 70 m/z 43 57 8-0 m/z = 86 M 90 100 71 m/z = 86 M -O 0 10 20 30 40 50 60 70 80 -88 m/z 90 100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained. Draw the structures of these fragments.
For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table  and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.

Chapter 6 Solutions

PHYSICAL CHEMISTRY-WEBASSIGN

Ch. 6 - Prob. 6A.2BECh. 6 - Prob. 6A.3AECh. 6 - Prob. 6A.3BECh. 6 - Prob. 6A.4AECh. 6 - Prob. 6A.4BECh. 6 - Prob. 6A.5AECh. 6 - Prob. 6A.5BECh. 6 - Prob. 6A.6AECh. 6 - Prob. 6A.6BECh. 6 - Prob. 6A.7AECh. 6 - Prob. 6A.7BECh. 6 - Prob. 6A.8AECh. 6 - Prob. 6A.8BECh. 6 - Prob. 6A.9AECh. 6 - Prob. 6A.9BECh. 6 - Prob. 6A.10AECh. 6 - Prob. 6A.10BECh. 6 - Prob. 6A.11AECh. 6 - Prob. 6A.11BECh. 6 - Prob. 6A.12AECh. 6 - Prob. 6A.12BECh. 6 - Prob. 6A.13AECh. 6 - Prob. 6A.13BECh. 6 - Prob. 6A.14AECh. 6 - Prob. 6A.14BECh. 6 - Prob. 6A.1PCh. 6 - Prob. 6A.2PCh. 6 - Prob. 6A.3PCh. 6 - Prob. 6A.4PCh. 6 - Prob. 6A.5PCh. 6 - Prob. 6A.6PCh. 6 - Prob. 6B.1DQCh. 6 - Prob. 6B.2DQCh. 6 - Prob. 6B.3DQCh. 6 - Prob. 6B.1AECh. 6 - Prob. 6B.1BECh. 6 - Prob. 6B.2AECh. 6 - Prob. 6B.2BECh. 6 - Prob. 6B.3AECh. 6 - Prob. 6B.3BECh. 6 - Prob. 6B.4AECh. 6 - Prob. 6B.4BECh. 6 - Prob. 6B.5AECh. 6 - Prob. 6B.5BECh. 6 - Prob. 6B.6AECh. 6 - Prob. 6B.6BECh. 6 - Prob. 6B.7AECh. 6 - Prob. 6B.7BECh. 6 - Prob. 6B.8AECh. 6 - Prob. 6B.8BECh. 6 - Prob. 6B.1PCh. 6 - Prob. 6B.2PCh. 6 - Prob. 6B.3PCh. 6 - Prob. 6B.4PCh. 6 - Prob. 6B.5PCh. 6 - Prob. 6B.6PCh. 6 - Prob. 6B.7PCh. 6 - Prob. 6B.8PCh. 6 - Prob. 6B.9PCh. 6 - Prob. 6B.10PCh. 6 - Prob. 6B.11PCh. 6 - Prob. 6B.12PCh. 6 - Prob. 6C.1DQCh. 6 - Prob. 6C.2DQCh. 6 - Prob. 6C.3DQCh. 6 - Prob. 6C.4DQCh. 6 - Prob. 6C.5DQCh. 6 - Prob. 6C.1AECh. 6 - Prob. 6C.1BECh. 6 - Prob. 6C.2AECh. 6 - Prob. 6C.2BECh. 6 - Prob. 6C.3AECh. 6 - Prob. 6C.3BECh. 6 - Prob. 6C.4AECh. 6 - Prob. 6C.4BECh. 6 - Prob. 6C.5AECh. 6 - Prob. 6C.5BECh. 6 - Prob. 6C.1PCh. 6 - Prob. 6C.2PCh. 6 - Prob. 6C.3PCh. 6 - Prob. 6C.4PCh. 6 - Prob. 6D.1DQCh. 6 - Prob. 6D.2DQCh. 6 - Prob. 6D.1AECh. 6 - Prob. 6D.1BECh. 6 - Prob. 6D.2AECh. 6 - Prob. 6D.2BECh. 6 - Prob. 6D.3AECh. 6 - Prob. 6D.3BECh. 6 - Prob. 6D.4AECh. 6 - Prob. 6D.4BECh. 6 - Prob. 6D.1PCh. 6 - Prob. 6D.2PCh. 6 - Prob. 6D.3PCh. 6 - Prob. 6D.4PCh. 6 - Prob. 6D.5PCh. 6 - Prob. 6D.6PCh. 6 - Prob. 6.1IACh. 6 - Prob. 6.2IACh. 6 - Prob. 6.3IACh. 6 - Prob. 6.4IACh. 6 - Prob. 6.7IACh. 6 - Prob. 6.8IACh. 6 - Prob. 6.10IACh. 6 - Prob. 6.12IA
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