EBK PHYSICAL CHEMISTRY
3rd Edition
ISBN: 9780133556094
Author: Reid
Publisher: YUZU
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Chapter 6, Problem 6.9CP
Interpretation Introduction
Interpretation: The validation of
Concept Introduction: A reversible
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I
Draw the anti-Markovnikov product of the hydration of this alkene.
this problem.
Note for advanced students: draw only one product, and don't worry about showing any stereochemistry. Drawing dash and wedge bonds has been disabled for
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Explanation
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3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
PH
P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
-1
1
2
3
2
H,PO,
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
Chapter 6 Solutions
EBK PHYSICAL CHEMISTRY
Ch. 6 - Prob. 6.1CPCh. 6 - Prob. 6.2CPCh. 6 - Prob. 6.3CPCh. 6 - Prob. 6.4CPCh. 6 - Prob. 6.5CPCh. 6 - Prob. 6.6CPCh. 6 - Prob. 6.7CPCh. 6 - Prob. 6.8CPCh. 6 - Prob. 6.9CPCh. 6 - Prob. 6.10CP
Ch. 6 - Prob. 6.11CPCh. 6 - Prob. 6.12CPCh. 6 - Prob. 6.13CPCh. 6 - Prob. 6.14CPCh. 6 - Prob. 6.15CPCh. 6 - Prob. 6.16CPCh. 6 - Prob. 6.17CPCh. 6 - Prob. 6.18CPCh. 6 - Prob. 6.19CPCh. 6 - Prob. 6.20CPCh. 6 - Prob. 6.21CPCh. 6 - Prob. 6.22CPCh. 6 - Prob. 6.23CPCh. 6 - Prob. 6.24CPCh. 6 - Prob. 6.25CPCh. 6 - Prob. 6.26CPCh. 6 - Prob. 6.27CPCh. 6 - Prob. 6.28CPCh. 6 - Prob. 6.29CPCh. 6 - Prob. 6.30CPCh. 6 - Prob. 6.31CPCh. 6 - Prob. 6.1NPCh. 6 - Prob. 6.2NPCh. 6 - Prob. 6.3NPCh. 6 - Prob. 6.4NPCh. 6 - Prob. 6.5NPCh. 6 - Prob. 6.6NPCh. 6 - Prob. 6.7NPCh. 6 - Prob. 6.8NPCh. 6 - Prob. 6.9NPCh. 6 - Prob. 6.10NPCh. 6 - Prob. 6.11NPCh. 6 - Prob. 6.12NPCh. 6 - Prob. 6.13NPCh. 6 - Prob. 6.14NPCh. 6 - Prob. 6.15NPCh. 6 - Prob. 6.16NPCh. 6 - Prob. 6.17NPCh. 6 - Prob. 6.18NPCh. 6 - Prob. 6.19NPCh. 6 - Prob. 6.20NPCh. 6 - Prob. 6.21NPCh. 6 - Prob. 6.22NPCh. 6 - Prob. 6.23NPCh. 6 - Prob. 6.24NPCh. 6 - Prob. 6.25NPCh. 6 - Prob. 6.26NPCh. 6 - Prob. 6.27NPCh. 6 - Prob. 6.28NPCh. 6 - Prob. 6.29NPCh. 6 - Prob. 6.30NPCh. 6 - Prob. 6.31NPCh. 6 - Prob. 6.32NPCh. 6 - Prob. 6.33NPCh. 6 - Prob. 6.34NPCh. 6 - Prob. 6.35NPCh. 6 - Prob. 6.36NPCh. 6 - Prob. 6.37NPCh. 6 - Prob. 6.38NPCh. 6 - Prob. 6.39NPCh. 6 - Prob. 6.40NPCh. 6 - Prob. 6.41NPCh. 6 - Prob. 6.42NPCh. 6 - Prob. 6.43NP
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