WebAssign for Zumdahl's Chemical Principles, 8th Edition [Instant Access], Single-Term
8th Edition
ISBN: 9780357119112
Author: Zumdahl; Steven S.
Publisher: Cengage Learning US
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Question
Chapter 6, Problem 67E
Interpretation Introduction
Interpretation:Whether smell of ammonia will increase or decrease as temperature of endothermic reaction is increased in below reaction is to be determined.
Concept introduction: In accordance to Le Chatelier’s principle change in reaction condition brings changes in position of equilibrium and shifts equilibrium in that direction that tends to decrease the change. It states that for an endothermic reaction increase in temperature tends to shift equilibrium in forward direction and for exothermic reaction it shifts in backward direction.
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Understanding how substituents activate
Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic
aromatic substitution.
Explanation
HN
NH2
Check
X
(Choose one)
(Choose one)
(Choose one)
(Choose one)
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Identifying electron-donating and electron-withdrawing effects on benzene
For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the
benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene.
Inductive Effects
Resonance Effects
Overall Electron-Density
Molecule
CF3
O donating
O donating
O withdrawing
O withdrawing
O no inductive effects
O no resonance effects
electron-rich
electron-deficient
O similar to benzene
CH3
O donating
O withdrawing
O no inductive effects
O donating
O withdrawing
Ono resonance effects
O electron-rich
O electron-deficient
O similar to benzene
Explanation
Check
Х
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* Hint: Think back to Chem 1 solubility rules.
Follow Up Questions for Part B
12. What impact do the following disturbances to a system at equilibrium have on k, the rate constant
for the forward reaction? Explain. (4 pts)
a) Changing the concentration of a reactant or product. (2 pts)
b) Changing the temperature of an exothermic reaction. (2 pts)
of
Chapter 6 Solutions
WebAssign for Zumdahl's Chemical Principles, 8th Edition [Instant Access], Single-Term
Ch. 6 - Prob. 1DQCh. 6 - The boxes shown below represent a set of initial...Ch. 6 - For the reaction H2(g)+I2(g)2HI(g) , considertwo...Ch. 6 - Given the reaction A(g)+B(g)C(g)+D(g) ,...Ch. 6 - Consider the reaction A(g)+2B(g)C(g)+D(g) ina...Ch. 6 - Consider the reaction A(g)+B(g)C(g)+D(g) . Afriend...Ch. 6 - Consider the following statements: “Consider the...Ch. 6 - Le Châtelier’s principle is stated (Section 6.8)...Ch. 6 - The value of the equilibrium constant K depends on...Ch. 6 - Prob. 10E
Ch. 6 - Consider the following reactions at some...Ch. 6 - Prob. 12ECh. 6 - Consider the same reaction as in Exercise 12. In a...Ch. 6 - Consider the following reaction at some...Ch. 6 - Prob. 15ECh. 6 - Prob. 16ECh. 6 - Prob. 17ECh. 6 - Prob. 18ECh. 6 - Explain the difference between K, Kp , and Q.Ch. 6 - Prob. 20ECh. 6 - Prob. 21ECh. 6 - For which reactions in Exercise 21 is Kp equal to...Ch. 6 - Prob. 23ECh. 6 - Prob. 24ECh. 6 - At 327°C, the equilibrium concentrations are...Ch. 6 - Prob. 26ECh. 6 - At a particular temperature, a 2.00-L flask at...Ch. 6 - Prob. 28ECh. 6 - Prob. 29ECh. 6 - Prob. 30ECh. 6 - Prob. 31ECh. 6 - Nitrogen gas (N2) reacts with hydrogen gas (H2) to...Ch. 6 - A sample of gaseous PCl5 was introduced into an...Ch. 6 - Prob. 34ECh. 6 - Prob. 35ECh. 6 - At a particular temperature, 8.0 moles of NO2 is...Ch. 6 - Prob. 37ECh. 6 - Prob. 38ECh. 6 - Prob. 39ECh. 6 - Prob. 40ECh. 6 - At a particular temperature, K=1.00102 for...Ch. 6 - Prob. 42ECh. 6 - Prob. 43ECh. 6 - For the reaction below at a certain temperature,...Ch. 6 - At 1100 K, Kp=0.25 for the following reaction:...Ch. 6 - At 2200°C, K=0.050 for the reaction...Ch. 6 - Prob. 47ECh. 6 - Prob. 48ECh. 6 - Prob. 49ECh. 6 - Prob. 50ECh. 6 - Prob. 51ECh. 6 - Prob. 52ECh. 6 - Prob. 53ECh. 6 - Prob. 54ECh. 6 - Which of the following statements is(are) true?...Ch. 6 - Prob. 56ECh. 6 - Prob. 57ECh. 6 - Prob. 58ECh. 6 - Chromium(VI) forms two different oxyanions, the...Ch. 6 - Solid NH4HS decomposes by the following...Ch. 6 - An important reaction in the commercial production...Ch. 6 - Prob. 62ECh. 6 - Prob. 63ECh. 6 - Prob. 64ECh. 6 - Prob. 65ECh. 6 - Prob. 66ECh. 6 - Prob. 67ECh. 6 - Prob. 68ECh. 6 - Prob. 69AECh. 6 - Prob. 70AECh. 6 - Prob. 71AECh. 6 - Prob. 72AECh. 6 - Prob. 73AECh. 6 - Prob. 74AECh. 6 - An initial mixture of nitrogen gas and hydrogen...Ch. 6 - Prob. 76AECh. 6 - Prob. 77AECh. 6 - Prob. 78AECh. 6 - Prob. 79AECh. 6 - Prob. 80AECh. 6 - Prob. 81AECh. 6 - For the reaction PCl5(g)PCl3(g)+Cl2(g) at 600. K,...Ch. 6 - Prob. 83AECh. 6 - The gas arsine (AsH3) decomposes as follows:...Ch. 6 - Prob. 85AECh. 6 - Prob. 86AECh. 6 - Consider the decomposition of the compound C5H6O3...Ch. 6 - Prob. 88AECh. 6 - Prob. 89AECh. 6 - Prob. 90AECh. 6 - Prob. 91AECh. 6 - Prob. 92AECh. 6 - Prob. 93AECh. 6 - Prob. 94AECh. 6 - Prob. 95AECh. 6 - Prob. 96CPCh. 6 - Nitric oxide and bromine at initial partial...Ch. 6 - Prob. 98CPCh. 6 - Prob. 99CPCh. 6 - Consider the reaction 3O2(g)2O3(g) At 175°C and a...Ch. 6 - A mixture of N2,H2andNH3 is at equilibrium...Ch. 6 - Prob. 103CPCh. 6 - Prob. 104CPCh. 6 - Prob. 105CPCh. 6 - A 1.604-g sample of methane (CH4) gas and 6.400 g...Ch. 6 - At 1000 K the N2(g)andO2(g) in air (78% N2, 21% O2...Ch. 6 - Prob. 108CPCh. 6 - Prob. 109CPCh. 6 - Prob. 110CPCh. 6 - Prob. 111CPCh. 6 - A sample of gaseous nitrosyl bromide (NOBr)...Ch. 6 - A gaseous material XY(g) dissociates to some...
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