CHEMISTRY:ATOMS FIRST (LL)>CUSTOM PKG.<
2nd Edition
ISBN: 9781259382307
Author: Burdge
Publisher: MCGRAW-HILL HIGHER EDUCATION
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Textbook Question
Chapter 6, Problem 6.65QP
Are the following statements true or false? (a) Formal charges represent an actual separation charges, (b) All second period elements obey the octet rule in their compounds, (c) The resonance structures of a molecule can be separated from one another in the laboratory.
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3.
a.
Use the MS to propose at least two possible molecular formulas.
For an unknown compound:
101.
27.0
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41.0
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52.0
55.0
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100
57.5
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58.5
62.0
63.0
64.0
65.0
74.0
40
75.0
76.0
20
20
40
60
80
100
120
140
160
180
200 220
m/z
99.5
68564810898409581251883040
115.0
116.0
77404799
17417M
117.0
12.9
118.0
33.5
119.0
36
133 0
1.2
157.0
2.1
159.0
16
169.0
219
170.0
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171.0
21.6
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181.0
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784
Relative Intensity
2
2
8
ō (ppm)
6
2
Solve the structure and assign each of the following spectra (IR and C-NMR)
1.
For an unknown compound with a molecular formula of C8H100:
a.
What is the DU? (show your work)
b.
Solve the structure and assign each of the following spectra.
8
6
2
ō (ppm)
4
2
0
200
150
100
50
ō (ppm)
LOD
D
4000
3000
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500
HAVENUMBERI -11
Chapter 6 Solutions
CHEMISTRY:ATOMS FIRST (LL)>CUSTOM PKG.<
Ch. 6.2 - Classify the following bonds as nonpolar, polar,...Ch. 6.2 - Classify the following bonds as nonpolar, polar,...Ch. 6.2 - Prob. 1PPBCh. 6.2 - Electrostatic potential maps are shown for HCl and...Ch. 6.2 - Prob. 6.2WECh. 6.2 - Prob. 2PPACh. 6.2 - Prob. 2PPBCh. 6.2 - Prob. 2PPCCh. 6.2 - Prob. 6.3WECh. 6.2 - Prob. 3PPA
Ch. 6.2 - Prob. 3PPBCh. 6.2 - Prob. 3PPCCh. 6.2 - Prob. 6.2.1SRCh. 6.2 - Prob. 6.2.2SRCh. 6.2 - Prob. 6.2.3SRCh. 6.2 - Prob. 6.2.4SRCh. 6.3 - Draw the Lewis structure for carbon disulfide...Ch. 6.3 - Prob. 4PPACh. 6.3 - Prob. 4PPBCh. 6.3 - Prob. 4PPCCh. 6.3 - Prob. 6.3.1SRCh. 6.3 - Prob. 6.3.2SRCh. 6.4 - The widespread use of fertilizers has resulted in...Ch. 6.4 - Prob. 5PPACh. 6.4 - Prob. 5PPBCh. 6.4 - Prob. 5PPCCh. 6.4 - Formaldehyde (CH2O), which can be used 10 preserve...Ch. 6.4 - Prob. 6PPACh. 6.4 - Prob. 6PPBCh. 6.4 - Prob. 6PPCCh. 6.4 - Prob. 6.4.1SRCh. 6.4 - Prob. 6.4.2SRCh. 6.5 - Prob. 6.7WECh. 6.5 - Prob. 7PPACh. 6.5 - Prob. 7PPBCh. 6.5 - Prob. 7PPCCh. 6.5 - Prob. 6.5.1SRCh. 6.5 - Prob. 6.5.2SRCh. 6.6 - Prob. 6.8WECh. 6.6 - Prob. 8PPACh. 6.6 - Prob. 8PPBCh. 6.6 - Prob. 8PPCCh. 6.6 - Prob. 6.9WECh. 6.6 - Prob. 9PPACh. 6.6 - Prob. 9PPBCh. 6.6 - Elements in the same group exhibit similar...Ch. 6.6 - Prob. 6.10WECh. 6.6 - Draw three resonance structures for the hydrogen...Ch. 6.6 - Draw two resonance structures for each speciesone...Ch. 6.6 - Prob. 10PPCCh. 6.6 - Prob. 6.6.1SRCh. 6.6 - Prob. 6.6.2SRCh. 6.6 - Prob. 6.6.3SRCh. 6.6 - Prob. 6.6.4SRCh. 6 - Prob. 6.1QPCh. 6 - Prob. 6.2QPCh. 6 - Prob. 6.3QPCh. 6 - Prob. 6.4QPCh. 6 - Prob. 6.5QPCh. 6 - Prob. 6.6QPCh. 6 - Prob. 6.7QPCh. 6 - Prob. 6.8QPCh. 6 - Prob. 6.9QPCh. 6 - Define electronegativity and explain the...Ch. 6 - Prob. 6.11QPCh. 6 - Prob. 6.12QPCh. 6 - Prob. 6.13QPCh. 6 - Prob. 6.14QPCh. 6 - Prob. 6.15QPCh. 6 - Prob. 6.16QPCh. 6 - Arrange the following bonds in order of increasing...Ch. 6 - Prob. 6.18QPCh. 6 - Prob. 6.19QPCh. 6 - Prob. 6.20QPCh. 6 - Prob. 6.21QPCh. 6 - Prob. 6.22QPCh. 6 - Prob. 6.23QPCh. 6 - Prob. 6.24QPCh. 6 - Prob. 6.25QPCh. 6 - Prob. 6.26QPCh. 6 - Prob. 6.27QPCh. 6 - Prob. 6.28QPCh. 6 - Prob. 6.29QPCh. 6 - Prob. 6.30QPCh. 6 - Prob. 6.31QPCh. 6 - Prob. 6.32QPCh. 6 - Prob. 6.33QPCh. 6 - Prob. 6.34QPCh. 6 - Draw all of the resonance structures for the...Ch. 6 - Prob. 6.36QPCh. 6 - Prob. 6.37QPCh. 6 - Draw three resonance structures for the molecule...Ch. 6 - Draw three reasonable resonance structures for the...Ch. 6 - Indicate which of the following are resonance...Ch. 6 - Prob. 6.41QPCh. 6 - Prob. 6.42QPCh. 6 - Draw a resonance structure of the guanine molecule...Ch. 6 - Prob. 6.44QPCh. 6 - Give three examples of compounds that do not...Ch. 6 - Prob. 6.46QPCh. 6 - Prob. 6.47QPCh. 6 - Prob. 6.48QPCh. 6 - Prob. 6.49QPCh. 6 - Prob. 6.50QPCh. 6 - Prob. 6.51QPCh. 6 - Prob. 6.52QPCh. 6 - Prob. 6.53QPCh. 6 - Draw Lewis structures for the radical species ClF2...Ch. 6 - Prob. 6.55QPCh. 6 - Prob. 6.56QPCh. 6 - Prob. 6.57QPCh. 6 - Prob. 6.58QPCh. 6 - Prob. 6.59QPCh. 6 - Prob. 6.60QPCh. 6 - Give an example of an ion or molecule containing...Ch. 6 - Prob. 6.62QPCh. 6 - Prob. 6.63QPCh. 6 - Prob. 6.64QPCh. 6 - Are the following statements true or false? (a)...Ch. 6 - Prob. 6.66QPCh. 6 - Prob. 6.67QPCh. 6 - Most organic acids can be represented as RCOOH,...Ch. 6 - Prob. 6.69QPCh. 6 - Prob. 6.70QPCh. 6 - Prob. 6.71QPCh. 6 - The following species have been detected in...Ch. 6 - Prob. 6.73QPCh. 6 - Prob. 6.74QPCh. 6 - The triiodide ion (I3) in which the I atoms are...Ch. 6 - Prob. 6.76QPCh. 6 - Prob. 6.77QPCh. 6 - The chlorine nitrate (ClONO2) molecule is believed...Ch. 6 - Prob. 6.79QPCh. 6 - For each of the following organic molecules draw a...Ch. 6 - Prob. 6.81QPCh. 6 - Draw Lewis structures for the following organic...Ch. 6 - Draw Lewis structures for the following four...Ch. 6 - Prob. 6.84QPCh. 6 - Prob. 6.85QPCh. 6 - Draw three resonance structures for (a) the...Ch. 6 - Prob. 6.87QPCh. 6 - Prob. 6.88QPCh. 6 - Prob. 6.89QPCh. 6 - Draw a Lewis structure for nitrogen pentoxide...Ch. 6 - Prob. 6.91QPCh. 6 - Nitrogen dioxide (NO2) is a stable compound....Ch. 6 - Prob. 6.93QPCh. 6 - Vinyl chloride (C2H3Cl) differs from ethylene...Ch. 6 - Prob. 6.95QPCh. 6 - Prob. 6.96QPCh. 6 - In 1999 an unusual cation containing only nitrogen...Ch. 6 - Prob. 6.98QPCh. 6 - Prob. 6.99QPCh. 6 - Electrostatic potential maps for three compounds...Ch. 6 - Which of the following atoms must always obey the...Ch. 6 - Prob. 6.2KSPCh. 6 - Prob. 6.3KSPCh. 6 - How many lone pairs are on the central atom in the...
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