General, Organic, and Biological Chemistry (3rd Edition)
3rd Edition
ISBN: 9780134042428
Author: Laura D. Frost, S. Todd Deal
Publisher: PEARSON
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Chapter 6, Problem 6.61AP
Summary Introduction
To draw:
The alpha and beta anomers of D-mannose.
Introduction:
Diastereomers are those stereoisomers who differ in orientation of two chiral centers due to which the isomers are not the mirror images of each other. The cyclic forms of diastereoisomeric sugars which differ at the anomeric carbon (carbonyl carbon which reacts to form hemiacetal) are known as anomers. Hemiacetal is formed when the carbonyl carbon (partially positive) and oxygen of hydroxyl group (partially negative) forms a bond. The hemiacetal anomers exist in alpha and beta forms based on the site of substituent at anomeric carbon.
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You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products:
xi
1. ☑
2. H₂O
хе
i
Draw the missing reagent X you think will make this synthesis work in the drawing area below.
If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank.
Click and drag to start drawing a
structure.
There is no reagent that will make this synthesis work without complications.
: ☐
S
☐
Predict the major products of this organic reaction:
H
OH
1. LiAlH4
2. H₂O
?
Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry.
Click and drag to start drawing a
structure.
G
C
टे
For each reaction below, decide if the first stable organic product that forms in solution will create a new C-C bond, and check the appropriate box.
Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below.
Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first
stable product you expect to form in solution.
NH2
CI
MgCl
?
Will the first product that forms in this reaction
create a new CC bond?
Yes
No
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?
Will the first product that forms in this reaction
create a new CC bond?
Yes
No
G
टे
Chapter 6 Solutions
General, Organic, and Biological Chemistry (3rd Edition)
Ch. 6 - Prob. 6.1PPCh. 6 - Prob. 6.2PPCh. 6 - Prob. 6.3PPCh. 6 - Prob. 6.4PPCh. 6 - Prob. 6.5PPCh. 6 - Classify each of the following alcohols as a...Ch. 6 - Prob. 6.7PPCh. 6 - Prob. 6.8PPCh. 6 - Prob. 6.9PPCh. 6 - Prob. 6.10PP
Ch. 6 - Prob. 6.11PPCh. 6 - Prob. 6.12PPCh. 6 - Prob. 6.13PPCh. 6 - Prob. 6.14PPCh. 6 - Prob. 6.15PPCh. 6 - Prob. 6.16PPCh. 6 - Prob. 6.17PPCh. 6 - Prob. 6.18PPCh. 6 - Prob. 6.19PPCh. 6 - Prob. 6.20PPCh. 6 - Prob. 6.21PPCh. 6 - Prob. 6.22PPCh. 6 - When an aldehyde undergoes oxidation, the...Ch. 6 - Prob. 6.24PPCh. 6 - Prob. 6.25PPCh. 6 - Prob. 6.26PPCh. 6 - Prob. 6.27PPCh. 6 - Prob. 6.28PPCh. 6 - Prob. 6.29PPCh. 6 - Prob. 6.30PPCh. 6 - Prob. 6.31PPCh. 6 - Prob. 6.32PPCh. 6 - Prob. 6.33PPCh. 6 - Prob. 6.34PPCh. 6 - Prob. 6.35PPCh. 6 - Prob. 6.36PPCh. 6 - Prob. 6.37PPCh. 6 - Prob. 6.38PPCh. 6 - Prob. 6.39PPCh. 6 - Prob. 6.40PPCh. 6 - Prob. 6.41PPCh. 6 - Prob. 6.42PPCh. 6 - Prob. 6.43PPCh. 6 - Prob. 6.44PPCh. 6 - Prob. 6.45APCh. 6 - Prob. 6.46APCh. 6 - Prob. 6.47APCh. 6 - Prob. 6.48APCh. 6 - Prob. 6.49APCh. 6 - Prob. 6.50APCh. 6 - Prob. 6.51APCh. 6 - Prob. 6.52APCh. 6 - Prob. 6.53APCh. 6 - Classify each of the following as primary,...Ch. 6 - Prob. 6.55APCh. 6 - Prob. 6.56APCh. 6 - Prob. 6.57APCh. 6 - Prob. 6.58APCh. 6 - Prob. 6.59APCh. 6 - Prob. 6.60APCh. 6 - Prob. 6.61APCh. 6 - Prob. 6.62APCh. 6 - Prob. 6.63APCh. 6 - Prob. 6.64APCh. 6 - Prob. 6.65APCh. 6 - Prob. 6.66APCh. 6 - Prob. 6.67APCh. 6 - Prob. 6.68APCh. 6 - Prob. 6.69APCh. 6 - Draw the product of the following 1 4...Ch. 6 - Prob. 6.71APCh. 6 - Prob. 6.72APCh. 6 - Prob. 6.73APCh. 6 - Prob. 6.74APCh. 6 - Prob. 6.75APCh. 6 - Prob. 6.76APCh. 6 - Prob. 6.77CPCh. 6 - Prob. 6.78CPCh. 6 - Prob. 6.79CPCh. 6 - Prob. 6.80CPCh. 6 - How much energy is produced if a person eats 50 g...Ch. 6 - Prob. 6.82CPCh. 6 - Prob. 1IA.1QCh. 6 - Prob. 1IA.2QCh. 6 - Prob. 1IA.3QCh. 6 - Prob. 1IA.4QCh. 6 - Prob. 1IA.5QCh. 6 - Prob. 1IA.6QCh. 6 - Prob. 1IA.7QCh. 6 - Prob. 1IA.8QCh. 6 - Prob. 1IA.9QCh. 6 - Prob. 2IA.1QCh. 6 - Which oxygen n the hemiacetal product in Figure 1...Ch. 6 - Prob. 2IA.3QCh. 6 - Prob. 2IA.4QCh. 6 - Where did you place the OH for C1 (top or bottom)?Ch. 6 - Prob. 2IA.6QCh. 6 - Prob. 2IA.7QCh. 6 - Prob. 1ICCh. 6 - Prob. 2ICCh. 6 - Prob. 3ICCh. 6 - Prob. 4ICCh. 6 - Prob. 5IC
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