ELEMENTARY PRINCIPLES OF CHEM. PROCESS.
ELEMENTARY PRINCIPLES OF CHEM. PROCESS.
4th Edition
ISBN: 9781119249214
Author: FELDER
Publisher: INTER WILE
bartleby

Concept explainers

Question
Book Icon
Chapter 6, Problem 6.4P
Interpretation Introduction

(a)

Interpretation:

A semi log plot for the given data is to be prepared and a linear expression relating lnp to 1/T(K) is to be determined. Using this expression, heat of vaporization of ethylene glycol is to be estimated. Also, vapor pressures at each of the given temperature are to be calculated using Clausius-Clapeyron equation.

Concept introduction:

The Clausius-Clapeyron equation is defined as:

ln(p)=ΔHlvR(1T)+C   ...... (1)

Here, p is the vapor pressure of the gas at temperature T, ΔHlv is the latent heat of vaporization, and R is the universal gas constant. C is the constant.

The equation of a straight line on semi-log plot is, lny=mx+lnb.

Given two points (x1,y1) and (x2,y2), the slope (m) for this equation is calculated as:

m=lny2lny1x2x1   ...... (2)

Interpretation Introduction

(b)

Interpretation:

A semi log plot for the given data is to be prepared and a linear expression relating lnp to 1/T(K) is to be determined using Slope and Intercept functions of APEx. Using this expression, heat of vaporization of ethylene glycol is to be estimated. Also, vapor pressures at each of the given temperature is to be calculated using Clausius-Clapeyron equation.

Concept introduction:

The Clausius-Clapeyron equation is defined as:

ln(p)=ΔHlvR(1T)+C   ...... (1)

Here, p is the vapor pressure of the gas at temperature T, ΔHlv is the latent heat of vaporization, and R is the universal gas constant. C is the constant.

APEx is a tool in Excel to carry out process calculations.

Interpretation Introduction

(c)

Interpretation:

Vapor pressures of ethylene glycol at given temperatures are to be determined using equation of part (b). Also, the boiling point temperature at given system pressures are to be estimated and all these results are to be compared with the values calculated by APEx.

Concept introduction:

The Clausius-Clapeyron equation is defined as:

ln(p)=ΔHlvR(1T)+C   ...... (1)

Here, p is the vapor pressure of the gas at temperature T, ΔHlv is the latent heat of vaporization, and R is the universal gas constant. C is the constant.

Blurred answer
Students have asked these similar questions
please, provide me the solution with details.
please, provide me the solution with details
Please, provide me the solution with details

Chapter 6 Solutions

ELEMENTARY PRINCIPLES OF CHEM. PROCESS.

Ch. 6 - Prob. 6.11PCh. 6 - Prob. 6.12PCh. 6 - Prob. 6.13PCh. 6 - Air at 50% relative humidity is cooled...Ch. 6 - Prob. 6.15PCh. 6 - Prob. 6.16PCh. 6 - Air at 90°C and 1.00 atm (absolute) contains 10.0...Ch. 6 - When fermentation units are operated with high...Ch. 6 - When you step out of a shower, the temperature in...Ch. 6 - A fuel cell is an electrochemical device in which...Ch. 6 - Prob. 6.21PCh. 6 - Prob. 6.22PCh. 6 - Prob. 6.23PCh. 6 - Prob. 6.24PCh. 6 - Prob. 6.25PCh. 6 - Prob. 6.26PCh. 6 - Prob. 6.27PCh. 6 - Prob. 6.28PCh. 6 - An air conditioner is designed to bring 10.000...Ch. 6 - Prob. 6.30PCh. 6 - Prob. 6.31PCh. 6 - Prob. 6.32PCh. 6 - A gas stream containing 40.0 mole% hydrogen, 35.0%...Ch. 6 - Prob. 6.34PCh. 6 - In the manufacture of an active pharmaceutical...Ch. 6 - Prob. 6.36PCh. 6 - In the ?nal stage of the manufacturing process...Ch. 6 - Prob. 6.38PCh. 6 - A fuel gas containing methane and ethane is burned...Ch. 6 - A mixture of propane and butane is burned with...Ch. 6 - An important parameter in the design of gas...Ch. 6 - A liquid stream consisting of 12.5 mole% n-butane...Ch. 6 - Nitric acid is a chemical intermediate primarily...Ch. 6 - Prob. 6.44PCh. 6 - Sulfur trioxide (SO3) dissolves in and reacts with...Ch. 6 - State whether you would use Raoult’s law or Henrys...Ch. 6 - A gas containing nitrogen, benzene, and toluene is...Ch. 6 - Prob. 6.48PCh. 6 - Prob. 6.49PCh. 6 - A conelation for methane solubility in...Ch. 6 - Prob. 6.51PCh. 6 - The constituent partial pressures of a gas in...Ch. 6 - Prob. 6.53PCh. 6 - Prob. 6.54PCh. 6 - Prob. 6.55PCh. 6 - Prob. 6.56PCh. 6 - Prob. 6.57PCh. 6 - Prob. 6.58PCh. 6 - Nitrogen is bubbled through a liquid mixture that...Ch. 6 - Prob. 6.60PCh. 6 - Prob. 6.61PCh. 6 - Prob. 6.62PCh. 6 - The feed to a distillation column (sketched below)...Ch. 6 - Prob. 6.64PCh. 6 - Prob. 6.65PCh. 6 - Prob. 6.66PCh. 6 - Prob. 6.67PCh. 6 - Prob. 6.68PCh. 6 - Prob. 6.69PCh. 6 - Prob. 6.70PCh. 6 - A methanol-water feed stream is introduced to a...Ch. 6 - Prob. 6.72PCh. 6 - In this problem you will use a spreadsheet to...Ch. 6 - Prob. 6.74PCh. 6 - Prob. 6.75PCh. 6 - Prob. 6.76PCh. 6 - Acetaldehyde is synthesized by the catalytic...Ch. 6 - Dehydration of natural gas is necessary to prevent...Ch. 6 - A two-unit process is used to separate H2S from a...Ch. 6 - Prob. 6.80PCh. 6 - Prob. 6.81PCh. 6 - Prob. 6.82PCh. 6 - Prob. 6.83PCh. 6 - A solution containing 100 lbm KNO3/100 Ibm H2O at...Ch. 6 - A 10.0 wt% aqueous solution of sodium chloride is...Ch. 6 - Potassium dichromate (K2Cr2O7) is to be recovered...Ch. 6 - Prob. 6.87PCh. 6 - Prob. 6.88PCh. 6 - Sodium bicarbonate is synthesized by reacting...Ch. 6 - An ore containing 90 wt% MgSO4(H2O and the balance...Ch. 6 - An aqueous waste stream leaving a process contains...Ch. 6 - A solution of diphenyl (MW = 154.2) in benzene is...Ch. 6 - An aqueous solution of urea (MW = 60.06) freezes...Ch. 6 - Prob. 6.94PCh. 6 - Derive Equation 6.54 for the boiling-point...Ch. 6 - Prob. 6.96PCh. 6 - A stream of 5.00 wt% oleic acid in cottonseed oil...Ch. 6 - Benzene and hexane are being considered as...Ch. 6 - Acetone is lo be extracted with n-hexane from a...Ch. 6 - Prob. 6.100PCh. 6 - Prob. 6.101PCh. 6 - Five kilograms of a 30 wt% acetone70% water...Ch. 6 - An aqueous acetone solution is fed at a rate of...Ch. 6 - Prob. 6.104PCh. 6 - Prob. 6.105PCh. 6 - Air at 25°C and 1 atm with a relative humidity of...Ch. 6 - Prob. 6.107PCh. 6 - Prob. 6.108PCh. 6 - Various amounts of activated carbon were added to...
Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Introduction to Chemical Engineering Thermodynami...
Chemical Engineering
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:McGraw-Hill Education
Text book image
Elementary Principles of Chemical Processes, Bind...
Chemical Engineering
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY
Text book image
Elements of Chemical Reaction Engineering (5th Ed...
Chemical Engineering
ISBN:9780133887518
Author:H. Scott Fogler
Publisher:Prentice Hall
Text book image
Process Dynamics and Control, 4e
Chemical Engineering
ISBN:9781119285915
Author:Seborg
Publisher:WILEY
Text book image
Industrial Plastics: Theory and Applications
Chemical Engineering
ISBN:9781285061238
Author:Lokensgard, Erik
Publisher:Delmar Cengage Learning
Text book image
Unit Operations of Chemical Engineering
Chemical Engineering
ISBN:9780072848236
Author:Warren McCabe, Julian C. Smith, Peter Harriott
Publisher:McGraw-Hill Companies, The