The ground state 18-outer electronic configuration of copper (I) ion and its charge has to be predicted. Concept Introduction: 18-outer electron configuration: The configuration of a transition metal ion with 18 electrons in the outer shell is a relatively stable electron configuration is called as 18-outer electron configuration. The unusual stability of ns 2 ,np 6 ,nd 10 outer electron configuration is often referred as 18-electron rule.

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Answer 1

Question

Chapter 6, Problem 6.34P

(a)

Interpretation Introduction

Interpretation:

The ground state 18-outer electronic configuration of copper (I) ion and its charge has to be predicted.

Concept Introduction:

18-outer electron configuration:

The configuration of a transition metal ion with 18 electrons in the outer shell is a relatively stable electron configuration is called as 18-outer electron configuration. The unusual stability of ns2,np6,nd10 outer electron configuration is often referred as 18-electron rule.

(b)

Interpretation Introduction

Interpretation:

The ground state 18-outer electronic configuration of gallium ion and its charge has to be predicted.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The ground state 18-outer electronic configuration of mercury (II) ion and its charge has to be predicted.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

The ground state 18-outer electronic configuration of Gold (I) ion and its charge has to be predicted.

Concept Introduction:

Refer to part (a).

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2. Provide a clear arrow-pushing mechanism for the following reactions. Do not skip proton transfers, do not combine steps, and make sure your arrows are clear enough to be interpreted without ambiguity. a. CH3 Ph OEt هد Ph CH3 Hint: the species on the left is an ynolate, which behaves a lot like an enolate.

b. CH3 H3C CH3 CH3 H3C an unexpected product, containing a single 9- membered ring the expected product, containing two fused rings H3C-I (H3C)2CuLi an enolate

Answer 2

Question

Chapter 6, Problem 6.34P

(a)

Interpretation Introduction

Interpretation:

The ground state 18-outer electronic configuration of copper (I) ion and its charge has to be predicted.

Concept Introduction:

18-outer electron configuration:

The configuration of a transition metal ion with 18 electrons in the outer shell is a relatively stable electron configuration is called as 18-outer electron configuration. The unusual stability of ns2,np6,nd10 outer electron configuration is often referred as 18-electron rule.

(b)

Interpretation Introduction

Interpretation:

The ground state 18-outer electronic configuration of gallium ion and its charge has to be predicted.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The ground state 18-outer electronic configuration of mercury (II) ion and its charge has to be predicted.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

The ground state 18-outer electronic configuration of Gold (I) ion and its charge has to be predicted.

Concept Introduction:

Refer to part (a).

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Answer 3

Question

Chapter 6, Problem 6.34P

(a)

Interpretation Introduction

Interpretation:

The ground state 18-outer electronic configuration of copper (I) ion and its charge has to be predicted.

Concept Introduction:

18-outer electron configuration:

The configuration of a transition metal ion with 18 electrons in the outer shell is a relatively stable electron configuration is called as 18-outer electron configuration. The unusual stability of ns2,np6,nd10 outer electron configuration is often referred as 18-electron rule.

(b)

Interpretation Introduction

Interpretation:

The ground state 18-outer electronic configuration of gallium ion and its charge has to be predicted.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The ground state 18-outer electronic configuration of mercury (II) ion and its charge has to be predicted.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

The ground state 18-outer electronic configuration of Gold (I) ion and its charge has to be predicted.

Concept Introduction:

Refer to part (a).

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Answer 4

Question

Chapter 6, Problem 6.34P

(a)

Interpretation Introduction

Interpretation:

The ground state 18-outer electronic configuration of copper (I) ion and its charge has to be predicted.

Concept Introduction:

18-outer electron configuration:

The configuration of a transition metal ion with 18 electrons in the outer shell is a relatively stable electron configuration is called as 18-outer electron configuration. The unusual stability of ns2,np6,nd10 outer electron configuration is often referred as 18-electron rule.

(b)

Interpretation Introduction

Interpretation:

The ground state 18-outer electronic configuration of gallium ion and its charge has to be predicted.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The ground state 18-outer electronic configuration of mercury (II) ion and its charge has to be predicted.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

The ground state 18-outer electronic configuration of Gold (I) ion and its charge has to be predicted.

Concept Introduction:

Refer to part (a).

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Answer 5

Chapter 6, Problem 6.34P

(a)

Interpretation Introduction

Interpretation:

The ground state 18-outer electronic configuration of copper (I) ion and its charge has to be predicted.

Concept Introduction:

18-outer electron configuration:

The configuration of a transition metal ion with 18 electrons in the outer shell is a relatively stable electron configuration is called as 18-outer electron configuration. The unusual stability of ns2,np6,nd10 outer electron configuration is often referred as 18-electron rule.

(b)

Interpretation Introduction

Interpretation:

The ground state 18-outer electronic configuration of gallium ion and its charge has to be predicted.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The ground state 18-outer electronic configuration of mercury (II) ion and its charge has to be predicted.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

The ground state 18-outer electronic configuration of Gold (I) ion and its charge has to be predicted.

Concept Introduction:

Refer to part (a).

Answer 6

Chapter 6, Problem 6.34P

(a)

Interpretation Introduction

Interpretation:

The ground state 18-outer electronic configuration of copper (I) ion and its charge has to be predicted.

Concept Introduction:

18-outer electron configuration:

The configuration of a transition metal ion with 18 electrons in the outer shell is a relatively stable electron configuration is called as 18-outer electron configuration. The unusual stability of ns2,np6,nd10 outer electron configuration is often referred as 18-electron rule.

Answer 7

Chapter 6, Problem 6.34P

(a)

Interpretation Introduction

Interpretation:

The ground state 18-outer electronic configuration of copper (I) ion and its charge has to be predicted.

Concept Introduction:

18-outer electron configuration:

The configuration of a transition metal ion with 18 electrons in the outer shell is a relatively stable electron configuration is called as 18-outer electron configuration. The unusual stability of ns2,np6,nd10 outer electron configuration is often referred as 18-electron rule.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The ground state 18-outer electronic configuration of gallium ion and its charge has to be predicted.

Concept Introduction:

Refer to part (a).

Answer 9

(b)

Interpretation Introduction

Interpretation:

The ground state 18-outer electronic configuration of gallium ion and its charge has to be predicted.

Concept Introduction:

Refer to part (a).

Answer 10

(c)

Interpretation Introduction

Interpretation:

The ground state 18-outer electronic configuration of mercury (II) ion and its charge has to be predicted.

Concept Introduction:

Refer to part (a).

Answer 11

(c)

Interpretation Introduction

Interpretation:

The ground state 18-outer electronic configuration of mercury (II) ion and its charge has to be predicted.

Concept Introduction:

Refer to part (a).

Answer 12

(d)

Interpretation Introduction

Interpretation:

The ground state 18-outer electronic configuration of Gold (I) ion and its charge has to be predicted.

Concept Introduction:

Refer to part (a).

Answer 13

(d)

Interpretation Introduction

Interpretation:

The ground state 18-outer electronic configuration of Gold (I) ion and its charge has to be predicted.

Concept Introduction:

Refer to part (a).

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 6 - Prob. 6.1P Ch. 6 - Prob. 6.2P Ch. 6 - Prob. 6.3P Ch. 6 - Prob. 6.4P Ch. 6 - Prob. 6.5P Ch. 6 - Prob. 6.6P Ch. 6 - Prob. 6.7P Ch. 6 - Prob. 6.8P Ch. 6 - Prob. 6.9P Ch. 6 - Prob. 6.10P

Interpretation: The ground state 18-outer electronic configuration of gallium ion and its charge has to be predicted. Concept Introduction: Refer to part (a).

Interpretation: The ground state 18-outer electronic configuration of mercury (II) ion and its charge has to be predicted. Concept Introduction: Refer to part (a).

Interpretation: The ground state 18-outer electronic configuration of Gold (I) ion and its charge has to be predicted. Concept Introduction: Refer to part (a).

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Chapter 6 Solutions

Interpretation:

The ground state 18-outer electronic configuration of gallium ion and its charge has to be predicted.

Concept Introduction:

Refer to part (a).

Interpretation:

The ground state 18-outer electronic configuration of mercury (II) ion and its charge has to be predicted.

Concept Introduction:

Refer to part (a).

Interpretation:

The ground state 18-outer electronic configuration of Gold (I) ion and its charge has to be predicted.

Concept Introduction:

Refer to part (a).