(a) Interpretation: Why the greater contribution, from the second of the two resonance structures shown, is counterintuitive based on charge stability is to be explained. Concept introduction: The relative stabilities of resonance structures can be determined on the basis of charge stability. The structure with positive charge on less electronegative atom and negative charge on more electronegative atom is more stable. The most stable resonance structure contributes more to the resonance hybrid.

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Answer 1

Question

Chapter 6, Problem 6.29P

Interpretation Introduction

(a)

Interpretation:

Why the greater contribution, from the second of the two resonance structures shown, is counterintuitive based on charge stability is to be explained.

Concept introduction:

The relative stabilities of resonance structures can be determined on the basis of charge stability. The structure with positive charge on less electronegative atom and negative charge on more electronegative atom is more stable. The most stable resonance structure contributes more to the resonance hybrid.

Interpretation Introduction

(b)

Interpretation:

The greater contribution from the second resonance structure is to be explained.

Concept introduction:

The most stable resonance structure contributes most to the hybrid.

Stability of a resonance structure depends on a number of factors. More the number of bonds, more the number of atoms that follow the octet or the duet rule and less the number of formal charge, the more stable the structure.

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For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? NH2 MgBr Will the first product that forms in this reaction create a new CC bond? ○ Yes ○ No MgBr ? Will the first product that forms in this reaction create a new CC bond? O Yes O No Click and drag to start drawing a structure. :☐ G x c olo Ar HE

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Answer 2

Question

Chapter 6, Problem 6.29P

Interpretation Introduction

(a)

Interpretation:

Why the greater contribution, from the second of the two resonance structures shown, is counterintuitive based on charge stability is to be explained.

Concept introduction:

The relative stabilities of resonance structures can be determined on the basis of charge stability. The structure with positive charge on less electronegative atom and negative charge on more electronegative atom is more stable. The most stable resonance structure contributes more to the resonance hybrid.

Interpretation Introduction

(b)

Interpretation:

The greater contribution from the second resonance structure is to be explained.

Concept introduction:

The most stable resonance structure contributes most to the hybrid.

Stability of a resonance structure depends on a number of factors. More the number of bonds, more the number of atoms that follow the octet or the duet rule and less the number of formal charge, the more stable the structure.

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Answer 3

Question

Chapter 6, Problem 6.29P

Interpretation Introduction

(a)

Interpretation:

Why the greater contribution, from the second of the two resonance structures shown, is counterintuitive based on charge stability is to be explained.

Concept introduction:

The relative stabilities of resonance structures can be determined on the basis of charge stability. The structure with positive charge on less electronegative atom and negative charge on more electronegative atom is more stable. The most stable resonance structure contributes more to the resonance hybrid.

Interpretation Introduction

(b)

Interpretation:

The greater contribution from the second resonance structure is to be explained.

Concept introduction:

The most stable resonance structure contributes most to the hybrid.

Stability of a resonance structure depends on a number of factors. More the number of bonds, more the number of atoms that follow the octet or the duet rule and less the number of formal charge, the more stable the structure.

Expert Solution & Answer

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Answer 4

Question

Chapter 6, Problem 6.29P

Interpretation Introduction

(a)

Interpretation:

Why the greater contribution, from the second of the two resonance structures shown, is counterintuitive based on charge stability is to be explained.

Concept introduction:

The relative stabilities of resonance structures can be determined on the basis of charge stability. The structure with positive charge on less electronegative atom and negative charge on more electronegative atom is more stable. The most stable resonance structure contributes more to the resonance hybrid.

Interpretation Introduction

(b)

Interpretation:

The greater contribution from the second resonance structure is to be explained.

Concept introduction:

The most stable resonance structure contributes most to the hybrid.

Stability of a resonance structure depends on a number of factors. More the number of bonds, more the number of atoms that follow the octet or the duet rule and less the number of formal charge, the more stable the structure.

Expert Solution & Answer

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Answer 5

Chapter 6, Problem 6.29P

Interpretation Introduction

(a)

Interpretation:

Why the greater contribution, from the second of the two resonance structures shown, is counterintuitive based on charge stability is to be explained.

Concept introduction:

The relative stabilities of resonance structures can be determined on the basis of charge stability. The structure with positive charge on less electronegative atom and negative charge on more electronegative atom is more stable. The most stable resonance structure contributes more to the resonance hybrid.

Interpretation Introduction

(b)

Interpretation:

The greater contribution from the second resonance structure is to be explained.

Concept introduction:

The most stable resonance structure contributes most to the hybrid.

Stability of a resonance structure depends on a number of factors. More the number of bonds, more the number of atoms that follow the octet or the duet rule and less the number of formal charge, the more stable the structure.

Answer 6

Chapter 6, Problem 6.29P

Interpretation Introduction

(a)

Interpretation:

Why the greater contribution, from the second of the two resonance structures shown, is counterintuitive based on charge stability is to be explained.

Concept introduction:

The relative stabilities of resonance structures can be determined on the basis of charge stability. The structure with positive charge on less electronegative atom and negative charge on more electronegative atom is more stable. The most stable resonance structure contributes more to the resonance hybrid.

Answer 7

Chapter 6, Problem 6.29P

Interpretation Introduction

(a)

Interpretation:

Why the greater contribution, from the second of the two resonance structures shown, is counterintuitive based on charge stability is to be explained.

Concept introduction:

The relative stabilities of resonance structures can be determined on the basis of charge stability. The structure with positive charge on less electronegative atom and negative charge on more electronegative atom is more stable. The most stable resonance structure contributes more to the resonance hybrid.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The greater contribution from the second resonance structure is to be explained.

Concept introduction:

The most stable resonance structure contributes most to the hybrid.

Stability of a resonance structure depends on a number of factors. More the number of bonds, more the number of atoms that follow the octet or the duet rule and less the number of formal charge, the more stable the structure.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The greater contribution from the second resonance structure is to be explained.

Concept introduction:

The most stable resonance structure contributes most to the hybrid.

Stability of a resonance structure depends on a number of factors. More the number of bonds, more the number of atoms that follow the octet or the duet rule and less the number of formal charge, the more stable the structure.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 6 - Prob. 6.1P Ch. 6 - Prob. 6.2P Ch. 6 - Prob. 6.3P Ch. 6 - Prob. 6.4P Ch. 6 - Prob. 6.5P Ch. 6 - Prob. 6.6P Ch. 6 - Prob. 6.7P Ch. 6 - Prob. 6.8P Ch. 6 - Prob. 6.9P Ch. 6 - Prob. 6.10P

Solution Summary: The author explains why the greater contribution from the second resonance structure is counterintuitive based on charge stability.

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