Organic Chemistry-Package(Custom)
Organic Chemistry-Package(Custom)
4th Edition
ISBN: 9781259141089
Author: SMITH
Publisher: MCG
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Chapter 6, Problem 6.1P
Interpretation Introduction

(a)

Interpretation: The given transformation is to be classified as substitution, elimination, or addition reaction.

Concept introduction: The substitution reactions involve the substitution or replacement of an atom or group of atoms in a compound by another atom or groups of atoms. In the substitution reactions, the replacement takes place by the break down of sigma bonds.

In elimination reaction, the formation of π bonds occurs due to the removal of an atom or group of atoms from the starting material, whereas the addition reaction involves the addition of elements into the starting material.

Expert Solution
Check Mark

Answer to Problem 6.1P

The given transformation is an example of a substitution reaction.

Explanation of Solution

The given transformation is shown as,

Organic Chemistry-Package(Custom), Chapter 6, Problem 6.1P , additional homework tip  1

Figure 1

In the above reaction, the hydroxyl group is replaced by a bromine atom. The breakdown of the sigma bond precedes the mechanism. On replacement of the hydroxyl group, one sigma bond breaks and another is formed at the same position. Therefore, it is classified as the substitution reaction.

Conclusion

The given transformation is classified as a substitution reaction.

Interpretation Introduction

(b)

Interpretation: The given transformation is to be classified as substitution, elimination, or addition reaction.

Concept introduction: The substitution reactions involve the substitution or replacement of an atom or group of atoms in a compound by another atom or groups of atoms. In the substitution reactions, the replacement takes place by the break down of sigma bonds.

In elimination reaction, the formation of π bonds occurs due to the removal of an atom or group of atoms from the starting material, whereas the addition reaction involves the addition of elements into the starting material.

Expert Solution
Check Mark

Answer to Problem 6.1P

The given transformation is an example of an addition reaction.

Explanation of Solution

The given transformation is shown as,

Organic Chemistry-Package(Custom), Chapter 6, Problem 6.1P , additional homework tip  2

Figure 2

The above reaction involves the breakdown of π bond. In this reaction, C=O bond is converted into OH group by the addition of two hydrogen atoms. Therefore, this reaction is an example of an addition reaction.

Conclusion

The given transformation is classified as an addition reaction.

Interpretation Introduction

(c)

Interpretation: The given transformation is to be classified as substitution, elimination, or addition.

Concept introduction: The substitution reactions involve the substitution or replacement of an atom or group of atoms in a compound by another atom or groups of atoms. In the substitution reactions, the replacement takes place by the break down of sigma bonds.

In elimination reaction, the formation of π bonds occurs due to the removal of an atom or group of atoms from the starting material, whereas the addition reaction involves the addition of elements into the starting material.

Expert Solution
Check Mark

Answer to Problem 6.1P

The given transformation is an example of a substitution reaction.

Explanation of Solution

The given transformation is shown as,

Organic Chemistry-Package(Custom), Chapter 6, Problem 6.1P , additional homework tip  3

Figure 3

In the above reaction, the hydrogen is replaced by chlorine. The breakdown of the sigma bond precedes the mechanism. On the replacement of hydrogen, one sigma bond breaks and another sigma bond is formed between carbon and substituent atom.

Conclusion

The given transformation is classified as a substitution reaction.

Interpretation Introduction

(d)

Interpretation: The given transformation as substitution, elimination, or addition is to be classified.

Concept introduction: The substitution reactions involve the substitution or replacement of an atom or group of atoms in a compound by another atom or groups of atoms. In the substitution reactions, the replacement takes place by the break down of sigma bonds.

In elimination reaction, the formation of π bonds occurs due to the removal of an atom or group of atoms from the starting material, whereas the addition reaction involves the addition of elements into the starting material.

Expert Solution
Check Mark

Answer to Problem 6.1P

The given transformation is an example of an elimination reaction.

Explanation of Solution

The given transformation is shown as,

Organic Chemistry-Package(Custom), Chapter 6, Problem 6.1P , additional homework tip  4

Figure 4

In this reaction, the formation of π bond takes place by the removal of a water molecule from the starting material. Therefore, it is an example of an elimination reaction.

Conclusion

The given transformation is classified as an elimination reaction.

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Chapter 6 Solutions

Organic Chemistry-Package(Custom)

Ch. 6 - Prob. 6.11PCh. 6 - For a reaction with H=40kJ/mol, decide which of...Ch. 6 - For a reaction with H=20kJ/mol, decide which of...Ch. 6 - Draw an energy diagram for a reaction in which the...Ch. 6 - Prob. 6.15PCh. 6 - Prob. 6.16PCh. 6 - Problem 6.19 Consider the following energy...Ch. 6 - Draw an energy diagram for a two-step reaction,...Ch. 6 - Which value if any corresponds to a faster...Ch. 6 - Prob. 6.20PCh. 6 - Problem 6.23 For each rate equation, what effect...Ch. 6 - Prob. 6.22PCh. 6 - Identify the catalyst in each equation. a....Ch. 6 - Draw the products of homolysis or heterolysis of...Ch. 6 - Explain why the bond dissociation energy for bond...Ch. 6 - Classify each transformation as substitution,...Ch. 6 - Prob. 6.27PCh. 6 - Draw the products of each reaction by following...Ch. 6 - Prob. 6.29PCh. 6 - Prob. 6.30PCh. 6 - Prob. 6.31PCh. 6 - Prob. 6.32PCh. 6 - Prob. 6.33PCh. 6 - Prob. 6.34PCh. 6 - Prob. 6.35PCh. 6 - 6.39. a. Which value corresponds to a negative...Ch. 6 - Prob. 6.37PCh. 6 - At 25 C, the energy difference Go for the...Ch. 6 - For which of the following reaction is S a...Ch. 6 - Prob. 6.40PCh. 6 - Prob. 6.41PCh. 6 - 6.44 Consider the following reaction: . Use curved...Ch. 6 - Prob. 6.43PCh. 6 - Draw an energy diagram for the Bronsted-Lowry...Ch. 6 - Prob. 6.45PCh. 6 - Prob. 6.46PCh. 6 - Prob. 6.47PCh. 6 - Prob. 6.48PCh. 6 - The conversion of acetyl chloride to methyl...Ch. 6 - Prob. 6.50PCh. 6 - Prob. 6.51PCh. 6 - 6.54 Explain why is more acidic than , even...Ch. 6 - Prob. 6.53PCh. 6 - Prob. 6.54PCh. 6 - Prob. 6.55PCh. 6 - Although Keq of equation 1 in problem 6.57 does...Ch. 6 - Prob. 6.57P
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