Organic Chemistry-Package(Custom)
Organic Chemistry-Package(Custom)
4th Edition
ISBN: 9781259141089
Author: SMITH
Publisher: MCG
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Chapter 6, Problem 6.19P

Which value (if any) corresponds to a faster reaction:

a) E a = 40 kJ / mol or E a = 4 kJ / mol

b) A reaction temperature of 0 ° C or a reaction temperature of 25 ° C .

c) K eq = 10 or K eq = 100

d) Δ H ° = 10 kJ / mol or Δ H ° = 10 kJ / mol

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Calculate ΔSsurr at the indicated temperature for each reaction.a. ΔH °rxn = -385 kJ; 298 K b. ΔH °rxn = -385 kJ; 77 Kc. ΔH °rxn = +114 kJ; 298 K d. ΔH °rxn = +114 kJ; 77 K
1)exothermic,isothermic,or endothermic 2)
Cl2(g) + 5F2(g) → 2ClF5(g)  ΔH°=-510.0 kJ ClF3(g) + Cl2(g) → 3ClF(g)  ΔH°=-5.5 kJ Cl2(g) + F2(g) → 2ClF(g)  ΔH°=-113.0 kJ     calculate ΔH° for the reaction:ClF5(g) → ClF3(g) + F2(g)

Chapter 6 Solutions

Organic Chemistry-Package(Custom)

Ch. 6 - Prob. 6.11PCh. 6 - For a reaction with H=40kJ/mol, decide which of...Ch. 6 - For a reaction with H=20kJ/mol, decide which of...Ch. 6 - Draw an energy diagram for a reaction in which the...Ch. 6 - Prob. 6.15PCh. 6 - Prob. 6.16PCh. 6 - Problem 6.19 Consider the following energy...Ch. 6 - Draw an energy diagram for a two-step reaction,...Ch. 6 - Which value if any corresponds to a faster...Ch. 6 - Prob. 6.20PCh. 6 - Problem 6.23 For each rate equation, what effect...Ch. 6 - Prob. 6.22PCh. 6 - Identify the catalyst in each equation. a....Ch. 6 - Draw the products of homolysis or heterolysis of...Ch. 6 - Explain why the bond dissociation energy for bond...Ch. 6 - Classify each transformation as substitution,...Ch. 6 - Prob. 6.27PCh. 6 - Draw the products of each reaction by following...Ch. 6 - Prob. 6.29PCh. 6 - Prob. 6.30PCh. 6 - Prob. 6.31PCh. 6 - Prob. 6.32PCh. 6 - Prob. 6.33PCh. 6 - Prob. 6.34PCh. 6 - Prob. 6.35PCh. 6 - 6.39. a. Which value corresponds to a negative...Ch. 6 - Prob. 6.37PCh. 6 - At 25 C, the energy difference Go for the...Ch. 6 - For which of the following reaction is S a...Ch. 6 - Prob. 6.40PCh. 6 - Prob. 6.41PCh. 6 - 6.44 Consider the following reaction: . Use curved...Ch. 6 - Prob. 6.43PCh. 6 - Draw an energy diagram for the Bronsted-Lowry...Ch. 6 - Prob. 6.45PCh. 6 - Prob. 6.46PCh. 6 - Prob. 6.47PCh. 6 - Prob. 6.48PCh. 6 - The conversion of acetyl chloride to methyl...Ch. 6 - Prob. 6.50PCh. 6 - Prob. 6.51PCh. 6 - 6.54 Explain why is more acidic than , even...Ch. 6 - Prob. 6.53PCh. 6 - Prob. 6.54PCh. 6 - Prob. 6.55PCh. 6 - Although Keq of equation 1 in problem 6.57 does...Ch. 6 - Prob. 6.57P
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