Chemistry for Engineering Students
3rd Edition
ISBN: 9781285199023
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
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Chapter 6, Problem 6.16PAE
6.13 Place these types of radiation in order of increasing energy per photon. (a) green light from a mercury lamp, (b) X-rays from a dental X-ray, (c) microwave oven, (d) an FM music station broadcasting at 89.1 MHz
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(a) Write down the structure of EDTA molecule and show the complex structure with Pb2+ . (b) When do you need to perform back titration? (c) Ni2+ can be analyzed by a back titration using standard Zn2+ at pH 5.5 with xylenol orange indicator. A solution containing 25.00 mL of Ni2+ in dilute HCl is treated with 25.00 mL of 0.05283 M Na2EDTA. The solution is neutralized with NaOH, and the pH is adjusted to 5.5 with acetate buffer. The solution turns yellow when a few drops of indicator are added. Titration with 0.02299 M Zn2+ requires 17.61 mL to reach the red end point. What is the molarity of Ni2+ in the unknown?
A compound has the molecular formula CH40, and shows a strong IR absorption at 2850-3150 cm. The following signals appear in the 'H NMR
spectrum: 1.4 ppm (triplet, 6H), 4.0 ppm (quartet, 4H), 6.8 ppm (broad singlet, 4H).
Which of the following structures is consistent with these data? Select the single best answer.
OCH CH₂
x
OCH2CH3
CH₂OCH3
OH
CH₂OCH
OH
CH, OCH₁
CH₂OCH,
CH₂OCH
HO
OH
°
CH₂OCH3
predict the major product while showing me the intermidiate products from each reagent/reagent group
Chapter 6 Solutions
Chemistry for Engineering Students
Ch. 6 - describe trace analysis and explain its role in...Ch. 6 - describe waves in terms of frequency, wavelength,...Ch. 6 - Prob. 3COCh. 6 - relate the frequency, wavelength, and amplitude of...Ch. 6 - describe the photoelectric effect by stating what...Ch. 6 - Prob. 6COCh. 6 - • use Planck’s equation to calculate the energy of...Ch. 6 - Prob. 8COCh. 6 - Prob. 9COCh. 6 - • describe similarities and differences between...
Ch. 6 - Prob. 11COCh. 6 - Prob. 12COCh. 6 - • identify an orbital (as 1s, 3p, etc.) from its...Ch. 6 - • list the number of orbitals of each type (1s,...Ch. 6 - • sketch the shapes of s and p orbitals and...Ch. 6 - • rank various orbitals in terms of size and...Ch. 6 - Prob. 17COCh. 6 - Prob. 18COCh. 6 - Prob. 19COCh. 6 - Prob. 20COCh. 6 - Prob. 6.1PAECh. 6 - 6.2 Unlike XRF, AAS cannot be used for...Ch. 6 - Prob. 6.3PAECh. 6 - Prob. 6.4PAECh. 6 - Prob. 6.5PAECh. 6 - Prob. 6.6PAECh. 6 - Explain why light is referred to as...Ch. 6 - Prob. 6.8PAECh. 6 - 6.7 Arrange the following regions of the...Ch. 6 - 6.8 Calculate the wavelength in meters, of...Ch. 6 - 6.9 If a string of decorative lights includes...Ch. 6 - 6.10 Define the term refraction.Ch. 6 - 6.11 Define the term photon.Ch. 6 - Prob. 6.14PAECh. 6 - 6.12 Find the energy of a photon with each of the...Ch. 6 - 6.13 Place these types of radiation in order of...Ch. 6 - 6.14 For photon with the following energies,...Ch. 6 - Prob. 6.18PAECh. 6 - 6.16 Various optical disk drives rely on laser...Ch. 6 - 6.17 The laser in most supermarket barcode...Ch. 6 - 6.18 Assume that a microwave oven operates at a...Ch. 6 - 6.19 Fill in the blanks below to complete a...Ch. 6 - 6.20 When light with a wavelength of 58.5 nm...Ch. 6 - 6.21 The electron binding energy fur copper metal...Ch. 6 - What is the difference between continuous and...Ch. 6 - Prob. 6.26PAECh. 6 - 6.23 Describe how the Bohr model of the atom...Ch. 6 - 6.24 According to the Bohr model of the atom, what...Ch. 6 - 6.25 Define the term ground state.Ch. 6 - 6.26 The figure below depicts the first four...Ch. 6 - 6.27 Refer w the data and energy-Ievel diagram...Ch. 6 - 6.28 A neon atom cmi light at many wavelengths,...Ch. 6 - 6.29 A mercury atom emits light at many...Ch. 6 - 6.30 How did the observation of electron...Ch. 6 - 6.31 Why do we use a wave function to describe...Ch. 6 - 6.32 What are the mathematical origins of quantum...Ch. 6 - Prob. 6.37PAECh. 6 - 6.34 Which of the following represent valid sets...Ch. 6 - 6.35 A particular orbital has n = 4 and l = 2....Ch. 6 - 6.36 Why are there no 2d orbitals?Ch. 6 - 6.34 What is the maximum number of electrons in an...Ch. 6 - 6.38 How many orbitals correspond to each of the...Ch. 6 - Prob. 6.43PAECh. 6 - Prob. 6.44PAECh. 6 - 6.40 Referring to Figure 6.15, draw a 4p orbitals,...Ch. 6 - Prob. 6.46PAECh. 6 - 6.43 Define the term spin paired.Ch. 6 - 6.44 On what does the Pauli exclusion principle...Ch. 6 - Prob. 6.49PAECh. 6 - Prob. 6.50PAECh. 6 - Prob. 6.51PAECh. 6 - 6.47 Depict two ways to place electrons in the 2p...Ch. 6 - 6.48 Write the ground state electron configuration...Ch. 6 - 6.49 Which of these electron configurations are...Ch. 6 - 6.50 From the list of atoms and ions given,...Ch. 6 - Prob. 6.56PAECh. 6 - Prob. 6.57PAECh. 6 - Prob. 6.58PAECh. 6 - Describe how valence electron configurations...Ch. 6 - Why is there no element to the immediate right of...Ch. 6 - Prob. 6.61PAECh. 6 - Prob. 6.62PAECh. 6 - 6.55 Explain why the s block of the periodic table...Ch. 6 - Prob. 6.64PAECh. 6 - Prob. 6.65PAECh. 6 - 6.60 Use the electron configurations of the alkali...Ch. 6 - 6.61 Using only a periodic table as a guide,...Ch. 6 - 6.62 Define the term ionization energy....Ch. 6 - 6.63 At which ionization for chlorine would you...Ch. 6 - 6.64 Arrange the following atoms in order of...Ch. 6 - Prob. 6.71PAECh. 6 - 6.66 Which element would you expect to have the...Ch. 6 - Prob. 6.73PAECh. 6 - 6.68 Indicate which species in each pair has the...Ch. 6 - 6.69 Compare the elements Na, B, Al, and C with...Ch. 6 - 6.70 Rank the following in order of decreasing...Ch. 6 - 6.71 Several excited states of the neon atom are...Ch. 6 - Prob. 6.78PAECh. 6 - Prob. 6.79PAECh. 6 - 6.92 The photoelectric effect can he used to...Ch. 6 - 6.93 A mercury atom is initially in its lowest...Ch. 6 - Prob. 6.82PAECh. 6 - 6.95 A metallic sample is known to be barium,...Ch. 6 - 6.96 When a helium atom absorbs light at 58.44 nm,...Ch. 6 - 6.97 Arrange the members of each of the following...Ch. 6 - 6.98 Arrange the following sets of anions in order...Ch. 6 - 6.99 The photoelectric effect can he used in...Ch. 6 - 6.100 Some spacecraft use ion propulsion engines....Ch. 6 - 6.101 Laser welding is a technique in which a...Ch. 6 - Prob. 6.90PAECh. 6 - 6.103 Atomic absorption spectroscopy is based on...Ch. 6 - 6.104 The red color in fireworks is the result of...Ch. 6 - 6.105 When we say that the existence of atomic...Ch. 6 - 6.106 When Bohr devised his model for the atom,...Ch. 6 - Prob. 6.95PAE
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