Chemistry for Today: General  Organic  and Biochemistry
Chemistry for Today: General Organic and Biochemistry
9th Edition
ISBN: 9781337514576
Author: Seager
Publisher: Cengage
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Chapter 6, Problem 6.15E

The following statements are best associated with the solid, liquid, or gaseous states of matter. Match the statements to the appropriate state of matter.

a. This state is characterized by the lowest density of the three.

b. This state is characterized by an indefinite shape and a high density.

c. In this state, disruptive forces prevail over cohesive forces.

d. In this state, cohesive forces are most dominant.

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Part I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400
• Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peak
Could you redraw these and also explain how to solve them for me pleas

Chapter 6 Solutions

Chemistry for Today: General Organic and Biochemistry

Ch. 6 - Prob. 6.11ECh. 6 - Prob. 6.12ECh. 6 - Explain each of the following observations using...Ch. 6 - Prob. 6.14ECh. 6 - The following statements are best associated with...Ch. 6 - Prob. 6.16ECh. 6 - Prob. 6.17ECh. 6 - Prob. 6.18ECh. 6 - Prob. 6.19ECh. 6 - Prob. 6.20ECh. 6 - Prob. 6.21ECh. 6 - Convert each of the following temperatures from...Ch. 6 - Prob. 6.23ECh. 6 - Prob. 6.24ECh. 6 - A 200.mL sample of oxygen gas is collected at...Ch. 6 - A 200.mL sample of nitrogen gas is collected at...Ch. 6 - Prob. 6.27ECh. 6 - Prob. 6.28ECh. 6 - What volume in liters of air measured at 1.00atm...Ch. 6 - What volume in liters of air measured at 1.00atm...Ch. 6 - Prob. 6.31ECh. 6 - Prob. 6.32ECh. 6 - Prob. 6.33ECh. 6 - Prob. 6.34ECh. 6 - A sample of gas has a volume of 375mL at 27C. The...Ch. 6 - What volume of gas in liters at 120.C must be...Ch. 6 - Prob. 6.37ECh. 6 - Prob. 6.38ECh. 6 - Prob. 6.39ECh. 6 - A helium balloon was partially filled with...Ch. 6 - You have a 1.50-L balloon full of air at 30.C. To...Ch. 6 - Prob. 6.42ECh. 6 - What minimum pressure would a 250.-mL aerosol can...Ch. 6 - Prob. 6.44ECh. 6 - Prob. 6.45ECh. 6 - Prob. 6.46ECh. 6 - Prob. 6.47ECh. 6 - Prob. 6.48ECh. 6 - Prob. 6.49ECh. 6 - The pressure gauge of a steel cylinder of methane...Ch. 6 - Suppose 12.0g of dry ice (solidCO2) was placed in...Ch. 6 - Prob. 6.52ECh. 6 - Prob. 6.53ECh. 6 - A sample of gaseous methyl ether has a mass of...Ch. 6 - A sample of gaseous nitrogen oxide is found to...Ch. 6 - A sample of gas weighs 0.176g and has a volume of...Ch. 6 - Prob. 6.57ECh. 6 - Prob. 6.58ECh. 6 - Prob. 6.59ECh. 6 - Prob. 6.60ECh. 6 - Prob. 6.61ECh. 6 - Prob. 6.62ECh. 6 - Prob. 6.63ECh. 6 - Classify each of the following processes as...Ch. 6 - Classify each of the following processes as...Ch. 6 - Prob. 6.66ECh. 6 - Prob. 6.67ECh. 6 - Prob. 6.68ECh. 6 - Prob. 6.69ECh. 6 - Prob. 6.70ECh. 6 - Prob. 6.71ECh. 6 - Prob. 6.72ECh. 6 - Prob. 6.73ECh. 6 - Prob. 6.74ECh. 6 - Prob. 6.75ECh. 6 - Using the specific heat data of Table 6.8,...Ch. 6 - Using the specific heat data of Table 6.8,...Ch. 6 - Prob. 6.78ECh. 6 - Prob. 6.79ECh. 6 - Liquid Freon (CCl2F2) is used as a refrigerant. It...Ch. 6 - Prob. 6.81ECh. 6 - What is the density of argon gas in g/mL at STP?Ch. 6 - Prob. 6.83ECh. 6 - Prob. 6.84ECh. 6 - Prob. 6.85ECh. 6 - Prob. 6.86ECh. 6 - Prob. 6.87ECh. 6 - Prob. 6.88ECh. 6 - Prob. 6.89ECh. 6 - Prob. 6.90ECh. 6 - Prob. 6.91ECh. 6 - Prob. 6.92ECh. 6 - Refer to Figure 6.12 and answer the question....Ch. 6 - Prob. 6.94ECh. 6 - Prob. 6.95ECh. 6 - Definite shape and definite volume best describes...Ch. 6 - Prob. 6.97ECh. 6 - Prob. 6.98ECh. 6 - Prob. 6.99ECh. 6 - Which of the following indicates the relative...Ch. 6 - Prob. 6.101ECh. 6 - Prob. 6.102ECh. 6 - What are the differentiating factors between...Ch. 6 - Prob. 6.104ECh. 6 - Prob. 6.105ECh. 6 - When a vapor condenses into a liquid: a.it absorbs...Ch. 6 - Prob. 6.107ECh. 6 - Prob. 6.108ECh. 6 - Prob. 6.109ECh. 6 - Prob. 6.110ECh. 6 - Prob. 6.111ECh. 6 - Prob. 6.112ECh. 6 - How much heat is required to raise the temperature...Ch. 6 - Prob. 6.115ECh. 6 - Prob. 6.116ECh. 6 - Prob. 6.117ECh. 6 - Prob. 6.118ECh. 6 - Prob. 6.119ECh. 6 - Prob. 6.120ECh. 6 - Prob. 6.121ECh. 6 - Prob. 6.122ECh. 6 - Prob. 6.123ECh. 6 - Prob. 6.124ECh. 6 - Prob. 6.125E
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