Chemistry
9th Edition
ISBN: 9781133611097
Author: Steven S. Zumdahl
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Textbook Question
Chapter 6, Problem 41E
One of the components of polluted air is NO. It is formed in the high-temperature environment of internal combustion engines by the following reaction:
Why are high temperatures needed to convert N2 and O2 to NO?
Expert Solution & Answer
Trending nowThis is a popular solution!
Chapter 6 Solutions
Chemistry
Ch. 6 - Define the following terms: potential energy,...Ch. 6 - Consider the following potential energy diagrams...Ch. 6 - What is the first law of thermodynamics? How can a...Ch. 6 - When a gas expands, what is the sign of w? Why?...Ch. 6 - What is the heat gained/released at constant...Ch. 6 - High-quality audio amplifiers generate large...Ch. 6 - Explain how calorimetry works to calculate H or E...Ch. 6 - What is Hesss law? When a reaction is reversed,...Ch. 6 - Define the standard enthalpy of formation. What...Ch. 6 - Objects placed together eventually reach the same...
Ch. 6 - What is meant by the term lower in energy? Which...Ch. 6 - A fire is started in a fireplace by striking a...Ch. 6 - Liquid water turns to ice. Is this process...Ch. 6 - Consider the following statements: ''Heat is a...Ch. 6 - Consider 5.5 L of a gas at a pressure of 3.0 atm...Ch. 6 - Consider 5.5 L of a gas at a pressure of 3.0 atm...Ch. 6 - What if energy was not conserved? How would this...Ch. 6 - Hesss law is really just another statement of the...Ch. 6 - In the equation w = P V, why is there a negative...Ch. 6 - Consider an airplane trip from Chicago, Illinois,...Ch. 6 - How is average bond strength related to relative...Ch. 6 - Assuming gasoline is pure C8H18(l), predict the...Ch. 6 - What is the difference between H and E?Ch. 6 - The enthalpy change for the reaction...Ch. 6 - For the reaction HgO(s)Hg(l)+12O2(g),H=+90.7kJ:...Ch. 6 - The enthalpy of combustion of CH4(g) when H2O(l)...Ch. 6 - The enthalpy change for a reaction is a state...Ch. 6 - Standard enthalpies of formation are relative...Ch. 6 - The combustion of methane can be represented as...Ch. 6 - Why is it a good idea to rinse your thermos bottle...Ch. 6 - Prob. 22QCh. 6 - What is incomplete combustion of fossil fuels? Why...Ch. 6 - Explain the advantages and disadvantages of...Ch. 6 - Prob. 25ECh. 6 - Which has the greater kinetic energy, an object...Ch. 6 - Consider the following diagram when answering the...Ch. 6 - A gas absorbs 45 kJ of heat and does 29 kJ of...Ch. 6 - A system releases 125 kJ of heal while 104 kJ of...Ch. 6 - Calculate E for each of the following. a. q = 47...Ch. 6 - A system undergoes a process consisting of the...Ch. 6 - If the internal energy of a thermodynamic system...Ch. 6 - Calculate the internal energy change for each of...Ch. 6 - A sample of an ideal gas at 15.0 atm and 10.0 L is...Ch. 6 - A piston performs work of 210. L atm on the...Ch. 6 - Consider a mixture of air and gasoline vapor in a...Ch. 6 - As a system increases in volume, it absorbs 52.5 J...Ch. 6 - A balloon filled with 39.1 moles of helium has a...Ch. 6 - One mole of H2O(g) at 1.00 atm and 100.C occupies...Ch. 6 - One of the components of polluted air is NO. It is...Ch. 6 - The reaction SO3(g)+H2O(l)H2SO4(aq) is the last...Ch. 6 - Are the following processes exothermic or...Ch. 6 - Are the following processes exothermic or...Ch. 6 - The overall reaction in a commercial heat pack can...Ch. 6 - Consider the following reaction:...Ch. 6 - Consider the combustion of propane:...Ch. 6 - Consider the following reaction:...Ch. 6 - For the process H2O(l) H2O(g) at 298 K and 1.0...Ch. 6 - For the following reactions at constant pressure,...Ch. 6 - Consider the substances in Table 7-1. Which...Ch. 6 - The specific heat capacity of silver is 0.24 J/Cg....Ch. 6 - A 500-g sample of one of the substances listed in...Ch. 6 - It takes 585 J of energy to raise the temperature...Ch. 6 - A 30.0-g sample of water at 280. K is mixed with...Ch. 6 - A biology experiment requires the preparation of a...Ch. 6 - A 5.00-g sample of aluminum pellets (specific heat...Ch. 6 - Hydrogen gives off 120. J/g of energy when burned...Ch. 6 - A 150.0-g sample of a metal at75.0C is added to...Ch. 6 - A 110.-g sample of copper (specific heat capacity...Ch. 6 - In a coffee-cup calorimeter, 50.0 mL of 0.100 M...Ch. 6 - In a coffee-cup calorimeter, 100.0 mL of 1.0 M...Ch. 6 - A coffee-cup calorimeter initially contains 125 g...Ch. 6 - In a coffee-cup calorimeter, 1.60 g NH4NO3 is...Ch. 6 - Consider the dissolution of CaCl2:...Ch. 6 - Consider the reaction...Ch. 6 - The heat capacity of a bomb calorimeter was...Ch. 6 - The combustion of 0.1584 g benzoic acid increases...Ch. 6 - The enthalpy of combustion of solid carbon to form...Ch. 6 - Combustion reactions involve reacting a substance...Ch. 6 - Given the following data calculate H for the...Ch. 6 - Prob. 72ECh. 6 - Given the following data 2O3(g) 3O2(g)H = 427 kJ...Ch. 6 - Calculate H for the reaction N2H4(l) + O2(g) ...Ch. 6 - Given the following data...Ch. 6 - Given the following data...Ch. 6 - Give the definition of the standard enthalpy of...Ch. 6 - Write reactions for which the enthalpy change will...Ch. 6 - Use the values ofHf in Appendix 4 to calculate H...Ch. 6 - Use the values of Hf in Appendix 4 to calculate H...Ch. 6 - The Ostwald process for the commercial production...Ch. 6 - Calculate H for each of the following reactions...Ch. 6 - The reusable booster rockets of the space shuttle...Ch. 6 - The space shuttle Orbiter utilizes the oxidation...Ch. 6 - Consider the reaction...Ch. 6 - The standard enthalpy of combustion of ethene gas,...Ch. 6 - Water gas is produced from the reaction of steam...Ch. 6 - Syngas can be burned directly or converted to...Ch. 6 - Ethanol (C2H5OH) has been proposed as an...Ch. 6 - Methanol (CH3OH) has also been proposed as an...Ch. 6 - Some automobiles and buses have been equipped to...Ch. 6 - Acetylene (C2H2) and butane (C4H10) are gaseous...Ch. 6 - Prob. 93ECh. 6 - The complete combustion of acetylene, C2H2(g),...Ch. 6 - It has been determined that the body can generate...Ch. 6 - One way to lose weight is to exercise! Walking...Ch. 6 - Three gas-phase reactions were run in a...Ch. 6 - Nitrogen gas reacts with hydrogen gas to form...Ch. 6 - Combustion of table sugar produces CO2(g) and H2O(...Ch. 6 - Prob. 100AECh. 6 - Consider the following cyclic process carried out...Ch. 6 - Calculate H for the reaction...Ch. 6 - The enthalpy of neutralization for the reaction of...Ch. 6 - Prob. 104AECh. 6 - If a student performs an endothermic reaction in a...Ch. 6 - In a bomb calorimeter, the reaction vessel is...Ch. 6 - The bomb calorimeter in Exercise 102 is filled...Ch. 6 - Consider the two space shuttle fuel reactions in...Ch. 6 - Consider the following equations:...Ch. 6 - Given the following data...Ch. 6 - At 298 K, the standard enthalpies of formation for...Ch. 6 - Using the following data, calculate the standard...Ch. 6 - A sample of nickel is heated to 99.8C and placed...Ch. 6 - Given: 2Cu2O(s) + O2(g) 4CuO(s)H = 288 kJ Cu2O(s)...Ch. 6 - Calculate H for each of the following reactions,...Ch. 6 - Consider a balloon filled with helium at the...Ch. 6 - In which of the following systems is(are) work...Ch. 6 - Which of the following processes are exothermic?...Ch. 6 - Consider the reaction...Ch. 6 - A swimming pool, 10.0 m by 4.0 m, is filled with...Ch. 6 - In a coffee-cup calorimeter, 150.0 mL of 0.50 M...Ch. 6 - Calculate H for the reaction...Ch. 6 - Which of the following substances have an enthalpy...Ch. 6 - Consider 2.00 moles of an ideal gas that are taken...Ch. 6 - For the process H2O(l)H2O(g) at 298 K and 1.0 atm,...Ch. 6 - The sun supplies energy at a rate of about 1.0...Ch. 6 - The best solar panels currently available are...Ch. 6 - On Easter Sunday, April 3, 1983, nitric acid...Ch. 6 - A piece of chocolate cake contains about 400...Ch. 6 - The standard enthalpies of formation for S(g),...Ch. 6 - You have a l.00-mole sample of water at 30.C and...Ch. 6 - A 500.0-g sample of an element at 195C is dropped...Ch. 6 - The preparation of NO2(g) from N2(g) and O2(g) is...Ch. 6 - Nitromethane, CH3NO2, can be used as a fuel. When...Ch. 6 - A cubic piece of uranium metal (specific heat...Ch. 6 - A gaseous hydrocarbon reacts completely with...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- The decomposition of ozone, O3, to oxygen, O2, is an exothermic reaction. What is the sign of q? If you were to touch a flask in which ozone is decomposing to oxygen, would you expect the flask to feel warm or cool?arrow_forwardA sample of sucrose, C12H22O11, is contaminated by sodium chloride. When the contaminated sample is burned in a bomb calorimeter, sodium chloride does not burn. What is the percentage of sucrose in the sample if a temperature increase of 1.67C is observed when 3.000 g of the sample are burned in the calorimeter? Sucrose gives off 5.64103kJ/mol when burned. The heat capacity of the calorimeter and water is 22.51 kJ/C.arrow_forwardGasohol, a mixture of gasoline and ethanol, C2H5OH, is used as automobile fuel. The alcohol releases energy in a combustion reaction with O2. C2H5OH(l)+3O2(g)2CO2(g)+3H2O(l) If 0.115 g ethanol evolves 3.62 kJ when burned at constant pressure, calculate the combustion enthalpy for ethanol.arrow_forward
- An industrial process for manufacturing sulfuric acid, H2SO4, uses hydrogen sulfide, H2S, from the purification of natural gas. In the first step of this process, the hydrogen sulfide is burned to obtain sulfur dioxide, SO2. 2H2S(g)+3O2(g)2H2O(l)+2SO2(g);H=1124kJ The density of sulfur dioxide at 25C and 1.00 atm is 2.62 g/L, and the molar heat capacity is 30.2 J/(mol C). (a) How much heat would be evolved in producing 1.00 L of SO2 at 25C and 1.00 atm? (b) Suppose heat from this reaction is used to heat 1.00 L of the SO2 from 25C to 500C for its use in the next step of the process. What percentage of the heat evolved is required for this?arrow_forwardExplain the difference between heat capacity and specific heat of a substance.arrow_forwardThe equation for the combustion of butane, C4H10, is C4H10(g)+132O2(g)4CO2(g)+5H2O(g) Which one of the following generates the least heat? Why? a Burning one mole of butane b Reacting one mole of oxygen with excess butane c Producing one mole of carbon dioxide by burning butane d Producing one mole of water by burning butanearrow_forward
- Nitric acid, HNO3, can be prepared by the following sequence of reactions: 4NH3(g)+5O2(g)4NO(g)+6H2O(g)2NO(g)+O2(g)2NO2(g)3NO2(g)+H2O(l)2HNO3(l)+NO(g) How much heat is evolved when 1 mol of NH3(g) is converted to HNO3(l)? Assume standard states at 25 C.arrow_forwardSulfur dioxide gas reacts with oxygen, O2(g), to produce SO3(g). This reaction releases 99.0 kJ of heat (at constant pressure) for each mole of sulfur dioxide that reacts. Write the thermochemical equation for the reaction of 2 mol of sulfur dioxide, and then also for the decomposition of 3 mol of sulfur trioxide gas into oxygen gas and sulfur dioxide gas. Do you need any other information to answer either question?arrow_forwardYou did an experiment in which you found that 59.8 J was required to raise the temperature of 25.0 g of ethylene glycol (a compound used as antifreeze in automobile engines) by 1.00 K. Calculate the specific heat capacity of ethylene glycol from these data.arrow_forward
- Ethylene glycol, HOCH2CH2OH, is used as antifreeze. It is produced from ethylene oxide, C2H4O, by the reaction C2H4O(g)+H2O(l)HOCH2CH2OH(l) Use Hesss law to obtain the enthalpy change for this reaction from the following enthalpy changes: 2C2H4O(g)+5O2(g)4CO2(g)+4H2O(l);H=2612.2kJHOCH2CH2OH(l)+52O2(g)2CO2(g)+3H2O(l);H=1189.8kJarrow_forwardWhen calcium carbonate, CaCO3 (the major constituent of limestone and seashells), is heated, it decomposes to calcium oxide (quicklime). CaCO3(s)CaO(s)+CO2(g);H=177.9kJ How much heat is required to decompose 21.3 g of calcium carbonate?arrow_forwardThe temperature of the cooling water as it leaves the hot engine of an automobile is 240 F. After it passes through the radiator it has a temperature of 175 F. Calculate the amount of heat transferred from the engine to the surroundings by one gallon of water with a specific heat of 4.184 J/g oC.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage Learning
- General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage LearningChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry for Engineering Students
Chemistry
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Calorimetry Concept, Examples and Thermochemistry | How to Pass Chemistry; Author: Melissa Maribel;https://www.youtube.com/watch?v=nSh29lUGj00;License: Standard YouTube License, CC-BY