Chemistry in Context
Chemistry in Context
8th Edition
ISBN: 9780073522975
Author: American Chemical Society
Publisher: McGraw-Hill Education
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Chapter 6, Problem 18Q

(a)

Interpretation Introduction

Interpretation:

Percent of nitrogen in coal has to be calculated.

(b)

Interpretation Introduction

Interpretation:

Mass of nitrogen in form of NO that is produced when 3 tons of coal is burned has to be calculated.

(c)

Interpretation Introduction

Interpretation:

The amount of NO produced is more when 3 tons of coal is burned has to be explained.

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3. What starting material would you use to synthesize 3-hydroxypentanoic acid using a NaBH4 reduction?
1. Give stereochemical (Fischer projection) formulas for all (but no extras) the stereoisomers that could theoretically form during the reduction of a. the carbonyl group of 2-methyl-3--pentanone b. both carbonyl groups of 2,4-pentanedione (careful!) 2. Predict the products of the reduction of O=CCH2CH2CH2C=O with a. LiAlH4 b. NaBH4 CH3 OH
Which of the following compounds can be synthesized using one reaction from any alkene, as a major product? If it can be synthesized, propose a route, and you may use any other starting materials, reagents and solvents as needed. If you do not think that it can be synthesized as a major product from an alkene, explain in detail why.

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