(a) Interpretation: The chemical formula of chlorate ion is to be stated. Concept introduction: A polyatomic ion is referred to as a charged chemical species that possess one or more than one element attached with an oxygen atom. This type of anion is also called oxyanion. They are named by adding the suffix -ate. Some other oxyanions are named by adding the suffix -ite. Those oxyanions which are named by adding the suffix -ite have one oxygen atom less in their formula than the ions with the suffix -ate.

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Answer 1

Question

Chapter 6, Problem 14E

Interpretation Introduction

(a)

Interpretation:

The chemical formula of chlorate ion is to be stated.

Concept introduction:

A polyatomic ion is referred to as a charged chemical species that possess one or more than one element attached with an oxygen atom. This type of anion is also called oxyanion. They are named by adding the suffix -ate. Some other oxyanions are named by adding the suffix -ite. Those oxyanions which are named by adding the suffix -ite have one oxygen atom less in their formula than the ions with the suffix -ate.

Interpretation Introduction

(b)

Interpretation:

The chemical formula of perchlorate ion is to be stated.

Concept introduction:

A polyatomic ion is referred to as a charged chemical species that possess one or more than one element attached with an oxygen atom. This type of anion is also called oxyanion. They are named by adding the suffix -ate. Some other oxyanions are named by adding the suffix -ite. Those oxyanions which are named by adding the suffix -ite have one oxygen atom less in their formula than the ions with the suffix-ate.

Interpretation Introduction

(c)

Interpretation:

The chemical formula of permanganate ion is to be stated.

Concept introduction:

A polyatomic ion is referred to as a charged chemical species that possess one or more than one element attached with an oxygen atom. This type of anion is also called oxyanion. They are named by adding the suffix -ate. Some other oxyanions are named by adding the suffix -ite. Those oxyanions which are named by adding the suffix-ite have one oxygen atom less in their formula than the ions with the suffix-ate.

Interpretation Introduction

(d)

Interpretation:

The chemical formula of acetate ion is to be stated.

Concept introduction:

A polyatomic ion is reffered to as a charged chemical species that possess one or more than one element attached with an oxygen atom. This type of anion is also called oxyanion. They are named by adding the suffix -ate. Some other oxyanions are named by adding the suffix -ite. Those oxyanions which are named by adding the suffix-ite have one oxygen atom less in their formula than the ions with the suffix -ate.

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Q1: Answer the questions for the reaction below: ..!! Br OH a) Predict the product(s) of the reaction. b) Is the substrate optically active? Are the product(s) optically active as a mix? c) Draw the curved arrow mechanism for the reaction. d) What happens to the SN1 reaction rate in each of these instances: 1. Change the substrate to Br "CI 2. Change the substrate to 3. Change the solvent from 100% CH3CH2OH to 10% CH3CH2OH + 90% DMF 4. Increase the substrate concentration by 3-fold.

Experiment 27 hates & Mechanisms of Reations Method I visual Clock Reaction A. Concentration effects on reaction Rates Iodine Run [I] mol/L [S₂082] | Time mo/L (SCC) 0.04 54.7 Log 1/ Time Temp Log [ ] 13,20] (time) / [I] 199 20.06 23.0 30.04 0.04 0.04 80.0 22.8 45 40.02 0.04 79.0 21.6 50.08 0.03 51.0 22.4 60-080-02 95.0 23.4 7 0.08 0-01 1970 23.4 8 0.08 0.04 16.1 22.6

(15 pts) Consider the molecule B2H6. Generate a molecular orbital diagram but this time using a different approach that draws on your knowledge and ability to put concepts together. First use VSEPR or some other method to make sure you know the ground state structure of the molecule. Next, generate an MO diagram for BH2. Sketch the highest occupied and lowest unoccupied MOs of the BH2 fragment. These are called frontier orbitals. Now use these frontier orbitals as your basis set for producing LGO's for B2H6. Since the BH2 frontier orbitals become the LGOS, you will have to think about what is in the middle of the molecule and treat its basis as well. Do you arrive at the same qualitative MO diagram as is discussed in the book? Sketch the new highest occupied and lowest unoccupied MOs for the molecule (B2H6).

Answer 2

Question

Chapter 6, Problem 14E

Interpretation Introduction

(a)

Interpretation:

The chemical formula of chlorate ion is to be stated.

Concept introduction:

A polyatomic ion is referred to as a charged chemical species that possess one or more than one element attached with an oxygen atom. This type of anion is also called oxyanion. They are named by adding the suffix -ate. Some other oxyanions are named by adding the suffix -ite. Those oxyanions which are named by adding the suffix -ite have one oxygen atom less in their formula than the ions with the suffix -ate.

Interpretation Introduction

(b)

Interpretation:

The chemical formula of perchlorate ion is to be stated.

Concept introduction:

A polyatomic ion is referred to as a charged chemical species that possess one or more than one element attached with an oxygen atom. This type of anion is also called oxyanion. They are named by adding the suffix -ate. Some other oxyanions are named by adding the suffix -ite. Those oxyanions which are named by adding the suffix -ite have one oxygen atom less in their formula than the ions with the suffix-ate.

Interpretation Introduction

(c)

Interpretation:

The chemical formula of permanganate ion is to be stated.

Concept introduction:

A polyatomic ion is referred to as a charged chemical species that possess one or more than one element attached with an oxygen atom. This type of anion is also called oxyanion. They are named by adding the suffix -ate. Some other oxyanions are named by adding the suffix -ite. Those oxyanions which are named by adding the suffix-ite have one oxygen atom less in their formula than the ions with the suffix-ate.

Interpretation Introduction

(d)

Interpretation:

The chemical formula of acetate ion is to be stated.

Concept introduction:

A polyatomic ion is reffered to as a charged chemical species that possess one or more than one element attached with an oxygen atom. This type of anion is also called oxyanion. They are named by adding the suffix -ate. Some other oxyanions are named by adding the suffix -ite. Those oxyanions which are named by adding the suffix-ite have one oxygen atom less in their formula than the ions with the suffix -ate.

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Answer 3

Question

Chapter 6, Problem 14E

Interpretation Introduction

(a)

Interpretation:

The chemical formula of chlorate ion is to be stated.

Concept introduction:

A polyatomic ion is referred to as a charged chemical species that possess one or more than one element attached with an oxygen atom. This type of anion is also called oxyanion. They are named by adding the suffix -ate. Some other oxyanions are named by adding the suffix -ite. Those oxyanions which are named by adding the suffix -ite have one oxygen atom less in their formula than the ions with the suffix -ate.

Interpretation Introduction

(b)

Interpretation:

The chemical formula of perchlorate ion is to be stated.

Concept introduction:

A polyatomic ion is referred to as a charged chemical species that possess one or more than one element attached with an oxygen atom. This type of anion is also called oxyanion. They are named by adding the suffix -ate. Some other oxyanions are named by adding the suffix -ite. Those oxyanions which are named by adding the suffix -ite have one oxygen atom less in their formula than the ions with the suffix-ate.

Interpretation Introduction

(c)

Interpretation:

The chemical formula of permanganate ion is to be stated.

Concept introduction:

A polyatomic ion is referred to as a charged chemical species that possess one or more than one element attached with an oxygen atom. This type of anion is also called oxyanion. They are named by adding the suffix -ate. Some other oxyanions are named by adding the suffix -ite. Those oxyanions which are named by adding the suffix-ite have one oxygen atom less in their formula than the ions with the suffix-ate.

Interpretation Introduction

(d)

Interpretation:

The chemical formula of acetate ion is to be stated.

Concept introduction:

A polyatomic ion is reffered to as a charged chemical species that possess one or more than one element attached with an oxygen atom. This type of anion is also called oxyanion. They are named by adding the suffix -ate. Some other oxyanions are named by adding the suffix -ite. Those oxyanions which are named by adding the suffix-ite have one oxygen atom less in their formula than the ions with the suffix -ate.

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Answer 4

Question

Chapter 6, Problem 14E

Interpretation Introduction

(a)

Interpretation:

The chemical formula of chlorate ion is to be stated.

Concept introduction:

A polyatomic ion is referred to as a charged chemical species that possess one or more than one element attached with an oxygen atom. This type of anion is also called oxyanion. They are named by adding the suffix -ate. Some other oxyanions are named by adding the suffix -ite. Those oxyanions which are named by adding the suffix -ite have one oxygen atom less in their formula than the ions with the suffix -ate.

Interpretation Introduction

(b)

Interpretation:

The chemical formula of perchlorate ion is to be stated.

Concept introduction:

A polyatomic ion is referred to as a charged chemical species that possess one or more than one element attached with an oxygen atom. This type of anion is also called oxyanion. They are named by adding the suffix -ate. Some other oxyanions are named by adding the suffix -ite. Those oxyanions which are named by adding the suffix -ite have one oxygen atom less in their formula than the ions with the suffix-ate.

Interpretation Introduction

(c)

Interpretation:

The chemical formula of permanganate ion is to be stated.

Concept introduction:

A polyatomic ion is referred to as a charged chemical species that possess one or more than one element attached with an oxygen atom. This type of anion is also called oxyanion. They are named by adding the suffix -ate. Some other oxyanions are named by adding the suffix -ite. Those oxyanions which are named by adding the suffix-ite have one oxygen atom less in their formula than the ions with the suffix-ate.

Interpretation Introduction

(d)

Interpretation:

The chemical formula of acetate ion is to be stated.

Concept introduction:

A polyatomic ion is reffered to as a charged chemical species that possess one or more than one element attached with an oxygen atom. This type of anion is also called oxyanion. They are named by adding the suffix -ate. Some other oxyanions are named by adding the suffix -ite. Those oxyanions which are named by adding the suffix-ite have one oxygen atom less in their formula than the ions with the suffix -ate.

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Answer 5

Chapter 6, Problem 14E

Interpretation Introduction

(a)

Interpretation:

The chemical formula of chlorate ion is to be stated.

Concept introduction:

A polyatomic ion is referred to as a charged chemical species that possess one or more than one element attached with an oxygen atom. This type of anion is also called oxyanion. They are named by adding the suffix -ate. Some other oxyanions are named by adding the suffix -ite. Those oxyanions which are named by adding the suffix -ite have one oxygen atom less in their formula than the ions with the suffix -ate.

Interpretation Introduction

(b)

Interpretation:

The chemical formula of perchlorate ion is to be stated.

Concept introduction:

A polyatomic ion is referred to as a charged chemical species that possess one or more than one element attached with an oxygen atom. This type of anion is also called oxyanion. They are named by adding the suffix -ate. Some other oxyanions are named by adding the suffix -ite. Those oxyanions which are named by adding the suffix -ite have one oxygen atom less in their formula than the ions with the suffix-ate.

Interpretation Introduction

(c)

Interpretation:

The chemical formula of permanganate ion is to be stated.

Concept introduction:

A polyatomic ion is referred to as a charged chemical species that possess one or more than one element attached with an oxygen atom. This type of anion is also called oxyanion. They are named by adding the suffix -ate. Some other oxyanions are named by adding the suffix -ite. Those oxyanions which are named by adding the suffix-ite have one oxygen atom less in their formula than the ions with the suffix-ate.

Interpretation Introduction

(d)

Interpretation:

The chemical formula of acetate ion is to be stated.

Concept introduction:

A polyatomic ion is reffered to as a charged chemical species that possess one or more than one element attached with an oxygen atom. This type of anion is also called oxyanion. They are named by adding the suffix -ate. Some other oxyanions are named by adding the suffix -ite. Those oxyanions which are named by adding the suffix-ite have one oxygen atom less in their formula than the ions with the suffix -ate.

Answer 6

Chapter 6, Problem 14E

Interpretation Introduction

(a)

Interpretation:

The chemical formula of chlorate ion is to be stated.

Concept introduction:

A polyatomic ion is referred to as a charged chemical species that possess one or more than one element attached with an oxygen atom. This type of anion is also called oxyanion. They are named by adding the suffix -ate. Some other oxyanions are named by adding the suffix -ite. Those oxyanions which are named by adding the suffix -ite have one oxygen atom less in their formula than the ions with the suffix -ate.

Answer 7

Chapter 6, Problem 14E

Interpretation Introduction

(a)

Interpretation:

The chemical formula of chlorate ion is to be stated.

Concept introduction:

A polyatomic ion is referred to as a charged chemical species that possess one or more than one element attached with an oxygen atom. This type of anion is also called oxyanion. They are named by adding the suffix -ate. Some other oxyanions are named by adding the suffix -ite. Those oxyanions which are named by adding the suffix -ite have one oxygen atom less in their formula than the ions with the suffix -ate.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The chemical formula of perchlorate ion is to be stated.

Concept introduction:

A polyatomic ion is referred to as a charged chemical species that possess one or more than one element attached with an oxygen atom. This type of anion is also called oxyanion. They are named by adding the suffix -ate. Some other oxyanions are named by adding the suffix -ite. Those oxyanions which are named by adding the suffix -ite have one oxygen atom less in their formula than the ions with the suffix-ate.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The chemical formula of perchlorate ion is to be stated.

Concept introduction:

A polyatomic ion is referred to as a charged chemical species that possess one or more than one element attached with an oxygen atom. This type of anion is also called oxyanion. They are named by adding the suffix -ate. Some other oxyanions are named by adding the suffix -ite. Those oxyanions which are named by adding the suffix -ite have one oxygen atom less in their formula than the ions with the suffix-ate.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The chemical formula of permanganate ion is to be stated.

Concept introduction:

A polyatomic ion is referred to as a charged chemical species that possess one or more than one element attached with an oxygen atom. This type of anion is also called oxyanion. They are named by adding the suffix -ate. Some other oxyanions are named by adding the suffix -ite. Those oxyanions which are named by adding the suffix-ite have one oxygen atom less in their formula than the ions with the suffix-ate.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The chemical formula of permanganate ion is to be stated.

Concept introduction:

A polyatomic ion is referred to as a charged chemical species that possess one or more than one element attached with an oxygen atom. This type of anion is also called oxyanion. They are named by adding the suffix -ate. Some other oxyanions are named by adding the suffix -ite. Those oxyanions which are named by adding the suffix-ite have one oxygen atom less in their formula than the ions with the suffix-ate.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The chemical formula of acetate ion is to be stated.

Concept introduction:

A polyatomic ion is reffered to as a charged chemical species that possess one or more than one element attached with an oxygen atom. This type of anion is also called oxyanion. They are named by adding the suffix -ate. Some other oxyanions are named by adding the suffix -ite. Those oxyanions which are named by adding the suffix-ite have one oxygen atom less in their formula than the ions with the suffix -ate.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The chemical formula of acetate ion is to be stated.

Concept introduction:

A polyatomic ion is reffered to as a charged chemical species that possess one or more than one element attached with an oxygen atom. This type of anion is also called oxyanion. They are named by adding the suffix -ate. Some other oxyanions are named by adding the suffix -ite. Those oxyanions which are named by adding the suffix-ite have one oxygen atom less in their formula than the ions with the suffix -ate.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 6 - Prob. 1CE Ch. 6 - Prob. 2CE Ch. 6 - Prob. 3CE Ch. 6 - Prob. 4CE Ch. 6 - Prob. 5CE Ch. 6 - Prob. 6CE Ch. 6 - Prob. 7CE Ch. 6 - Prob. 8CE Ch. 6 - Prob. 9CE Ch. 6 - Prob. 10CE

Solution Summary: The author explains the chemical formula of chlorate ion, which is ClO_3-.

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Chapter 6 Solutions