Using the results from Analyzing and Solving Multi- Concept Problems in Section 6.6 and the Practice Exercise 6.14 just after it, determine the heat of reaction for the ionization of one mole of acetic acid in water. Consider the distribution of molecular kinetic energies shown in the following diagram for a gas at 25 °C : (a) Which point corresponds to the most frequently occurring (also called the most probable) molecular kinetic energy? (b) Which point corresponds to the average molecular kinetic energy? (c) If the temperature of the gas is raised to 50 °C , how will the height of the curve at B change? (d) If the temperature of the gas is raised to 50 °C , how will the height of the curve at A change? How will the maximum height of the curve change?
Using the results from Analyzing and Solving Multi- Concept Problems in Section 6.6 and the Practice Exercise 6.14 just after it, determine the heat of reaction for the ionization of one mole of acetic acid in water. Consider the distribution of molecular kinetic energies shown in the following diagram for a gas at 25 °C : (a) Which point corresponds to the most frequently occurring (also called the most probable) molecular kinetic energy? (b) Which point corresponds to the average molecular kinetic energy? (c) If the temperature of the gas is raised to 50 °C , how will the height of the curve at B change? (d) If the temperature of the gas is raised to 50 °C , how will the height of the curve at A change? How will the maximum height of the curve change?
Using the results from Analyzing and Solving Multi- Concept Problems in Section 6.6 and the Practice Exercise 6.14 just after it, determine the heat of reaction for the ionization of one mole of acetic acid in water.
Consider the distribution of molecular kinetic energies shown in the following diagram for a gas at
25 °C
:
(a) Which point corresponds to the most frequently occurring (also called the most probable) molecular kinetic energy?
(b) Which point corresponds to the average molecular kinetic energy?
(c) If the temperature of the gas is raised to
50 °C
, how will the height of the curve at B change?
(d) If the temperature of the gas is raised to
50 °C
, how will the height of the curve at A change? How will the maximum height of the curve change?
1.
For an unknown compound with a molecular formula of C8H100:
a.
What is the DU? (show your work)
b.
Solve the structure and assign each of the following spectra.
8
6
2
ō (ppm)
4
2
0
200
150
100
50
ō (ppm)
LOD
D
4000
3000
2000
1500
1000
500
HAVENUMBERI -11
16. The proton NMR spectral information shown in this problem is for a compound with formula
CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec-
tral results, including DEPT-135 and DEPT-90 results, are tabulated:
7
J
Normal Carbon
DEPT-135
DEPT-90
19 ppm
Positive
No peak
122
Positive
Positive
cus
и
124
Positive
Positive
126
Positive
Positive
128
No peak
No peak
4°
129
Positive
Positive
130
Positive
Positive
(144
No peak
No peak
148
No peak
No peak
150
Positive
Positive
してし
3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing
mechanism below, but make sure to draw the product of each proposed step (3 points).
+ En
CN
CN
Chemistry: An Introduction to General, Organic, and Biological Chemistry (13th Edition)
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