ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<
ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<
2nd Edition
ISBN: 9781118872925
Author: Klein
Publisher: JOHN WILEY+SONS INC.CUSTOM
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Chapter 5.4, Problem 18PTS
Interpretation Introduction

Interpretation:

To calculate the enantiomeric excess (ee) of given molecules.

Concept Introduction:

The enantiomeric excess (ee) is a measurement of purity for chiral substance. Further it is reflected the degree to which a sample containes one enantiomers in greater amounts than the other.

The optically pure solution containing 100% of the d-enantiomer and 0% of the l-enantiomer would have an enantiomeric excess of 100%.

To identify:  The given molecules enantiomeric excess (ee) should be identified.

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Consider this step in a radical reaction: Br N O hv What type of step is this? Check all that apply. Draw the products of the step on the right-hand side of the drawing area below. If more than one set of products is possible, draw any set. Also, draw the mechanism arrows on the left-hand side of the drawing area to show how this happens. O primary Otermination O initialization O electrophilic O none of the above × ☑
None
Can I get a drawing of what is happening with the orbitals (particularly the p orbital) on the O in the OH group?  Is the p orbital on the O involved in the ring resonance?  Why or why not?
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