The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry. Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected. Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

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Answer 1

Question

Chapter 5.2C, Problem 5.5P

(a)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(b)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(c)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(d)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(e)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(f)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(g)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(h)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

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(a 4 shows scanning electron microscope (SEM) images of extruded actions of packing bed for two capillary columns of different diameters, al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the same stationary phase, spherical particles with 1-um diameter. A) When the columns were prepared, the figure shows that the column with the larger diameter has more packing irregularities. Explain this observation. B) Predict what affect this should have on band broadening and discuss your prediction using the van Deemter terms. C) Does this figure support your explanations in application question 33? Explain why or why not and make any changes in your answers in light of this figure. Figure 4 SEM images of sections of packed columns for a) 750 and b) 30-um-i.d. capillary columns.³

fcrip = ↓ bandwidth Il temp 32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual components of the van Deemter equation and consequently, band broadening? Increase temperature Longer column Using a gas mobile phase instead of liquid Smaller particle stationary phase Multiple Paths Diffusion Mass Transfer

34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.). A) Predict whether decreasing the column inner diameters increase or decrease bandwidth. B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or decreasing bandwidth as a function of i.d. and justify your answer. Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles. 35 20 H(um) 큰 20 15 90 0+ 1500 100 75 550 01 02 594 05 μ(cm/sec) 30 15 10

Answer 2

Question

Chapter 5.2C, Problem 5.5P

(a)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(b)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(c)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(d)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(e)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(f)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(g)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(h)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

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Answer 3

Question

Chapter 5.2C, Problem 5.5P

(a)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(b)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(c)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(d)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(e)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(f)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(g)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(h)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

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Answer 4

Question

Chapter 5.2C, Problem 5.5P

(a)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(b)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(c)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(d)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(e)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(f)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(g)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(h)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

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Answer 5

Chapter 5.2C, Problem 5.5P

(a)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(b)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(c)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(d)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(e)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(f)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(g)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

(h)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

Answer 6

Chapter 5.2C, Problem 5.5P

(a)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

Answer 7

Chapter 5.2C, Problem 5.5P

(a)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

Answer 8

(b)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

Answer 9

(b)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

Answer 10

(c)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

Answer 11

(c)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

Answer 12

(d)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

Answer 13

(d)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

Answer 14

(e)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

Answer 15

(e)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

Answer 16

(f)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

Answer 17

(f)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

Answer 18

(g)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

Answer 19

(g)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

Answer 20

(h)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

Answer 21

(h)

Interpretation Introduction

To determine: The plane of symmetry if the molecule has an internal plane of symmetry and if the structure is chiral on absence of plane of symmetry.

Interpretation: The validation of the statement that the given molecule contains a plane of symmetry is to be stated and on absence of plane of symmetry, the chirality of the molecule is to be detected.

Concept introduction: A carbon which has all the four different atoms or group of atoms show tetrahedral geometry is referred to as the chiral carbon. The mirror image of an object that contains chiral carbon has non-super imposable mirror image. The two different forms in which a single chiral carbon can exist is referred to as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centres.

Answer 22

Expert Solution & Answer

Answer 23

Expert Solution & Answer

Answer 24

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Answer 25

Ch. 5.2 - Determine whether the following objects are chiral...Ch. 5.2A - Prob. 5.2P Ch. 5.2B - Prob. 5.3P Ch. 5.2B - Prob. 5.4P Ch. 5.2C - Prob. 5.5P Ch. 5.3 - Prob. 5.6P Ch. 5.3 - Prob. 5.7P Ch. 5.4D - Prob. 5.8P Ch. 5.4D - Prob. 5.9P Ch. 5.4D - Prob. 5.10P

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