Concept explainers
Interpretation:
In a nonpolar covalent bond, the degree of inequality in sharing of electrons has to be chosen from the given options.
Concept Introduction:
Close relationship between ionic and covalent bonding models becomes apparent if the bond polarity and electronegativity is considered. Electronegativity is the measure of relative attractive for the shared pair of electrons in a bond. Higher the electronegative value for an atom, the more it attracts the shared pair of electrons towards itself.
In Periodic table, when moving from left to right in a period, the electronegativity value increases. While moving from top to bottom within group, the electronegativity value decreases. Nonmetals have higher electronegativity values than metals. Metals gives electrons and nonmetals accepts electrons.
Bond polarity is the degree of inequality in the electron pair sharing between two atoms in a
The ionic and covalent bonds can be identified by using the electronegativity difference between the atoms that are bonded together.
- Bonds that are formed between two similar electronegative atoms are known as nonpolar covalent bonds. The electronegativity difference has to be 0.4 or less.
- The bonds that have electronegativity difference greater than 0.4 and lesser than 1.5 are known as polar covalent bonds.
- If the electronegativity difference is more than 2.0, then the bond is considered to be ionic.
- If the electronegativity difference is between 1.5 to 2.0, then the bond can be ionic or covalent depending upon the type of atoms that is bonded. If the bond is between a metal and nonmetal, then it is ionic and if it is between two nonmetals then it is polar covalent.
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Chapter 5 Solutions
EBK GENERAL, ORGANIC, AND BIOLOGICAL CH
- Use the literature Ka value of the acetic acid, and the data below to answer these questions. Note: You will not use the experimental titration graphs to answer the questions that follow. Group #1: Buffer pH = 4.35 Group #2: Buffer pH = 4.70 Group #3: Buffer pH = 5.00 Group #4: Buffer pH = 5.30 Use the Henderson-Hasselbalch equation, the buffer pH provided and the literature pKa value of acetic acid to perform the following: a) calculate the ratios of [acetate]/[acetic acid] for each of the 4 groups buffer solutions above. b) using the calculated ratios, which group solution will provide the best optimal buffer (Hint: what [acetate]/[acetic acid] ratio value is expected for an optimal buffer?) c) explain your choicearrow_forwardHow would you prepare 1 liter of a 50 mM Phosphate buffer at pH 7.5 beginning with K3PO4 and 1 M HCl or 1 M NaOH? Please help and show calculations. Thank youarrow_forwardDraw the four most importantcontributing structures of the cation intermediate thatforms in the electrophilic chlorination of phenol,(C6H5OH) to form p-chlorophenol. Put a circle aroundthe best one. Can you please each step and also how you would approach a similar problem. Thank you!arrow_forward
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- General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage LearningOrganic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,
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