EBK CHEMISTRY: AN ATOMS FIRST APPROACH
2nd Edition
ISBN: 8220100552236
Author: ZUMDAHL
Publisher: CENGAGE L
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Chapter 5, Problem 9RQ
Consider the following mixture of SO2(g) and O2(g).
If SO2(g) and O2(g) react to form SO3(g), draw a representation of the product mixture assuming the reaction goes to completion. What is the limiting reactant in the reaction? If 96.0 g of SO2 react with 32.0 g O2, what mass o f product will form?
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10. Complete the substitution reaction of 2 pentanol with these reagents.
Reagents & Reaction Conditions use practice sheet. Please write only
major products, minor product like water, other gases are not
required.
Hint: In substitution of alcohol, we generally substitute OH group
with Halogens like cl, Br, F using some reagent containing
halogens. Ensure to add halogens to the same carbon number
where you are removing OH from
Examples
Alcohols can be converted to Alkyl Halides with HX acids
HBr
H₂O
HCI
+ H₂O
HI
+
H₂O
CH,CH₂OH + SOCI₂
CH,CH₂OH + PCI₁₂
A
BBYJU'S
CH CHCI + SO₂+ HCI
CH₂CH CIP(OH), + HCI
CH,CH₂OH + PCI CHCHCI + POCI + HCI
CH,CH₂OH + PBr, CH,CH,Br + P(OH), + HBr
1. Reaction with HBr with 2 Pentanol
2.Reaction with HI with 2 pentanol
© Byjus.com
3.Reaction with HCI+ZnCl,, with 2 pentanol (Zncl2 is catalyst no role)
4.Reaction with SOCI,, with 2 Pentanol
5.Reaction with PBr; or PCl, with 2 pentanol
3. Is 2-methyl-2-propanol a primary, secondary, or tertiary alcohol? Write
out the
structures of 2-methyl-2-propanol and also any oxidation products of 2-
methyl-2-
propanol. If there is more than one oxidation product, give the structure of
each
of the products.
4. 2-Propanol is the IUPAC systematic name of this alcohol. It has a
common name
by which it is much better known (You'll see it in the grocery store or
pharmacy).
Give that common name
5. Aldehydes can be synthesized by the oxidation of. Please choose from
below choices
A. Primary alcohols
B. Secondary alcohols
C. Organic acids
D. Inorganic acids
6. Tertiary alcohol Can undergo oxidation. yes or no. ? If yes then answer the
product.
Finish the reactions
hand written please
Chapter 5 Solutions
EBK CHEMISTRY: AN ATOMS FIRST APPROACH
Ch. 5 - Prob. 1RQCh. 5 - Atomic masses are relative masses. What does this...Ch. 5 - The atomic mass of boron (B) is given in the...Ch. 5 - What three conversion factors and in what order...Ch. 5 - Fig. 5-5 illustrates a schematic diagram of a...Ch. 5 - What is the difference between the empirical and...Ch. 5 - Consider the hypothetical reaction between A2 and...Ch. 5 - Prob. 8RQCh. 5 - Consider the following mixture of SO2(g) and...Ch. 5 - Why is the actual yield of a reaction often less...
Ch. 5 - The following are actual student responses to the...Ch. 5 - What information do we get from a chemical...Ch. 5 - You are making cookies and are missing a key...Ch. 5 - Nitrogen gas (N2) and hydrogen gas (H2) react to...Ch. 5 - For the preceding question, which of the following...Ch. 5 - Prob. 6ALQCh. 5 - Prob. 7ALQCh. 5 - Consider an iron bar on a balance as shown. As the...Ch. 5 - You may have noticed that water sometimes drips...Ch. 5 - Prob. 10ALQCh. 5 - What is true about the chemical properties of the...Ch. 5 - Is there a difference between a homogeneous...Ch. 5 - Prob. 13ALQCh. 5 - The average mass of a carbon atom is 12.011....Ch. 5 - Can the subscripts in a chemical formula be...Ch. 5 - Consider the equation 2A + B . A2B. If you mix 1.0...Ch. 5 - According to the law of conservation of mass, mass...Ch. 5 - Which of the following pairs of compounds have the...Ch. 5 - Atoms of three different elements are represented...Ch. 5 - In chemistry, what is meant by the term mole? What...Ch. 5 - Which (if any) of the following is (are) true...Ch. 5 - Consider the equation 3A + B C + D. You react 4...Ch. 5 - Reference Section 5-2 to find the atomic masses of...Ch. 5 - Avogadros number, molar mass, and the chemical...Ch. 5 - If you had a mole of U.S. dollar bills and equally...Ch. 5 - Prob. 26QCh. 5 - Which of the following compounds have the same...Ch. 5 - Prob. 28QCh. 5 - How is the mass percent of elements in a compound...Ch. 5 - A balanced chemical equation contains a large...Ch. 5 - Prob. 31QCh. 5 - Hydrogen gas and oxygen gas react to form water,...Ch. 5 - What is the theoretical yield for a reaction, and...Ch. 5 - What does it mean to say a reactant is present in...Ch. 5 - Consider the following generic reaction: A2B2 + 2C...Ch. 5 - Consider the following generic reaction:...Ch. 5 - An element consists of 1.40% of an isotope with...Ch. 5 - An element X bas five major isotopes, which are...Ch. 5 - The element rhenium (Re) bas two naturally...Ch. 5 - Assume silicon has three major isotopes in nature...Ch. 5 - The element europium exists in nature as two...Ch. 5 - The element silver (Ag) has two naturally...Ch. 5 - The mass spectrum of bromine (Br2) consists of...Ch. 5 - The stable isotopes of iron arc 54Fe, 56Fe, 57Fe,...Ch. 5 - Calculate the mass of 500. atoms of iron (Fe).Ch. 5 - What number of Fe atoms and what amount (moles) of...Ch. 5 - Diamond is a natural form of pure carbon. What...Ch. 5 - A diamond contains 5.0 1021 atoms of carbon. What...Ch. 5 - Aluminum metal is produced by passing an electric...Ch. 5 - The Freons are a class of compounds containing...Ch. 5 - Calculate the molar mass of the following...Ch. 5 - Calculate the molar mass of the following...Ch. 5 - What amount (moles) of compound is present in 1.00...Ch. 5 - What amount (moles) of compound is present in 1.00...Ch. 5 - What mass of compound is present in 5.00 moles of...Ch. 5 - What mass of compound is present in 5.00 moles of...Ch. 5 - Prob. 57ECh. 5 - Prob. 58ECh. 5 - Prob. 59ECh. 5 - What number of molecules (or formula units) are...Ch. 5 - What number of atoms of nitrogen are present in...Ch. 5 - Prob. 62ECh. 5 - Freon- 12 (CCI2F2) is used as a refrigerant in air...Ch. 5 - Bauxite, the principal ore used in the production...Ch. 5 - What amount (moles) is represented by each of...Ch. 5 - What amount (moles) is represented by each of...Ch. 5 - What number of atoms of nitrogen are present in...Ch. 5 - Complete the following table.Ch. 5 - Ascorbic acid, or vitamin C (C6H8O6), is an...Ch. 5 - The molecular formula of acetylsalicylic acid...Ch. 5 - Chloral hydrate (C2H3Cl3O2) is a drug formerly...Ch. 5 - Dimethylnitrosamine, (CH3)2N2O , is a carcinogenic...Ch. 5 - Calculate the percent composition by mass of the...Ch. 5 - In 1987 the first substance to act as a...Ch. 5 - Prob. 75ECh. 5 - Arrange the following substances in order of...Ch. 5 - Fungal laccase, a blue protein found in...Ch. 5 - Hemoglobin is the protein that transports oxygen...Ch. 5 - Express the composition of each of the following...Ch. 5 - Considering your answer to Exercise 79, which type...Ch. 5 - Give the empirical formula for each of the...Ch. 5 - Determine the molecular formulas to which the...Ch. 5 - A compound that contains only carbon, hydrogen,...Ch. 5 - The most common form of nylon (nylon-6) is 63.68%...Ch. 5 - There are two binary compounds of mercury and...Ch. 5 - A sample of urea contains 1.121 g N, 0.161 g H,...Ch. 5 - Prob. 87ECh. 5 - Determine the molecular formula of a compound that...Ch. 5 - A compound contains 47.08% carbon, 6.59% hydrogen,...Ch. 5 - Maleic acid is an organic compound composed of...Ch. 5 - One of the components that make up common table...Ch. 5 - A compound contains only C, H, and N. 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Cr(s) + S8(s) ...Ch. 5 - Silicon is produced for the chemical and...Ch. 5 - Prob. 104ECh. 5 - Over the years, the thermite reaction has been...Ch. 5 - The reaction between potassium chlorate and red...Ch. 5 - The reusable booster rockets of the U.S. space...Ch. 5 - One of relatively few reactions that takes place...Ch. 5 - Elixirs such as Atka-Seltzer use the reaction of...Ch. 5 - Aspirin (C9H8O4) is synthesized by reacting...Ch. 5 - Bacterial digestion is an economical method of...Ch. 5 - Phosphorus can be prepared from calcium phosphate...Ch. 5 - Coke is an impure form of carbon that is often...Ch. 5 - The space shuttle environmental control system...Ch. 5 - Consider the reaction between NO(g) and O2(g)...Ch. 5 - Consider the following reaction:...Ch. 5 - Prob. 117ECh. 5 - Consider the following unbalanced equation:...Ch. 5 - Hydrogen peroxide is used as a cleansing agent in...Ch. 5 - Silver sulfadiazine bum-treating cream creates a...Ch. 5 - Hydrogen cyanide is produced industrially from the...Ch. 5 - Acrylonitrile C3H3N) is the starting material for...Ch. 5 - Prob. 123ECh. 5 - DDT, an insecticide harmful to fish, birds, and...Ch. 5 - Bornite (Cu3FeS3) is a copper ore used in the...Ch. 5 - Consider the following unbalanced reaction:...Ch. 5 - In using a mass spectrometer, a chemist sees a...Ch. 5 - Boron consists of two isotopes, 10B and 11B....Ch. 5 - A given sample of a xenon fluoride compound...Ch. 5 - Aspartame is an artificial sweetener that is 160...Ch. 5 - Anabolic steroids are performance enhancement...Ch. 5 - Many cereals are made with high moisture content...Ch. 5 - The compound adrenaline contains 56.79% C, 6.56%...Ch. 5 - Adipic acid is an organic compound composed of...Ch. 5 - Prob. 135AECh. 5 - Some bismuth tablets, a medication used to treat...Ch. 5 - The empirical formula of styrene is CH; the molar...Ch. 5 - Terephthalic acid is an important chemical used in...Ch. 5 - A sample of a hydrocarbon (a compound consisting...Ch. 5 - A binary compound between an unknown element E and...Ch. 5 - A 0.755-g sample of hydrated copper(II) sulfate...Ch. 5 - ABS plastic is a tough, hard plastic used in...Ch. 5 - Prob. 143AECh. 5 - Methane (CH4) is the main component of marsh gas....Ch. 5 - A potential fuel for rockets is a combination of...Ch. 5 - A 0.4230-g sample of impure sodium nitrate was...Ch. 5 - Prob. 147AECh. 5 - Commercial brass, an alloy of Zn and Cu, reacts...Ch. 5 - Prob. 149AECh. 5 - You have seven closed containers, each with equal...Ch. 5 - A substance X2Z has the composition (by mass) of...Ch. 5 - Consider samples of phosphine (PH3), water (H2O),...Ch. 5 - Calculate the number of moles for each compound in...Ch. 5 - Arrange the following substances in order of...Ch. 5 - Para-cresol, a substance used as a disinfectant...Ch. 5 - A compound with molar mass 180.1 g/mol has the...Ch. 5 - Prob. 157CWPCh. 5 - Consider the following unbalanced chemical...Ch. 5 - Sulfur dioxide gas reacts with sodium hydroxide to...Ch. 5 - Gallium arsenide, GaAs, has gained widespread use...Ch. 5 - Consider the following data for three binary...Ch. 5 - Natural rubidium has the average mass of 85.4678 u...Ch. 5 - A compound contains only carbon, hydrogen,...Ch. 5 - Nitric acid is produced commercially by the...Ch. 5 - When the supply of oxygen is limited, iron metal...Ch. 5 - A 9.780-g gaseous mixture contains ethane (C2H6)...Ch. 5 - Zinc and magnesium metal each reacts with...Ch. 5 - Prob. 168CPCh. 5 - Consider a gaseous binary compound with a molar...Ch. 5 - Prob. 170CPCh. 5 - Prob. 171CPCh. 5 - The aspirin substitute, acetaminophen (C8H9O2N),...Ch. 5 - An element X forms both a dichloride (XCl2) and a...Ch. 5 - Prob. 174CPCh. 5 - When aluminum metal is heated with an element from...Ch. 5 - Consider a mixture of potassium chloride and...Ch. 5 - Ammonia reacts with O2 to form either NO(g) or...Ch. 5 - You take 1.00 g of an aspirin tablet (a compound...Ch. 5 - With the advent of techniques such as scanning...Ch. 5 - Tetrodotoxin is a toxic chemical found in fugu...Ch. 5 - Prob. 181IPCh. 5 - Prob. 182IPCh. 5 - Prob. 183IPCh. 5 - A 2.077-g sample of an element, which has an...Ch. 5 - Consider the following balanced chemical equation:...
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