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OWLv2 for Moore/Stanitski's Chemistry: The Molecular Science, 5th Edition, [Instant Access], 1 term (6 months)
5th Edition
ISBN: 9781285460420
Author: John W. Moore; Conrad L. Stanitski
Publisher: Cengage Learning US
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Chapter 5, Problem 95QRT
Determine the lattice energy for LiCl(s) given these data: Sublimation enthalpy of Li, 161 kJ/mol; IE, for Li, 520 kJ/mol; BE of Cl2(g), 242 kJ/mol;
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Complete the following table. The only density needed is already given. Show your
calculations in a neat and easy-to-follow manner in the space below the table. All units
should be included and significant figures should be given close attention. Be sure to notice
that the amount of material should be in millimoles rather than moles, and the theoretical
mass of the product should in milligrams rather than grams.
LOCH 3
+
H2SO4
HNO 3
O=C-OCH 3
NO2
x
H₂O
F.W.
4.0 mL 1.3 M
amount
0.50 mL
in H2SO4
mg Theoretical
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mmoles
density
1.09
Kumada Coupling:
1. m-Diisobutylbenzene below could hypothetically be synthesized by Friedel-Crafts reaction. Write out the reaction with a
mechanism and give two reasons why you would NOT get the desired product.
Draw the reaction (NOT a mechanism) for a Kumada coupling to produce the molecule above from m-dichlorobenzene.
Calculate the theoretical yield for the reaction in question 2 using 1.5 g of p-dichlorobenzene and 3.0 mL isobutyl bromide.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Wintergreen from Aspirin:
1. In isolating the salicylic acid, why is it important to press out as much of the water as possible?
2. Write the mechanism of the esterification reaction you did.
3.
What characteristic absorption band changes would you expect in the IR spectrum on going from aspirin to salicyclic acid and
then to methyl salicylate as you did in the experiment today? Give approximate wavenumbers associated with each functional
group change.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Chapter 5 Solutions
OWLv2 for Moore/Stanitski's Chemistry: The Molecular Science, 5th Edition, [Instant Access], 1 term (6 months)
Ch. 5.1 - In the upper atmosphere there is solar radiation...Ch. 5.1 - A fellow chemistry student says that low-frequency...Ch. 5.1 - One type of solar radiation in the upper...Ch. 5.2 - Prob. 5.2PSPCh. 5.2 - Prob. 5.3ECh. 5.3 - Prob. 5.4ECh. 5.3 - Prob. 5.3PSPCh. 5.3 - The hydrogen atom contains only one electron, but...Ch. 5.3 - (a) Calculate the frequency and the wavelength of...Ch. 5.3 - Show that the value of the Rydberg constant per...
Ch. 5.4 - Calculate the de Broglie wavelength of a neutron...Ch. 5.5 - Prob. 5.7ECh. 5.5 - Prob. 5.8ECh. 5.5 - Prob. 5.6PSPCh. 5.5 - Prob. 5.9ECh. 5.5 - Prob. 5.10CECh. 5.5 - Prob. 5.11ECh. 5.5 - Prob. 5.12ECh. 5.5 - Prob. 5.13CECh. 5.7 - Use atomic orbital box diagrams to determine which...Ch. 5.7 - Prob. 5.7PSPCh. 5.7 - Prob. 5.15ECh. 5.7 - Prob. 5.8PSPCh. 5.8 - (a) What Period 3 anion with a 2 charge has the...Ch. 5.8 - Prob. 5.10PSPCh. 5.8 - Fluoride ion, F, has no unpaired electrons....Ch. 5.9 - Prob. 5.11PSPCh. 5.10 - Which of these isoelectronic ions, Ba2+, Cs+, or...Ch. 5.11 - Prob. 5.13PSPCh. 5.13 - Consider these ionic compounds: KCl, CaS, CaO,...Ch. 5 - Prob. 1QRTCh. 5 - Prob. 2QRTCh. 5 - Prob. 3QRTCh. 5 - Prob. 4QRTCh. 5 - Prob. 5QRTCh. 5 - Prob. 6QRTCh. 5 - Prob. 7QRTCh. 5 - Prob. 8QRTCh. 5 -
Write the electron configurations for the valence...Ch. 5 - Prob. 10QRTCh. 5 - Prob. 11QRTCh. 5 - Prob. 12QRTCh. 5 - Prob. 13QRTCh. 5 - The colors of the visible spectrum and the...Ch. 5 - Prob. 15QRTCh. 5 - Prob. 16QRTCh. 5 - Prob. 17QRTCh. 5 - Prob. 18QRTCh. 5 - Prob. 19QRTCh. 5 - Light of very long wavelength strikes a...Ch. 5 - Prob. 21QRTCh. 5 - Prob. 22QRTCh. 5 - Prob. 23QRTCh. 5 - A photoemissive material has a threshold energy,...Ch. 5 - Prob. 25QRTCh. 5 - Prob. 26QRTCh. 5 - Prob. 27QRTCh. 5 - Prob. 28QRTCh. 5 - Prob. 29QRTCh. 5 - Prob. 30QRTCh. 5 - Prob. 31QRTCh. 5 - Calculate the energy and wavelength of the photon...Ch. 5 - Calculate the energy and the wavelength of the...Ch. 5 - Spectroscopists have observed He+ in outer space....Ch. 5 - Prob. 35QRTCh. 5 - Prob. 36QRTCh. 5 - Prob. 37QRTCh. 5 - Prob. 38QRTCh. 5 - Prob. 39QRTCh. 5 - Prob. 40QRTCh. 5 - Prob. 41QRTCh. 5 - Give possible values for all four quantum numbers...Ch. 5 - Prob. 43QRTCh. 5 - Assign a correct set of four quantum numbers for...Ch. 5 - Prob. 45QRTCh. 5 - Prob. 46QRTCh. 5 - Assign a correct set of four quantum numbers for...Ch. 5 - Prob. 48QRTCh. 5 - Prob. 49QRTCh. 5 - Prob. 50QRTCh. 5 - Prob. 51QRTCh. 5 - Prob. 52QRTCh. 5 - Prob. 53QRTCh. 5 - Titanium metal and Cr2+ have the same number of...Ch. 5 - Consider a 2+ ion that has six 3d electrons; which...Ch. 5 - Prob. 56QRTCh. 5 - Prob. 57QRTCh. 5 - Prob. 58QRTCh. 5 - Prob. 59QRTCh. 5 - Prob. 60QRTCh. 5 - Prob. 61QRTCh. 5 - Prob. 62QRTCh. 5 - Prob. 63QRTCh. 5 - Prob. 64QRTCh. 5 - Prob. 65QRTCh. 5 - Prob. 66QRTCh. 5 - Prob. 67QRTCh. 5 - Prob. 68QRTCh. 5 - Prob. 69QRTCh. 5 - Prob. 70QRTCh. 5 - Prob. 71QRTCh. 5 - Prob. 72QRTCh. 5 - Prob. 73QRTCh. 5 - Prob. 74QRTCh. 5 - Prob. 75QRTCh. 5 - Prob. 76QRTCh. 5 - Prob. 77QRTCh. 5 - Prob. 78QRTCh. 5 - Use electron configurations to explain why (a)...Ch. 5 - Prob. 80QRTCh. 5 - Arrange these elements in order of increasing...Ch. 5 - Prob. 82QRTCh. 5 - Arrange these elements in order of increasing...Ch. 5 - Prob. 84QRTCh. 5 - Prob. 85QRTCh. 5 - Prob. 86QRTCh. 5 - Prob. 87QRTCh. 5 - Prob. 88QRTCh. 5 - Prob. 89QRTCh. 5 - Compare the elements B, Al, C, Si. (a) Which has...Ch. 5 - Prob. 91QRTCh. 5 - Prob. 92QRTCh. 5 - Prob. 93QRTCh. 5 - Prob. 94QRTCh. 5 - Determine the lattice energy for LiCl(s) given...Ch. 5 - Prob. 96QRTCh. 5 - Prob. 97QRTCh. 5 - Prob. 98QRTCh. 5 - Prob. 99QRTCh. 5 - Prob. 100QRTCh. 5 - Prob. 101QRTCh. 5 - Prob. 102QRTCh. 5 - Prob. 103QRTCh. 5 - Prob. 104QRTCh. 5 - Prob. 105QRTCh. 5 - Prob. 106QRTCh. 5 - Prob. 107QRTCh. 5 - Prob. 108QRTCh. 5 - Prob. 109QRTCh. 5 - Prob. 113QRTCh. 5 - Prob. 114QRTCh. 5 - Prob. 115QRTCh. 5 - Prob. 116QRTCh. 5 - Prob. 117QRTCh. 5 - Prob. 119QRTCh. 5 - Prob. 120QRTCh. 5 - Prob. 121QRTCh. 5 - Prob. 123QRTCh. 5 - Prob. 124QRTCh. 5 - Prob. 125QRTCh. 5 - Prob. 126QRTCh. 5 - Prob. 127QRTCh. 5 - Prob. 128QRTCh. 5 - Prob. 129QRTCh. 5 - Calculate the effective nuclear charge, Z, on...Ch. 5 - Prob. 131QRTCh. 5 - Prob. 133QRTCh. 5 - Prob. 134QRTCh. 5 - Prob. 135QRTCh. 5 - According to a relationship developed by Niels...Ch. 5 - Prob. 137QRTCh. 5 - Prob. 138QRTCh. 5 - Prob. 139QRTCh. 5 - Prob. 140QRTCh. 5 - Prob. 141QRTCh. 5 - Prob. 142QRTCh. 5 - Prob. 143QRTCh. 5 - Prob. 144QRTCh. 5 - Prob. 5.ACPCh. 5 - Prob. 5.CCP
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