The atomic orbital for 4s and 3d electrons in manganese atom has to be given. Concept Introduction: Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

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Answer 1

Question

Chapter 5, Problem 63QRT

(a)

Interpretation Introduction

Interpretation:

The atomic orbital for 4s and 3d electrons in manganese atom has to be given.

Concept Introduction:

Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

(b)

Interpretation Introduction

Interpretation:

The atomic orbital for 4s and 3d electrons in manganese ion Mn+ has to be given.

Concept Introduction:

Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

(c)

Interpretation Introduction

Interpretation:

The atomic orbital for 4s and 3d electrons in manganese ion Mn5+ has to be given.

Concept Introduction:

Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

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Boron, atomic number 5, occurs naturally as two isotopes, 10B and 11B, with natural abundances of 19.9% and 80.1%, respectively.(a) In what ways do the two isotopes differ from each other? Does the electronic configuration of 10B differ from that of 11B? (b) Drawthe orbital diagram for an atom of 11B. Which electrons are the valence electrons? (c) Indicate three ways in which the 1s electrons inboron differ from its 2s electrons. (d) Elemental boron reacts with fluorine to form BF3, a gas. Write a balanced chemical equation forthe reaction of solid boron with fluorine gas. (e) ΔHf° for BF31g2 is -1135.6 kJ>mol. Calculate the standard enthalpy change in thereaction of boron with fluorine. (f) Will the mass percentage of F be the same in 10BF3 and 11BF3? If not, why is that the case?

Boron, atomic number 5, occurs naturally as two isotopes, 10B and 11B, with natural abundances of 19.9% and 80.1%, respectively. (a) In what ways do the two isotopes differ from each other? Does the electronic configuration of 10B differ from that of 11B? (b) Draw the orbital diagram for an atom of 11B. Which electrons are the valence electrons? (c) Indicate three ways in which the 1s electrons in boron differ from its 2s electrons. (d) Elemental boron reacts with fluorine to form BF3, a gas. Write a balanced chemical equation for the reaction of solid boron with fluorine gas. (e) ΔHf° for BF3(g) is -1135.6 kj/mol. Calculate the standard enthalpy change in the reaction of boron with fluorine. (f) Will the mass percentage of F be the same in 10BF3 and 11BF3? If not, why is that the case?

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Answer 2

Question

Chapter 5, Problem 63QRT

(a)

Interpretation Introduction

Interpretation:

The atomic orbital for 4s and 3d electrons in manganese atom has to be given.

Concept Introduction:

Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

(b)

Interpretation Introduction

Interpretation:

The atomic orbital for 4s and 3d electrons in manganese ion Mn+ has to be given.

Concept Introduction:

Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

(c)

Interpretation Introduction

Interpretation:

The atomic orbital for 4s and 3d electrons in manganese ion Mn5+ has to be given.

Concept Introduction:

Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

Expert Solution & Answer

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Answer 3

Question

Chapter 5, Problem 63QRT

(a)

Interpretation Introduction

Interpretation:

The atomic orbital for 4s and 3d electrons in manganese atom has to be given.

Concept Introduction:

Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

(b)

Interpretation Introduction

Interpretation:

The atomic orbital for 4s and 3d electrons in manganese ion Mn+ has to be given.

Concept Introduction:

Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

(c)

Interpretation Introduction

Interpretation:

The atomic orbital for 4s and 3d electrons in manganese ion Mn5+ has to be given.

Concept Introduction:

Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

Expert Solution & Answer

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Answer 4

Question

Chapter 5, Problem 63QRT

(a)

Interpretation Introduction

Interpretation:

The atomic orbital for 4s and 3d electrons in manganese atom has to be given.

Concept Introduction:

Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

(b)

Interpretation Introduction

Interpretation:

The atomic orbital for 4s and 3d electrons in manganese ion Mn+ has to be given.

Concept Introduction:

Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

(c)

Interpretation Introduction

Interpretation:

The atomic orbital for 4s and 3d electrons in manganese ion Mn5+ has to be given.

Concept Introduction:

Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

Expert Solution & Answer

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Answer 5

Chapter 5, Problem 63QRT

(a)

Interpretation Introduction

Interpretation:

The atomic orbital for 4s and 3d electrons in manganese atom has to be given.

Concept Introduction:

Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

(b)

Interpretation Introduction

Interpretation:

The atomic orbital for 4s and 3d electrons in manganese ion Mn+ has to be given.

Concept Introduction:

Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

(c)

Interpretation Introduction

Interpretation:

The atomic orbital for 4s and 3d electrons in manganese ion Mn5+ has to be given.

Concept Introduction:

Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

Answer 6

Chapter 5, Problem 63QRT

(a)

Interpretation Introduction

Interpretation:

The atomic orbital for 4s and 3d electrons in manganese atom has to be given.

Concept Introduction:

Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

Answer 7

Chapter 5, Problem 63QRT

(a)

Interpretation Introduction

Interpretation:

The atomic orbital for 4s and 3d electrons in manganese atom has to be given.

Concept Introduction:

Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The atomic orbital for 4s and 3d electrons in manganese ion Mn+ has to be given.

Concept Introduction:

Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The atomic orbital for 4s and 3d electrons in manganese ion Mn+ has to be given.

Concept Introduction:

Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The atomic orbital for 4s and 3d electrons in manganese ion Mn5+ has to be given.

Concept Introduction:

Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The atomic orbital for 4s and 3d electrons in manganese ion Mn5+ has to be given.

Concept Introduction:

Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

Answer 12

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Answer 13

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Answer 14

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Answer 15

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The atomic orbital for 4s and 3d electrons in manganese atom has to be given. Concept Introduction: Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

Solution Summary: The author explains Hund's rule: Each orbital must be singly occupied, all the electrons have same spin, and one electron is removed from outermost shell to become manganese ion.

Videos

Interpretation:

The atomic orbital for 4s and 3d electrons in manganese atom has to be given.

Concept Introduction:

Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

Interpretation:

The atomic orbital for 4s and 3d electrons in manganese ion Mn+ has to be given.

Concept Introduction:

Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

Interpretation:

The atomic orbital for 4s and 3d electrons in manganese ion Mn5+ has to be given.

Concept Introduction:

Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

Want to see the full answer?

Chapter 5 Solutions

The atomic orbital for 4s and 3d electrons in manganese atom has to be given. Concept Introduction: Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

Solution Summary: The author explains Hund's rule: Each orbital must be singly occupied, all the electrons have same spin, and one electron is removed from outermost shell to become manganese ion.

Videos

Interpretation: The atomic orbital for 4s and 3d electrons in manganese atom has to be given. Concept Introduction: Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

Interpretation: The atomic orbital for 4s and 3d electrons in manganese ion Mn+ has to be given. Concept Introduction: Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

Interpretation: The atomic orbital for 4s and 3d electrons in manganese ion Mn5+ has to be given. Concept Introduction: Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

Want to see the full answer?

Chapter 5 Solutions

Interpretation:

The atomic orbital for 4s and 3d electrons in manganese atom has to be given.

Concept Introduction:

Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

Interpretation:

The atomic orbital for 4s and 3d electrons in manganese ion Mn+ has to be given.

Concept Introduction:

Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.

Interpretation:

The atomic orbital for 4s and 3d electrons in manganese ion Mn5+ has to be given.

Concept Introduction:

Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.