Chemistry In Context
9th Edition
ISBN: 9781259638145
Author: Fahlman, Bradley D., Purvis-roberts, Kathleen, Kirk, John S., Bentley, Anne K., Daubenmire, Patrick L., ELLIS, Jamie P., Mury, Michael T., American Chemical Society
Publisher: Mcgraw-hill Education,
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Chapter 5, Problem 65Q
Tetraethyllead (TEL) has an octane rating of 270. How does this compare with other gasoline additives? Examine a structural formula for TEL and propose a reason for the value of its octane rating in comparison to other additives.
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
N2 (g) + 3H2 (g) = 2NH3 (g) AG⁰ = -34. KJ
Now suppose a reaction vessel is filled with 8.06 atm of nitrogen (N2) and 2.58 atm of ammonia (NH3) at 106. °C. Answer the following questions about this
system:
?
rise
Under these conditions, will the pressure of N2 tend to rise or fall?
☐ x10
fall
Is it possible to reverse this tendency by adding H₂?
In other words, if you said the pressure of N2 will tend to rise, can that be
changed to a tendency to fall by adding H₂? Similarly, if you said the
pressure of N2 will tend to fall, can that be changed to a tendency to rise
by adding H₂?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of H₂ needed to reverse it.
Round your answer to 2 significant digits.
yes
no
☐
atm
☑
5
00.
18
Ar
Chapter 5 Solutions
Chemistry In Context
Ch. 5.1 - Prob. 5.1YTCh. 5.1 - Prob. 5.2YTCh. 5.1 - Consult the interactive trends found in the...Ch. 5.1 - Prob. 5.4YTCh. 5.2 - For each of the fuels below, write the balanced...Ch. 5.2 - Prob. 5.6YTCh. 5.3 - Prob. 5.7YTCh. 5.4 - Prob. 5.8YTCh. 5.4 - Prob. 5.9YTCh. 5.4 - Scientific Practices Coal Versus Ethanol On the...
Ch. 5.5 - Prob. 5.12YTCh. 5.5 - Prob. 5.13YTCh. 5.6 - Although power plants require several steps to...Ch. 5.7 - Prob. 5.15YTCh. 5.7 - Prob. 5.16YTCh. 5.7 - An input of energy can be used to decrease entropy...Ch. 5.8 - Prob. 5.18YTCh. 5.8 - Prob. 5.19YTCh. 5.8 - Prob. 5.20YTCh. 5.8 - Prob. 5.21YTCh. 5.10 - Prob. 5.22YTCh. 5.11 - The combustion of one gram of natural gas releases...Ch. 5.11 - a. During the extraction of natural gas, the...Ch. 5.12 - Prob. 5.25YTCh. 5.13 - Prob. 5.26YTCh. 5.13 - Beginning in the 1920s, the octane-booster...Ch. 5.15 - Prob. 5.28YTCh. 5.15 - Prob. 5.29YTCh. 5.16 - Prob. 5.30YTCh. 5.17 - Have you ever been served cherries Jubilee or...Ch. 5.17 - Prob. 5.34YTCh. 5 - Prob. 1QCh. 5 - Prob. 2QCh. 5 - Prob. 3QCh. 5 - Energy exists in different forms in our natural...Ch. 5 - A coal-burning power plant generates electrical...Ch. 5 - Prob. 6QCh. 5 - Prob. 7QCh. 5 - Prob. 8QCh. 5 - Mercury (Hg) is present in trace amounts in coal,...Ch. 5 - Prob. 10QCh. 5 - Here are the condensed structural formulas for two...Ch. 5 - Prob. 12QCh. 5 - Prob. 13QCh. 5 - Consider these three hydrocarbons: At room...Ch. 5 - During petroleum distillation, kerosene and...Ch. 5 - Prob. 16QCh. 5 - a. Write the balanced chemical equation for the...Ch. 5 - Prob. 18QCh. 5 - Prob. 19QCh. 5 - State whether these processes are endothermic or...Ch. 5 - Use the bond energies in Table 5.1 to calculate...Ch. 5 - Use the bond energies in Table 5.1 to calculate...Ch. 5 - Ethanol can be produced by fermentation. Another...Ch. 5 - Here are structural formulas for ethane, ethene...Ch. 5 - These three compounds all have the same chemical...Ch. 5 - Catalysts speed up cracking reactions in oil...Ch. 5 - Explain why cracking is a necessary part of the...Ch. 5 - Consider this equation representing the process of...Ch. 5 - Prob. 29QCh. 5 - Consider these three alcohols: methanol, ethanol,...Ch. 5 - Prob. 31QCh. 5 - Prob. 32QCh. 5 - Prob. 33QCh. 5 - Compare and contrast a molecule of biodiesel with...Ch. 5 - Use Figure 5.6 to compare the energy released for...Ch. 5 - Prob. 36QCh. 5 - The sustainability of burning coal (and other...Ch. 5 - In this chapter, we approximated the chemical...Ch. 5 - Prob. 39QCh. 5 - Compare the processes of combustion and...Ch. 5 - How might you explain the difference between...Ch. 5 - Write a response to this statement: Because of the...Ch. 5 - The concept of entropy and probability is used in...Ch. 5 - Bond energies such as those in Table 5.1 are...Ch. 5 - Use the bond energies in Table 5.1 to explain why...Ch. 5 - Prob. 46QCh. 5 - Prob. 47QCh. 5 - Prob. 48QCh. 5 - Prob. 49QCh. 5 - Prob. 50QCh. 5 - Prob. 51QCh. 5 - Prob. 52QCh. 5 - Prob. 53QCh. 5 - Use a diagram to show the relationship among these...Ch. 5 - On a timescale of a few years, the combustion of...Ch. 5 - Emissions of some pollutants are lower when...Ch. 5 - Although coal contains only trace amounts of...Ch. 5 - Prob. 58QCh. 5 - An article in Scientific American pointed out that...Ch. 5 - C. P. Snow, a noted scientist and author, wrote an...Ch. 5 - Chemical explosions are very exothermic reactions....Ch. 5 - Prob. 63QCh. 5 - Tetraethyllead (TEL) was first approved for use in...Ch. 5 - Tetraethyllead (TEL) has an octane rating of 270....Ch. 5 - Another type of catalyst used in the combustion of...Ch. 5 - Figure 5.8 shows energy differences for the...Ch. 5 - Prob. 68Q
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- i need help with the followingarrow_forwardUsing reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NO(g) +Cl₂ (g) = 2NOC1 (g) AGº = -41. kJ Now suppose a reaction vessel is filled with 8.90 atm of chlorine (C12) and 5.71 atm of nitrosyl chloride (NOC1) at 1075. °C. Answer the following questions about this system: rise Under these conditions, will the pressure of NOCI tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of NOCI will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of NOCI will tend to fall, can that be changed to a tendency to rise by adding NO? yes no If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. Round your answer to 2 significant digits. atm ☑ 18 Ararrow_forwardIdentifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HCN is a weak acid. acids: 0.29 mol of NaOH is added to 1.0 L of a 1.2M HCN solution. bases: ☑ other: 0.09 mol of HCl is added to acids: 1.0 L of a solution that is bases: 0.3M in both HCN and KCN. other: 0,0,... ? 00. 18 Ar 日arrow_forward
- Identifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HF is a weak acid. acids: 0.2 mol of KOH is added to 1.0 L of a 0.5 M HF solution. bases: Х other: ☐ acids: 0.10 mol of HI is added to 1.0 L of a solution that is 1.4M in both HF and NaF. bases: other: ☐ 0,0,... ด ? 18 Ararrow_forwardIdentifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that NH3 is a weak base. acids: ☐ 1.8 mol of HCl is added to 1.0 L of a 1.0M NH3 bases: ☐ solution. other: ☐ 0.18 mol of HNO3 is added to 1.0 L of a solution that is 1.4M in both NH3 and NH₁Br. acids: bases: ☐ other: ☐ 0,0,... ? 000 18 Ar B 1arrow_forwardUsing reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NH3 (g) = N2 (g) +3H₂ —N2 (g) AGº = 34. kJ Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this system: rise Under these conditions, will the pressure of NH 3 tend to rise or fall? ☐ x10 fall Х Is it possible to reverse this tendency by adding H₂? In other words, if you said the pressure of NH 3 will tend to rise, can that be changed to a tendency to fall by adding H₂? Similarly, if you said the pressure of NH3 will tend to fall, can that be changed to a tendency to rise by adding H₂? If you said the tendency can be reversed in the second question, calculate the minimum pressure of H₂ needed to reverse it. Round your answer to 2 significant digits. yes no atm 00. 18 Ar 무ㅎ ?arrow_forward
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- Identifying the major species in weak acid or weak base equilibria Your answer is incorrect. • Row 2: Your answer is incorrect. • Row 3: Your answer is incorrect. • Row 6: Your answer is incorrect. 0/5 The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HF is a weak acid. acids: HF 0.1 mol of NaOH is added to 1.0 L of a 0.7M HF solution. bases: 0.13 mol of HCl is added to 1.0 L of a solution that is 1.0M in both HF and KF. Exponent other: F acids: HF bases: F other: K 1 0,0,... ? 000 18 Ararrow_forwardUsing reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NOCI (g) 2NO (g) + Cl2 (g) AGº =41. kJ Now suppose a reaction vessel is filled with 4.50 atm of nitrosyl chloride (NOCI) and 6.38 atm of chlorine (C12) at 212. °C. Answer the following questions about this system: ? rise Under these conditions, will the pressure of NOCI tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of NOCI will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of NOCI will tend to fall, can that be changed to a tendency to rise by adding NO? yes no If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. Round your answer to 2 significant digits. 0.035 atm ✓ G 00. 18 Ararrow_forwardHighlight each glycosidic bond in the molecule below. Then answer the questions in the table under the drawing area. HO- HO- -0 OH OH HO NG HO- HO- OH OH OH OH NG OHarrow_forward
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