
Chemistry In Context
9th Edition
ISBN: 9781259638145
Author: Fahlman, Bradley D., Purvis-roberts, Kathleen, Kirk, John S., Bentley, Anne K., Daubenmire, Patrick L., ELLIS, Jamie P., Mury, Michael T., American Chemical Society
Publisher: Mcgraw-hill Education,
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Question
Chapter 5.3, Problem 5.7YT
(a)
Interpretation Introduction
Interpretation:
For the given reaction, whether the reactants or products have more potential energy has to be decided.
(b)
Interpretation Introduction
Interpretation:
For the given reaction, whether the reactants or products have more potential energy has to be decided.
(c)
Interpretation Introduction
Interpretation:
For the given reaction, whether the reactants or products have more potential energy has to be decided.
(d)
Interpretation Introduction
Interpretation:
For the given reaction, whether the reactants or products have more potential energy has to be decided.
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(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 5 Solutions
Chemistry In Context
Ch. 5.1 - Prob. 5.1YTCh. 5.1 - Prob. 5.2YTCh. 5.1 - Consult the interactive trends found in the...Ch. 5.1 - Prob. 5.4YTCh. 5.2 - For each of the fuels below, write the balanced...Ch. 5.2 - Prob. 5.6YTCh. 5.3 - Prob. 5.7YTCh. 5.4 - Prob. 5.8YTCh. 5.4 - Prob. 5.9YTCh. 5.4 - Scientific Practices Coal Versus Ethanol On the...
Ch. 5.5 - Prob. 5.12YTCh. 5.5 - Prob. 5.13YTCh. 5.6 - Although power plants require several steps to...Ch. 5.7 - Prob. 5.15YTCh. 5.7 - Prob. 5.16YTCh. 5.7 - An input of energy can be used to decrease entropy...Ch. 5.8 - Prob. 5.18YTCh. 5.8 - Prob. 5.19YTCh. 5.8 - Prob. 5.20YTCh. 5.8 - Prob. 5.21YTCh. 5.10 - Prob. 5.22YTCh. 5.11 - The combustion of one gram of natural gas releases...Ch. 5.11 - a. During the extraction of natural gas, the...Ch. 5.12 - Prob. 5.25YTCh. 5.13 - Prob. 5.26YTCh. 5.13 - Beginning in the 1920s, the octane-booster...Ch. 5.15 - Prob. 5.28YTCh. 5.15 - Prob. 5.29YTCh. 5.16 - Prob. 5.30YTCh. 5.17 - Have you ever been served cherries Jubilee or...Ch. 5.17 - Prob. 5.34YTCh. 5 - Prob. 1QCh. 5 - Prob. 2QCh. 5 - Prob. 3QCh. 5 - Energy exists in different forms in our natural...Ch. 5 - A coal-burning power plant generates electrical...Ch. 5 - Prob. 6QCh. 5 - Prob. 7QCh. 5 - Prob. 8QCh. 5 - Mercury (Hg) is present in trace amounts in coal,...Ch. 5 - Prob. 10QCh. 5 - Here are the condensed structural formulas for two...Ch. 5 - Prob. 12QCh. 5 - Prob. 13QCh. 5 - Consider these three hydrocarbons: At room...Ch. 5 - During petroleum distillation, kerosene and...Ch. 5 - Prob. 16QCh. 5 - a. Write the balanced chemical equation for the...Ch. 5 - Prob. 18QCh. 5 - Prob. 19QCh. 5 - State whether these processes are endothermic or...Ch. 5 - Use the bond energies in Table 5.1 to calculate...Ch. 5 - Use the bond energies in Table 5.1 to calculate...Ch. 5 - Ethanol can be produced by fermentation. Another...Ch. 5 - Here are structural formulas for ethane, ethene...Ch. 5 - These three compounds all have the same chemical...Ch. 5 - Catalysts speed up cracking reactions in oil...Ch. 5 - Explain why cracking is a necessary part of the...Ch. 5 - Consider this equation representing the process of...Ch. 5 - Prob. 29QCh. 5 - Consider these three alcohols: methanol, ethanol,...Ch. 5 - Prob. 31QCh. 5 - Prob. 32QCh. 5 - Prob. 33QCh. 5 - Compare and contrast a molecule of biodiesel with...Ch. 5 - Use Figure 5.6 to compare the energy released for...Ch. 5 - Prob. 36QCh. 5 - The sustainability of burning coal (and other...Ch. 5 - In this chapter, we approximated the chemical...Ch. 5 - Prob. 39QCh. 5 - Compare the processes of combustion and...Ch. 5 - How might you explain the difference between...Ch. 5 - Write a response to this statement: Because of the...Ch. 5 - The concept of entropy and probability is used in...Ch. 5 - Bond energies such as those in Table 5.1 are...Ch. 5 - Use the bond energies in Table 5.1 to explain why...Ch. 5 - Prob. 46QCh. 5 - Prob. 47QCh. 5 - Prob. 48QCh. 5 - Prob. 49QCh. 5 - Prob. 50QCh. 5 - Prob. 51QCh. 5 - Prob. 52QCh. 5 - Prob. 53QCh. 5 - Use a diagram to show the relationship among these...Ch. 5 - On a timescale of a few years, the combustion of...Ch. 5 - Emissions of some pollutants are lower when...Ch. 5 - Although coal contains only trace amounts of...Ch. 5 - Prob. 58QCh. 5 - An article in Scientific American pointed out that...Ch. 5 - C. P. Snow, a noted scientist and author, wrote an...Ch. 5 - Chemical explosions are very exothermic reactions....Ch. 5 - Prob. 63QCh. 5 - Tetraethyllead (TEL) was first approved for use in...Ch. 5 - Tetraethyllead (TEL) has an octane rating of 270....Ch. 5 - Another type of catalyst used in the combustion of...Ch. 5 - Figure 5.8 shows energy differences for the...Ch. 5 - Prob. 68Q
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