Chemistry for Engineering Students
3rd Edition
ISBN: 9781285199023
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
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Textbook Question
Chapter 5, Problem 5CO
- perform stoichiometric ca1cu1uions for reactions involving gases as reactants or products.
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The human body burns glucose C6H12O6 for energy according to this chemical reaction:→+C6H12O66O2+6CO26H2O. The products of the reaction are carbon dioxide CO2 and water H2O. Interestingly, all of the carbon dioxide and much of the water exits the body through the lungs: on every breath, the average person exhales 500.mLof air, which is typically enriched to 4% CO2 and 5% water vapor by volume. In short, when a person loses weight by dieting, the weight that is lost actually departs his body as a gas, every time he exhales. Each kilogram of body fat lost requires exhaling about 3.0kg of carbon dioxide. Calculate how many breaths it takes an average person to "exhale" 2.00kg of fat. Round your answer to the nearest thousand. You'll need to know that the density of CO2 is 2.0/kgm3
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A steel cylinder contains 5.00 moles graphite (pure carbon) and 5.00 moles O2. The mixture is ignited and all the graphite reacts. Combustion
produces a mixture of CO gas and CO2 gas. After the cylinder has cooled to its original temperature, it is found that the pressure of the
cylinder has increased by 40.0%. Calculate the mole fractions of CO, CO2, and O2 in the final gaseous mixture.
Mole fraction of CO =
Mole fraction of CO2
Mole fraction of O2 =
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The average kinetic energy of the molecules in a gas sample depends only on the temperature, T. However, given the same
kinetic energies, a lighter molecule will move faster than a heavier molecule, as shown in the equation for rms speed
rms speed
rms speed:
=
where R = 8.314 J/(mol·K) and M is molar mass in kilograms per mole. Note that a joule is the same as a kilogram-meter
squared per second squared (kg-m²/s²).
What is the rms speed of Cl₂ molecules at 383 K?
3RT
M
rms speed:
What is the rms speed of He atoms at 383 K?
m/s
m/s
Chapter 5 Solutions
Chemistry for Engineering Students
Ch. 5 - Prob. 1COCh. 5 - Prob. 2COCh. 5 - Prob. 3COCh. 5 - Prob. 4COCh. 5 - perform stoichiometric ca1cu1uions for reactions...Ch. 5 - Prob. 6COCh. 5 - Prob. 7COCh. 5 - Prob. 8COCh. 5 - Prob. 9COCh. 5 - Prob. 10CO
Ch. 5 - Prob. 11COCh. 5 - List two types of chemical compounds that must be...Ch. 5 - When ozone levels in urban areas reach unhealthy...Ch. 5 - Prob. 5.3PAECh. 5 - Prob. 5.4PAECh. 5 - Asphalt is composed of a mixture of organic...Ch. 5 - Prob. 5.6PAECh. 5 - Prob. 5.7PAECh. 5 - Prob. 5.8PAECh. 5 - Prob. 5.9PAECh. 5 - Prob. 5.10PAECh. 5 - Prob. 5.11PAECh. 5 - 5.12 Water has a density that is 13.6 times less...Ch. 5 - 5.13 Water has a density that is 13.6 times less...Ch. 5 - Prob. 5.14PAECh. 5 - 5.15 Gas pressure can be expressed in units of mm...Ch. 5 - 5.16 If the atmospheric pressure is 97.4 kPa, how...Ch. 5 - Prob. 5.17PAECh. 5 - 5.18 When helium escapes from a balloon, the...Ch. 5 - 5.19 A sample of CO2 gas has a pressure of 56.5 mm...Ch. 5 - Prob. 5.20PAECh. 5 - Prob. 5.21PAECh. 5 - Prob. 5.22PAECh. 5 - Prob. 5.23PAECh. 5 - Prob. 5.24PAECh. 5 - Prob. 5.25PAECh. 5 - Prob. 5.26PAECh. 5 - 5.23 A gas bubble forms inside a vat containing a...Ch. 5 - 5.24 A bicycle tire is inflated to a pressure of...Ch. 5 - 5.25 A balloon filled with helium has a volume of...Ch. 5 - 5.26 How many moles of an ideal gas are there if...Ch. 5 - 5.27 A newly discovered gas has a density of 2.39...Ch. 5 - 5.28 Calculate the mass of each of the following...Ch. 5 - 5.29 What are the densities of the following gases...Ch. 5 - Prob. 5.34PAECh. 5 - 5.31 A cylinder is filled with toxic COS gas to a...Ch. 5 - 5.32 Cylinders of compressed gases are often...Ch. 5 - Prob. 5.37PAECh. 5 - 5.34 Define the term mole fractionCh. 5 - Prob. 5.39PAECh. 5 - 36 What is the total pressure exerted by a mixture...Ch. 5 - Prob. 5.41PAECh. 5 - 38 For a gas sample whose total pressure is 740...Ch. 5 - 39 A sample containing only NO2 and SO2, has a...Ch. 5 - Prob. 5.44PAECh. 5 - 41 A sample of a smokestack emission was collected...Ch. 5 - 42 Air is often dry air, ignoring the water mole...Ch. 5 - 43 In an experiment, a mixture of gases occupies a...Ch. 5 - Prob. 5.48PAECh. 5 - Prob. 5.49PAECh. 5 - Prob. 5.50PAECh. 5 - 47 HCl(g) reacts with ammonia gas, NH3(g), to form...Ch. 5 - 48 Hydrogen gas is generated when acids come into...Ch. 5 - Prob. 5.53PAECh. 5 - 50 The first step in processing zinc metal from...Ch. 5 - 51 What volume of oxygen at 24 C and 0.88 atm is...Ch. 5 - 52 If tetraborane, B4H10, is treated with pure...Ch. 5 - 53 N2O5is an unstable gas that decomposes...Ch. 5 - 54 One way to generate oxygen is to heat potassium...Ch. 5 - 55 Ammonia is not the only possible fertilizer....Ch. 5 - 56 Consider the following reaction:...Ch. 5 - 57 What volume of hydrogen gas, in liters, is...Ch. 5 - 58 Magnesium will burn in air to form both Mg3N2...Ch. 5 - 59 During a collision, automobile air bags are...Ch. 5 - 60 Automakers are always investigating reactions...Ch. 5 - 61 As one step in its purification, nickel metal...Ch. 5 - 62 Ammonium dinitramide (ADN), NH4N(NO2)2, was...Ch. 5 - Prob. 5.67PAECh. 5 - Prob. 5.68PAECh. 5 - Prob. 5.69PAECh. 5 - Prob. 5.70PAECh. 5 - Prob. 5.71PAECh. 5 - Prob. 5.72PAECh. 5 - Prob. 5.73PAECh. 5 - Prob. 5.74PAECh. 5 - Prob. 5.75PAECh. 5 - Prob. 5.76PAECh. 5 - Prob. 5.77PAECh. 5 - Prob. 5.78PAECh. 5 - Prob. 5.79PAECh. 5 - Prob. 5.80PAECh. 5 - Prob. 5.81PAECh. 5 - Prob. 5.82PAECh. 5 - Prob. 5.83PAECh. 5 - Prob. 5.84PAECh. 5 - Prob. 5.85PAECh. 5 - 88 Liquid oxygen for use as a rocket fuel can be...Ch. 5 - 89 A number of compounds containing the heavier...Ch. 5 - Prob. 5.88PAECh. 5 - 91 A 0.2500-g sample of an Al-Zn alloy reacts with...Ch. 5 - Prob. 5.90PAECh. 5 - 93 The complete combustion of octane can be used...Ch. 5 - 94 Mining engineers often have to deal with gases...Ch. 5 - 95 Some engineering designs call for the use of...Ch. 5 - Prob. 5.94PAECh. 5 - 97 Homes in rural areas where natural gas service...Ch. 5 - Prob. 5.96PAECh. 5 - 99 Pure gaseous nitrogen dioxide (NO2) cannot be...Ch. 5 - Prob. 5.98PAECh. 5 - Prob. 5.99PAECh. 5 - 102 A mixture of helium and neon gases has a...Ch. 5 - Prob. 5.101PAECh. 5 - Prob. 5.102PAECh. 5 - 105 The decomposition of mercury(II) thiocyanate...Ch. 5 - Prob. 5.104PAECh. 5 - 107 A soft drink can’s label indicates that the...Ch. 5 - Prob. 5.106PAECh. 5 - 109 An ore sample with a mass of 670 kg contains...Ch. 5 - Prob. 5.108PAECh. 5 - Prob. 5.109PAECh. 5 - Prob. 5.110PAECh. 5 - 111 Consider a room that is 14ft20ft wih an 8-ft...Ch. 5 - Prob. 5.112PAECh. 5 - 113 A 0.0125-g sample of a gas with an empirical...Ch. 5 - Prob. 5.114PAE
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Butane gas, C4H10, is sold to campers as bottled fuel. Its density at 25C and 1.00 atm is 2.38 g/L. What volume of butane gas at 25C and 1.00 atm is required to heat one gallon of water (d=1.00g/mL) from 25C to 98C ? The reaction for the combustion of butane (H f =125.6kJ/mol) is C4H10(g)+132 O2(g)4CO2(g)+5H2O(g)arrow_forwardDefine the joule in terms of SI base units.arrow_forwardUrea (H2NCONH2) is used extensively as a nitrogen source in fertilizers. It is produced commercially from the reaction of ammonia and carbon dioxide: 2NH3(g)+CO2(g)PressureHeatH2NCONH2(s)+H2O(g) Ammonia gas at 223C and 90. atm flows into a reactor at a rate of 500. L/min. Carbon dioxide at 223C and 45 atm flows into the reactor at a rate of 600. L/min. What mass of urea is produced per minute by this reaction assuming 100% yield?arrow_forward
- How does hydraulic fracturing differ from previously used techniques for the recovery of natural gas from the earth?arrow_forward62 Ammonium dinitramide (ADN), NH4N(NO2)2, was considered as a possible replacement for aluminium chloride as the oxidizer in the solid fuel booster rockets used to launch the space shuttle. When detonated by a spark, AND rapidly decomposes to produce a gaseous mixture of N2,O2, and H2O. (This is not a combustion reaction. The ADN is the only reactant.) The reaction releases a lot of heat, so the gases are initially formed at high temperature and pressure. The thrust of the rocket results mainly from the expansion of this gas mixture. Suppose a 2.3-kg sample of ADN is denoted and decomposes completely to give N2,O2, and H2O. If the resulting gas mixture expands until it reaches a temperature of 100°C and a pressure of 1.00 atm, what volume will it occupy? Is your answer consistent with the proposed use of ADN as a rocket fuel?arrow_forwardYou have a gas, one of the three known phosphorus-fluorine compounds (PF3, PF3, and P2F4). To find out which, you have decided to measure its molar mass. (a) First, yon determine that the density of the gas is 5.60 g/L at a pressure of 0.971 atm and a temperature of 18.2 C. Calculate the molar mass and identify the compound. (b) To check the results from part (a), you decide to measure the molar mass based on the relative rales of effusion of the unknown gas and CO2. You find that CO2 effuses at a rate of 0.050 mol/min, whereas the unknown phosphorus fluoride effuses at a rate of 0.028 mol/min. Calculate the molar mass of the unknown gas based on these results.arrow_forward
- Given that a sample of air is made up of nitrogen, oxygen, and argon in the mole fractions 0.78 N2, 0.21 O2, and 0.010 Ar, what is the density of air at standard temperature and pressure?arrow_forwardAt elevated temperatures, sodium chlorate decomposes to produce sodium chloride and oxygen gas. A 0.8765-g sample of impure sodium chlorate was heated until the production of oxygen gas ceased. The oxygen gas collected over water occupied 57.2 mL at a temperature of 22C and a pressure of 734 torr. Calculate the mass percent of NaClO3 in the original sample. (At 22C the vapor pressure of water is 19.8 torr.)arrow_forward5-37 A sample of a gas at 77°C and 1.33 atm occupies a volume of 50.3 L. (a) How many moles of the gas are present? (b) Does your answer depend on knowing what gas it is?arrow_forward
- Please answer completely. Thank youu!arrow_forwardThe methanation reaction, 3H2 + CO → CH4 + H2O, is used commercially to prepare methane. A gas reactor with a volume of 1.00 x 102 L is pressurized at 591 K with 24.6 bar of hydrogen gas and 11.2 bar of CO gas; 115 g of CH4 is produced. What is the percent yield of the synthesis?The percent yield = --------- %arrow_forwardQ6. (a)The vander waals equation is used to describe the behaviour of real gases but still not so useful in many industrial applications. Explain why?(3) (b)In kinetic molecular theory of gases it is assumed that The molecules of the gases occupy negligible volume as compared to the total volume of the gas' which factor can be actually described by this postulate?(2)arrow_forward
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