Chemistry for Engineering Students
3rd Edition
ISBN: 9781285199023
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
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Question
Chapter 5, Problem 5.37PAE
Interpretation Introduction
Interpretation:
The term partial pressure has to be defined.
Concept Introduction:
- An ideal gas has is a hypothetical gas that is formed by a few molecules so that, its density is low, and the intermolecular forces are null. The model of gas facilitates mathematical calculations to study gases.
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Indicate the processes in the dismutation of Cu2O.
1. Consider these three reactions as the elementary steps in the mechanism for a chemical reaction.
2600
2400
2200
2000
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1600
1400
1200
1000
800
Potential Energy (kJ)
600
400
200
0
-200-
-400
-600-
-800
(i) Cl₂ (g) + Pt(s) → 2Cl (g) + Pt(s)
(ii) Cl (g)+ CO (g) + Pt (s) → CICO (g) + Pt (s)
Ea = 1550 kJ
Ea = 2240 kJ
(iii) Cl (g) + CICO (g) → Cl₂CO (g)
Ea
= 2350 kJ
AH=-950 kJ
ΔΗ = 575 ΚΙ
AH=-825 kJ
a. Draw the potential energy diagram for the reaction. Label the data points for clarity.
The potential energy of the reactants is 600 kJ
Reaction Progress
b. What is the overall chemical equation?
c. What is the overall change in enthalpy for the above chemical reaction?
d. What is the overall amount of activation energy for the above chemical reaction?
e. Which reaction intermediate would be considered a catalyst (if any) and why?
f. If you were to add 2700kJ of energy to the reaction (e.g. 2700 kl of heat or electricity), would
you be able to make the reaction reverse itself (i.e. have…
draw the enolate anion and the carbonyl that would be needed to make this product through an aldol addition reaction.
Chapter 5 Solutions
Chemistry for Engineering Students
Ch. 5 - Prob. 1COCh. 5 - Prob. 2COCh. 5 - Prob. 3COCh. 5 - Prob. 4COCh. 5 - perform stoichiometric ca1cu1uions for reactions...Ch. 5 - Prob. 6COCh. 5 - Prob. 7COCh. 5 - Prob. 8COCh. 5 - Prob. 9COCh. 5 - Prob. 10CO
Ch. 5 - Prob. 11COCh. 5 - List two types of chemical compounds that must be...Ch. 5 - When ozone levels in urban areas reach unhealthy...Ch. 5 - Prob. 5.3PAECh. 5 - Prob. 5.4PAECh. 5 - Asphalt is composed of a mixture of organic...Ch. 5 - Prob. 5.6PAECh. 5 - Prob. 5.7PAECh. 5 - Prob. 5.8PAECh. 5 - Prob. 5.9PAECh. 5 - Prob. 5.10PAECh. 5 - Prob. 5.11PAECh. 5 - 5.12 Water has a density that is 13.6 times less...Ch. 5 - 5.13 Water has a density that is 13.6 times less...Ch. 5 - Prob. 5.14PAECh. 5 - 5.15 Gas pressure can be expressed in units of mm...Ch. 5 - 5.16 If the atmospheric pressure is 97.4 kPa, how...Ch. 5 - Prob. 5.17PAECh. 5 - 5.18 When helium escapes from a balloon, the...Ch. 5 - 5.19 A sample of CO2 gas has a pressure of 56.5 mm...Ch. 5 - Prob. 5.20PAECh. 5 - Prob. 5.21PAECh. 5 - Prob. 5.22PAECh. 5 - Prob. 5.23PAECh. 5 - Prob. 5.24PAECh. 5 - Prob. 5.25PAECh. 5 - Prob. 5.26PAECh. 5 - 5.23 A gas bubble forms inside a vat containing a...Ch. 5 - 5.24 A bicycle tire is inflated to a pressure of...Ch. 5 - 5.25 A balloon filled with helium has a volume of...Ch. 5 - 5.26 How many moles of an ideal gas are there if...Ch. 5 - 5.27 A newly discovered gas has a density of 2.39...Ch. 5 - 5.28 Calculate the mass of each of the following...Ch. 5 - 5.29 What are the densities of the following gases...Ch. 5 - Prob. 5.34PAECh. 5 - 5.31 A cylinder is filled with toxic COS gas to a...Ch. 5 - 5.32 Cylinders of compressed gases are often...Ch. 5 - Prob. 5.37PAECh. 5 - 5.34 Define the term mole fractionCh. 5 - Prob. 5.39PAECh. 5 - 36 What is the total pressure exerted by a mixture...Ch. 5 - Prob. 5.41PAECh. 5 - 38 For a gas sample whose total pressure is 740...Ch. 5 - 39 A sample containing only NO2 and SO2, has a...Ch. 5 - Prob. 5.44PAECh. 5 - 41 A sample of a smokestack emission was collected...Ch. 5 - 42 Air is often dry air, ignoring the water mole...Ch. 5 - 43 In an experiment, a mixture of gases occupies a...Ch. 5 - Prob. 5.48PAECh. 5 - Prob. 5.49PAECh. 5 - Prob. 5.50PAECh. 5 - 47 HCl(g) reacts with ammonia gas, NH3(g), to form...Ch. 5 - 48 Hydrogen gas is generated when acids come into...Ch. 5 - Prob. 5.53PAECh. 5 - 50 The first step in processing zinc metal from...Ch. 5 - 51 What volume of oxygen at 24 C and 0.88 atm is...Ch. 5 - 52 If tetraborane, B4H10, is treated with pure...Ch. 5 - 53 N2O5is an unstable gas that decomposes...Ch. 5 - 54 One way to generate oxygen is to heat potassium...Ch. 5 - 55 Ammonia is not the only possible fertilizer....Ch. 5 - 56 Consider the following reaction:...Ch. 5 - 57 What volume of hydrogen gas, in liters, is...Ch. 5 - 58 Magnesium will burn in air to form both Mg3N2...Ch. 5 - 59 During a collision, automobile air bags are...Ch. 5 - 60 Automakers are always investigating reactions...Ch. 5 - 61 As one step in its purification, nickel metal...Ch. 5 - 62 Ammonium dinitramide (ADN), NH4N(NO2)2, was...Ch. 5 - Prob. 5.67PAECh. 5 - Prob. 5.68PAECh. 5 - Prob. 5.69PAECh. 5 - Prob. 5.70PAECh. 5 - Prob. 5.71PAECh. 5 - Prob. 5.72PAECh. 5 - Prob. 5.73PAECh. 5 - Prob. 5.74PAECh. 5 - Prob. 5.75PAECh. 5 - Prob. 5.76PAECh. 5 - Prob. 5.77PAECh. 5 - Prob. 5.78PAECh. 5 - Prob. 5.79PAECh. 5 - Prob. 5.80PAECh. 5 - Prob. 5.81PAECh. 5 - Prob. 5.82PAECh. 5 - Prob. 5.83PAECh. 5 - Prob. 5.84PAECh. 5 - Prob. 5.85PAECh. 5 - 88 Liquid oxygen for use as a rocket fuel can be...Ch. 5 - 89 A number of compounds containing the heavier...Ch. 5 - Prob. 5.88PAECh. 5 - 91 A 0.2500-g sample of an Al-Zn alloy reacts with...Ch. 5 - Prob. 5.90PAECh. 5 - 93 The complete combustion of octane can be used...Ch. 5 - 94 Mining engineers often have to deal with gases...Ch. 5 - 95 Some engineering designs call for the use of...Ch. 5 - Prob. 5.94PAECh. 5 - 97 Homes in rural areas where natural gas service...Ch. 5 - Prob. 5.96PAECh. 5 - 99 Pure gaseous nitrogen dioxide (NO2) cannot be...Ch. 5 - Prob. 5.98PAECh. 5 - Prob. 5.99PAECh. 5 - 102 A mixture of helium and neon gases has a...Ch. 5 - Prob. 5.101PAECh. 5 - Prob. 5.102PAECh. 5 - 105 The decomposition of mercury(II) thiocyanate...Ch. 5 - Prob. 5.104PAECh. 5 - 107 A soft drink can’s label indicates that the...Ch. 5 - Prob. 5.106PAECh. 5 - 109 An ore sample with a mass of 670 kg contains...Ch. 5 - Prob. 5.108PAECh. 5 - Prob. 5.109PAECh. 5 - Prob. 5.110PAECh. 5 - 111 Consider a room that is 14ft20ft wih an 8-ft...Ch. 5 - Prob. 5.112PAECh. 5 - 113 A 0.0125-g sample of a gas with an empirical...Ch. 5 - Prob. 5.114PAE
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