Interpretation: The temperature-composition diagram of a mixture of octane and methylbenzene for the given data has to be drawn. The composition of vapor in equilibrium with the liquid of composition (i)
Concept introduction: The azeotropic mixture is defined as a mixture of two or more liquids which evaporates without altering the composition of the mixture. The azeotropic mixture has a constant boiling point because of the same composition in liquid as well as vapor phase. The components of azeotropic mixture are not separated by distillation processes.
The temperature-composition diagram represents the changes in the mixture on changing the temperature of the mixture.

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Chapter 5 Solutions
ATKINS' PHYSICAL CHEMISTRY
- What I Have Learned Directions: Given the following reaction and the stress applied in each reaction, answer the question below. A. H2(g) + Cl2(g) 2 HCl(g) Stress applied: Decreasing the pressure 1. What is the Keq expression? 2. What will be the effect in the number of moles of HCl(g)? 3. What will be the Equilibrium Shift or the reaction? B. Fe3O4(s) + 4 H2(g) + heat 53 Fe(s) + 4 H₂O(g) Stress applied: Increasing the temperature 1. What is the Keq expression?. 2. What will be the effect in the volume of water vapor collected? 3. What will be the Equilibrium Shift or the reaction? C. 4 NH3(g) + 5 O2(g) 4 NO(g) + 6 H2O(g) + heat Stress applied: Increasing the volume of the container 1. What is the Keq expression?. 2. What will be the effect in the amount of H₂O? 3. What will be the Equilibrium Shift or the reaction?arrow_forwardConsider the solubility products (Ksp values) for the following compounds:SrSO4 (Ksp = 7.6 x 10−7), BaSO4 (Ksp = 1.5 x 10−9), SrCO3 (Ksp = 7.0 x 10−10), BaCO3 (Ksp = 1.6 x 10−9)Which anion is the harder base, CO32− or SO42−? Justify your answer.arrow_forwardQ1: a) Arrange the compounds in order of decreasing pKa, highest first. ОН ΟΗ ῸΗ дон ОН ОН CI Brarrow_forward
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- d) Circle the substrates that will give an achiral product after a Grignard reaction with CH3MgBr. Harrow_forwardQ4: Predict the organic products for the following reactions. Then draw curved arrow electron- pushing mechanism for the reactions. a) NaBH4 EtOH Page 4 of 5 Chem 0310 Organic Chemistry 1 HW Problem Sets b) 요 1. Et₂O H MgBr 2. H+, H₂Oarrow_forward5Helparrow_forward
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