CHEM:ATOM FOC 2E CL (TEXT)
2nd Edition
ISBN: 9780393284218
Author: Stacey Lowery Bretz, Natalie Foster, Thomas R. Gilbert, Rein V. Kirss
Publisher: WW Norton & Co
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Chapter 5, Problem 5.68QA
Interpretation Introduction
To explain:
If the hybridization of all the nitrogen atoms in N4O is the same
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A 0.10 M solution of acetic acid (CH3COOH, Ka = 1.8 x 10^-5) is titrated with a 0.0250 M solution of magnesium hydroxide (Mg(OH)2). If 10.0 mL of the acid solution is titrated with 20.0 mL of the base solution, what is the pH of the resulting solution?
For the decomposition reaction of N2O5(g): 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed:
N2O5 NO2 + NO3 (K1) | NO2 + NO3 → N2O5 (k-1) | NO2 + NO3 NO2 + O2 + NO (k2) | NO + N2O51 NO2 + NO2 + NO2 (K3)
→
Give the expression for the acceptable rate.
→
→
(A).
d[N205]
dt
==
2k,k₂[N₂O₂]
k₁+k₁₂
(B).
d[N2O5]
=-k₁[N₂O] + k₁[NO₂] [NO3] - k₂[NO₂]³
dt
(C).
d[N2O5]
=-k₁[N₂O] + k [NO] - k₂[NO] [NO]
d[N2O5]
(D).
=
dt
= -k₁[N2O5] - k¸[NO][N₂05]
dt
Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard
the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction.
For the decomposition reaction of N2O5(g): 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed:
N2O5 NO2 + NO3 (K1) | NO2 + NO3 → N2O5 (k-1) | NO2 + NO3 NO2 + O2 + NO (k2) | NO + N2O51 NO2 + NO2 + NO2 (K3)
→
Give the expression for the acceptable rate.
→
→
(A).
d[N205]
dt
==
2k,k₂[N₂O₂]
k₁+k₁₂
(B).
d[N2O5]
=-k₁[N₂O] + k₁[NO₂] [NO3] - k₂[NO₂]³
dt
(C).
d[N2O5]
=-k₁[N₂O] + k [NO] - k₂[NO] [NO]
d[N2O5]
(D).
=
dt
= -k₁[N2O5] - k¸[NO][N₂05]
dt
Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard
the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction.
Chapter 5 Solutions
CHEM:ATOM FOC 2E CL (TEXT)
Ch. 5 - Prob. 5.1VPCh. 5 - Prob. 5.2VPCh. 5 - Prob. 5.3VPCh. 5 - Prob. 5.4VPCh. 5 - Prob. 5.5VPCh. 5 - Prob. 5.6VPCh. 5 - Prob. 5.7VPCh. 5 - Prob. 5.8VPCh. 5 - Prob. 5.9VPCh. 5 - Prob. 5.10VP
Ch. 5 - Prob. 5.11QACh. 5 - Prob. 5.12QACh. 5 - Prob. 5.13QACh. 5 - Prob. 5.14QACh. 5 - Prob. 5.15QACh. 5 - Prob. 5.16QACh. 5 - Prob. 5.17QACh. 5 - Prob. 5.18QACh. 5 - Prob. 5.19QACh. 5 - Prob. 5.20QACh. 5 - Prob. 5.21QACh. 5 - Prob. 5.22QACh. 5 - Prob. 5.23QACh. 5 - Prob. 5.24QACh. 5 - Prob. 5.25QACh. 5 - Prob. 5.26QACh. 5 - Prob. 5.27QACh. 5 - Prob. 5.28QACh. 5 - Prob. 5.29QACh. 5 - Prob. 5.30QACh. 5 - Prob. 5.31QACh. 5 - Prob. 5.32QACh. 5 - Prob. 5.33QACh. 5 - Prob. 5.34QACh. 5 - Prob. 5.35QACh. 5 - Prob. 5.36QACh. 5 - Prob. 5.37QACh. 5 - Prob. 5.38QACh. 5 - Prob. 5.39QACh. 5 - Prob. 5.40QACh. 5 - Prob. 5.41QACh. 5 - Prob. 5.42QACh. 5 - Prob. 5.43QACh. 5 - Prob. 5.44QACh. 5 - Prob. 5.45QACh. 5 - Prob. 5.46QACh. 5 - Prob. 5.47QACh. 5 - Prob. 5.48QACh. 5 - Prob. 5.49QACh. 5 - Prob. 5.50QACh. 5 - Prob. 5.51QACh. 5 - Prob. 5.52QACh. 5 - Prob. 5.53QACh. 5 - Prob. 5.54QACh. 5 - Prob. 5.55QACh. 5 - Prob. 5.56QACh. 5 - Prob. 5.57QACh. 5 - Prob. 5.58QACh. 5 - Prob. 5.59QACh. 5 - Prob. 5.60QACh. 5 - Prob. 5.61QACh. 5 - Prob. 5.62QACh. 5 - Prob. 5.63QACh. 5 - Prob. 5.64QACh. 5 - Prob. 5.65QACh. 5 - Prob. 5.66QACh. 5 - Prob. 5.67QACh. 5 - Prob. 5.68QACh. 5 - Prob. 5.69QACh. 5 - Prob. 5.70QACh. 5 - Prob. 5.71QACh. 5 - Prob. 5.72QACh. 5 - Prob. 5.73QACh. 5 - Prob. 5.74QACh. 5 - Prob. 5.75QACh. 5 - Prob. 5.76QACh. 5 - Prob. 5.77QACh. 5 - Prob. 5.78QACh. 5 - Prob. 5.79QACh. 5 - Prob. 5.80QACh. 5 - Prob. 5.81QACh. 5 - Prob. 5.82QACh. 5 - Prob. 5.83QACh. 5 - Prob. 5.84QACh. 5 - Prob. 5.85QACh. 5 - Prob. 5.86QACh. 5 - Prob. 5.87QACh. 5 - Prob. 5.88QACh. 5 - Prob. 5.89QACh. 5 - Prob. 5.90QACh. 5 - Prob. 5.91QACh. 5 - Prob. 5.92QACh. 5 - Prob. 5.93QACh. 5 - Prob. 5.94QACh. 5 - Prob. 5.95QACh. 5 - Prob. 5.96QACh. 5 - Prob. 5.97QACh. 5 - Prob. 5.98QACh. 5 - Prob. 5.99QACh. 5 - Prob. 5.100QACh. 5 - Prob. 5.101QACh. 5 - Prob. 5.102QACh. 5 - Prob. 5.103QACh. 5 - Prob. 5.104QACh. 5 - Prob. 5.105QACh. 5 - Prob. 5.106QACh. 5 - Prob. 5.107QACh. 5 - Prob. 5.108QACh. 5 - Prob. 5.109QACh. 5 - Prob. 5.110QACh. 5 - Prob. 5.111QACh. 5 - Prob. 5.112QACh. 5 - Prob. 5.113QACh. 5 - Prob. 5.114QACh. 5 - Prob. 5.115QACh. 5 - Prob. 5.116QACh. 5 - Prob. 5.117QACh. 5 - Prob. 5.118QACh. 5 - Prob. 5.119QACh. 5 - Prob. 5.120QACh. 5 - Prob. 5.121QACh. 5 - Prob. 5.122QACh. 5 - Prob. 5.123QACh. 5 - Prob. 5.124QACh. 5 - Prob. 5.125QACh. 5 - Prob. 5.126QACh. 5 - Prob. 5.127QACh. 5 - Prob. 5.128QACh. 5 - Prob. 5.129QACh. 5 - Prob. 5.130QACh. 5 - Prob. 5.131QACh. 5 - Prob. 5.132QACh. 5 - Prob. 5.133QACh. 5 - Prob. 5.134QACh. 5 - Prob. 5.135QACh. 5 - Prob. 5.136QACh. 5 - Prob. 5.137QACh. 5 - Prob. 5.138QACh. 5 - Prob. 5.139QACh. 5 - Prob. 5.140QA
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