CHEM:ATOM FOC 2E CL (TEXT)
2nd Edition
ISBN: 9780393284218
Author: Stacey Lowery Bretz, Natalie Foster, Thomas R. Gilbert, Rein V. Kirss
Publisher: WW Norton & Co
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Question
Chapter 5, Problem 5.119QA
Interpretation Introduction
To find:
Are either or both Cl-O-O-Cl and Cl-O-Cl-O molecules linear and do they have a permanent dipole?
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The reaction of what nucleophile and substrate is represented by the following transition
state?
CH3
CH3O
-Br
อ
δ
CH3
Methanol with 2-bromopropane
Methanol with 1-bromopropane
Methoxide with 1-bromopropane
Methoxide with 2-bromopropane
What is the stepwise mechanism for this reaction?
32. Consider a two-state system in which the low energy level is 300 J mol 1 and the higher energy
level is 800 J mol 1, and the temperature is 300 K. Find the population of each level. Hint: Pay attention
to your units.
A. What is the partition function for this system?
B. What are the populations of each level?
Now instead, consider a system with energy levels of 0 J mol
C. Now what is the partition function?
D. And what are the populations of the two levels?
E. Finally, repeat the second calculation at 500 K.
and 500 J mol 1 at 300 K.
F. What do you notice about the populations as you increase the temperature? At what temperature
would you expect the states to have equal populations?
Chapter 5 Solutions
CHEM:ATOM FOC 2E CL (TEXT)
Ch. 5 - Prob. 5.1VPCh. 5 - Prob. 5.2VPCh. 5 - Prob. 5.3VPCh. 5 - Prob. 5.4VPCh. 5 - Prob. 5.5VPCh. 5 - Prob. 5.6VPCh. 5 - Prob. 5.7VPCh. 5 - Prob. 5.8VPCh. 5 - Prob. 5.9VPCh. 5 - Prob. 5.10VP
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