EBK CHEMISTRY
4th Edition
ISBN: 8220102797864
Author: Burdge
Publisher: YUZU
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Textbook Question
Chapter 5, Problem 55QP
Each diagram shows a system before and after a chemical reaction along with the corresponding enthalpy of reaction. Determine the enthalpy of reaction for the last reaction represented.
The following diagrams depict three
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each pair of substrates below, choose the one that will react faster in a substitution reaction, assuming that:
1. the rate of substitution doesn't depend on nucleophile concentration and
2. the products are a roughly 50/50 mixture of enantiomers.
Substrate A
Substrate B
Faster Rate
X
Ś
CI
(Choose one)
(Choose one)
CI
Br
Explanation
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Br
(Choose one)
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
4.1 ppm? Select the single best answer.
The
H
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HỌC—C—0—CH, CH,
2
A
ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
Check
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B
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
Chapter 5 Solutions
EBK CHEMISTRY
Ch. 5.1 - Practice Problem ATTEMPT
(a) Calculate the energy...Ch. 5.1 - Practice Problem BUILD
(a) Calculate the velocity...Ch. 5.1 - Prob. 1PPCCh. 5.1 - Prob. 1CPCh. 5.1 - How much greater is the electrostatic potential...Ch. 5.1 - Prob. 3CPCh. 5.1 - 5.1.4 The label on packaged food indicates that it...Ch. 5.1 - 5.1.5 Arrange the following pairs of charged...Ch. 5.1 - Prob. 6CPCh. 5.2 - Practice Problem ATTEMPT
Calculate the change in...
Ch. 5.2 - Practice ProblemBUILD Calculate the magnitude of q...Ch. 5.2 - Prob. 1PPCCh. 5.2 - Calculate the overall change in internal energy...Ch. 5.2 - Calculate w, and determine whether work is done by...Ch. 5.2 - Prob. 3CPCh. 5.2 - Prob. 4CPCh. 5.3 - Prob. 1PPACh. 5.3 - Prob. 1PPBCh. 5.3 - Prob. 1PPCCh. 5.3 - Given the thermochemical equation: H 2 ( g ) + Br...Ch. 5.3 - Given the thermochemical equation: 2Cu 2 O ( s ) →...Ch. 5.4 - Prob. 1PPACh. 5.4 - Prob. 1PPBCh. 5.4 - Prob. 1PPCCh. 5.4 - Prob. 1CPCh. 5.4 - Prob. 2CPCh. 5.4 - Prob. 3CPCh. 5.4 - 5.4.4 Quantities of 50.0 mL of 1.00 M HCl and 50.0...Ch. 5.5 - Prob. 1PPACh. 5.5 - Prob. 1PPBCh. 5.5 - Prob. 1PPCCh. 5.5 - Prob. 1CPCh. 5.5 - Prob. 2CPCh. 5.5 - 5.5.3 Each diagram shows a systems before and...Ch. 5.5 - Prob. 4CPCh. 5.6 - Prob. 1PPACh. 5.6 - Prob. 1PPBCh. 5.6 - Prob. 1PPCCh. 5.6 - Prob. 1CPCh. 5.6 - Prob. 2CPCh. 5.6 - Prob. 3CPCh. 5.6 - Prob. 4CPCh. 5.7 - Prob. 1PPACh. 5.7 - Prob. 1PPBCh. 5.7 - Prob. 1PPCCh. 5.8 - Prob. 1PPACh. 5.8 - Prob. 1PPBCh. 5.8 - Practice ProblemCONCEPTUALIZE The diagrams...Ch. 5.9 - Practice ProblemATTEMPT Use the following data to...Ch. 5.9 - Prob. 1PPBCh. 5.9 - Prob. 1PPCCh. 5 - Using data from Appendix 2, calculate the standard...Ch. 5 - Prob. 2KSPCh. 5 - Prob. 3KSPCh. 5 - Using only whole-number coefficients, the...Ch. 5 - Prob. 1QPCh. 5 - Prob. 2QPCh. 5 - Prob. 3QPCh. 5 - 5.4 A truck initially trawling at 60 km/h is...Ch. 5 - These are various forms of energy: chemical, heat,...Ch. 5 - 5.6 Define these terms: thermochemistry,...Ch. 5 - 5.7 Stoichiometry is based on the law of...Ch. 5 - Prob. 8QPCh. 5 - Decomposition reactions are usually endothermic,...Ch. 5 - Prob. 10QPCh. 5 - Prob. 11QPCh. 5 - Prob. 12QPCh. 5 - Prob. 13QPCh. 5 - Prob. 14QPCh. 5 - Prob. 15QPCh. 5 - Prob. 16QPCh. 5 - Prob. 17QPCh. 5 - Use the following diagrams for Problems 5.17 and...Ch. 5 - Consider these changes. (a) Hg ( t ) → Hg ( g )...Ch. 5 - Prob. 20QPCh. 5 - Prob. 21QPCh. 5 - 5.22 Explain the meaning of this thermochemical...Ch. 5 - Consider this reaction: 2 CH 3 OH ( l ) + 3 O 2 (...Ch. 5 - Prob. 24QPCh. 5 - Prob. 25QPCh. 5 - Prob. 26QPCh. 5 - Prob. 27QPCh. 5 - Prob. 28QPCh. 5 - Prob. 29QPCh. 5 - Prob. 30QPCh. 5 - Prob. 31QPCh. 5 - For most biological processes, the changes in...Ch. 5 - Prob. 33QPCh. 5 - 5.34 Define calorimetry and describe two commonly...Ch. 5 - A 6.22-kg piece of copper metal is heated from 20...Ch. 5 - Prob. 36QPCh. 5 - Prob. 37QPCh. 5 - A 0.1375-g sample of solid magnesium is burned in...Ch. 5 - A quantity of 2 .00 × 10 2 mL of 0 .862 M HCl is...Ch. 5 - 5.40 A 50.75 g sample of water at is added to a...Ch. 5 - A 25.95-g sample of methanol at 35 .6°C is added...Ch. 5 - Prob. 42QPCh. 5 - Prob. 43QPCh. 5 - Consider the following data: Metal Al Cu Mass(g)...Ch. 5 - Prob. 45QPCh. 5 - Prob. 46QPCh. 5 - Prob. 47QPCh. 5 - Prob. 48QPCh. 5 - Prob. 49QPCh. 5 - Prob. 50QPCh. 5 - Prob. 51QPCh. 5 - Prob. 52QPCh. 5 - Prob. 53QPCh. 5 - Prob. 54QPCh. 5 - 5.55 Each diagram shows a system before and after...Ch. 5 - Prob. 56QPCh. 5 - 5.57 Determine the value of for the following...Ch. 5 - Prob. 58QPCh. 5 - Prob. 59QPCh. 5 - Prob. 60QPCh. 5 - Prob. 61QPCh. 5 - Prob. 62QPCh. 5 - Prob. 63QPCh. 5 - Prob. 64QPCh. 5 - Prob. 65QPCh. 5 - Prob. 66QPCh. 5 - Prob. 67QPCh. 5 - Prob. 68QPCh. 5 - Prob. 69QPCh. 5 - Prob. 70QPCh. 5 - Prob. 71QPCh. 5 - Prob. 72QPCh. 5 - Prob. 73QPCh. 5 - Prob. 74QPCh. 5 - Pentaborane - 9 ( B 5 H 9 ) is a colorless, highly...Ch. 5 - Prob. 76QPCh. 5 - Prob. 77QPCh. 5 - Prob. 78QPCh. 5 - Prob. 79QPCh. 5 - Prob. 80QPCh. 5 - Prob. 81APCh. 5 - Prob. 82APCh. 5 - Prob. 83APCh. 5 - Prob. 84APCh. 5 - Prob. 85APCh. 5 - Prob. 86APCh. 5 - Prob. 87APCh. 5 - Prob. 88APCh. 5 - Ethanol ( C 2 H 5 OH ) and gasoline (assumed to be...Ch. 5 - Prob. 90APCh. 5 - The heat of vaporization of a liquid ( Δ H vap )...Ch. 5 - Prob. 92APCh. 5 - Prob. 93APCh. 5 - Prob. 94APCh. 5 - Prob. 95APCh. 5 - Prob. 96APCh. 5 - 5.97 The enthalpy of combustion of benzoic add is...Ch. 5 - 5.98 At , the standard enthalpy of formation of...Ch. 5 - From the enthalpy of formation for CO, and the...Ch. 5 - In the nineteenth century, two scientists named...Ch. 5 - Prob. 101APCh. 5 - Prob. 102APCh. 5 - Prob. 103APCh. 5 - A quantity of 85 .0 mL of 0 .600 M HCl is mixed...Ch. 5 - Prob. 105APCh. 5 - Prob. 106APCh. 5 - A 4.117-g impure sample of glucose (C 4 H 12 O 6 )...Ch. 5 - Prob. 108APCh. 5 - In a constant-pressure calorimetry experiment, a...Ch. 5 - Prob. 110APCh. 5 - Give an example for each of the following...Ch. 5 - Prob. 112APCh. 5 - Prob. 113APCh. 5 - 5.114 A 3.52-g sample of ammonium nitrate was...Ch. 5 - 5.115 A quantity of is mixed with in a...Ch. 5 - Prob. 116APCh. 5 - Prob. 117APCh. 5 - Prob. 118APCh. 5 - Prob. 119APCh. 5 - Prob. 120APCh. 5 - 5.121 A gas company in Massachusetts charges 27...Ch. 5 - Prob. 122APCh. 5 - For reactions in condensed phases ( liquids and...Ch. 5 - Prob. 124APCh. 5 - Prob. 125APCh. 5 - The so-called hydrogen economy is based on...Ch. 5 - Prob. 127APCh. 5 - 5.128 Calculate the standard enthalpy change for...Ch. 5 - Prob. 129APCh. 5 - Prob. 130APCh. 5 - Why are cold, damp air and hot, humid air more...Ch. 5 - A woman expends 95 kJ of energy walking a...Ch. 5 - The carbon dioxide exhaled by sailors in a...Ch. 5 - Prob. 134APCh. 5 - Acetylene ( C 2 H 2 ) can be made by combining...Ch. 5 - (a) A person drinks four glasses of cold water ( 3...Ch. 5 - Both glucose and fructose are simple sugars with...Ch. 5 - Prob. 138APCh. 5 - Prob. 139APCh. 5 - Prob. 140APCh. 5 - Prob. 141APCh. 5 - Prob. 142APCh. 5 - 5.143 Hydrazine decomposes to form ammonia and...Ch. 5 - Prob. 144APCh. 5 - Prob. 145APCh. 5 - Prob. 1SEPPCh. 5 - What is the heat capacity ( C v ) of the...Ch. 5 - What is the energy content of the food? a) 22 .8...Ch. 5 - 4. What would be the effect on the result if the...
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(b)
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