Chemistry For Today: General, Organic, And Biochemistry, Loose-leaf Version
9th Edition
ISBN: 9781305968707
Author: Spencer L. Seager
Publisher: Brooks Cole
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Chapter 5, Problem 5.58E
Interpretation Introduction
Interpretation:
The percentage yield of the combination reaction is to be calculated.
Concept introduction:
The percentage yield is calculated by the formula,
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter 5 Solutions
Chemistry For Today: General, Organic, And Biochemistry, Loose-leaf Version
Ch. 5 - Identify the reactants and products in each of the...Ch. 5 - Identify the reactants and products in each of the...Ch. 5 - Prob. 5.3ECh. 5 - Identify which of the following are consistent...Ch. 5 - Prob. 5.5ECh. 5 - Determine the number of atoms of each element on...Ch. 5 - Balance the following equations: a....Ch. 5 - Balance the following equations: a....Ch. 5 - Assign oxidation numbers to the blue element in...Ch. 5 - Assign oxidation numbers to the blue element in...
Ch. 5 - Find the element with the highest oxidation number...Ch. 5 - Find the element with the highest oxidation number...Ch. 5 - For each of the following equations, indicate...Ch. 5 - For each of the following equations, indicate...Ch. 5 - Assign oxidation numbers to each element in the...Ch. 5 - Assign oxidation numbers to each element in the...Ch. 5 - The tarnish of silver objects is a coating of...Ch. 5 - Prob. 5.18ECh. 5 - Prob. 5.19ECh. 5 - Classify each of the reactions represented by the...Ch. 5 - Classify each of the reactions represented by the...Ch. 5 - Prob. 5.22ECh. 5 - Prob. 5.23ECh. 5 - Prob. 5.24ECh. 5 - Prob. 5.25ECh. 5 - Prob. 5.26ECh. 5 - Prob. 5.27ECh. 5 - Consider all of the following ionic compounds to...Ch. 5 - Consider all of the following ionic compounds to...Ch. 5 - Prob. 5.30ECh. 5 - Reactions represented by the following equations...Ch. 5 - Prob. 5.32ECh. 5 - Prob. 5.33ECh. 5 - Prob. 5.34ECh. 5 - Prob. 5.35ECh. 5 - Prob. 5.36ECh. 5 - Prob. 5.37ECh. 5 - Prob. 5.38ECh. 5 - Prob. 5.39ECh. 5 - Prob. 5.40ECh. 5 - Calculate the number of grams of SO2 that must...Ch. 5 - Calculate the mass of limestone (CaCO3) that must...Ch. 5 - Calculate the number of moles of CO2 generated by...Ch. 5 - Calculate the number of grams of bromine (Br2)...Ch. 5 - Prob. 5.45ECh. 5 - Prob. 5.46ECh. 5 - Pure titanium metal is produced by reacting...Ch. 5 - An important metabolic process of the body is the...Ch. 5 - Caproic acid is oxidized in the body as follows:...Ch. 5 - A sample of 4.00g of methane (CH4) is mixed with...Ch. 5 - Nitrogen and oxygen react as follows:...Ch. 5 - Suppose you want to use acetylene (C2H2) as a...Ch. 5 - Ammonia, carbon dioxide, and water vapor react to...Ch. 5 - Prob. 5.55ECh. 5 - The actual yield of a reaction was 11.74g of...Ch. 5 - A product weighing 14.37g was isolated from a...Ch. 5 - Prob. 5.58ECh. 5 - A sample of calcium metal with a mass of 2.00g was...Ch. 5 - Upon heating, mercury (II) oxide undergoes a...Ch. 5 - Prob. 5.61ECh. 5 - Rewrite the following word equation using chemical...Ch. 5 - The element with an electron configuration of...Ch. 5 - Assuming a 100 reaction yield, it was calculated...Ch. 5 - The decomposition of a sample of a compound...Ch. 5 - Prob. 5.66ECh. 5 - Prob. 5.67ECh. 5 - Prob. 5.68ECh. 5 - Prob. 5.69ECh. 5 - Prob. 5.70ECh. 5 - Certain vegetables and fruits, such as potatoes...Ch. 5 - In an ordinary flashlight battery, an oxidation...Ch. 5 - Prob. 5.73ECh. 5 - Prob. 5.74ECh. 5 - Which of the following equations is balanced? a....Ch. 5 - Prob. 5.76ECh. 5 - Prob. 5.77ECh. 5 - What is the oxidation number of sodium in the...Ch. 5 - Prob. 5.79ECh. 5 - Prob. 5.80ECh. 5 - Prob. 5.81ECh. 5 - Prob. 5.82ECh. 5 - Prob. 5.83ECh. 5 - Which of the following species is being oxidized...Ch. 5 - Identify the oxidizing agent and the reducing...Ch. 5 - Prob. 5.86ECh. 5 - Identify the following as an oxidation, a...Ch. 5 - Prob. 5.88ECh. 5 - Prob. 5.89ECh. 5 - Prob. 5.90ECh. 5 - What is the net ionic equation of the following...Ch. 5 - Prob. 5.92ECh. 5 - Prob. 5.93ECh. 5 - The number of grams of hydroegn formed by the...Ch. 5 - In the reaction CaCl2+Na2CO3CaCO3+2NaCl, if...Ch. 5 - Prob. 5.96E
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