PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
2nd Edition
ISBN: 9781285074788
Author: Ball
Publisher: CENGAGE L
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Chapter 5, Problem 5.44E
Biological standard states include specifying a reference temperature of
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Give the major organic product(s) of each of the following reactions or sequences of reactions. Show all
relevant stereochemistry. [two only]
CH3O
(11
HC-C-C-CH3
A.
CH3
12. NaOH
Diethyl malonate can be prepared by the following reaction sequence. Draw the structures of each of the
missing intermediates in the boxes provided.
17
1. Br PBr
H&C
OH 2 H₂O
CH3CH₂OH
На
NaCN
H₂SO4
NC.
CH CH₂OH
на
H₂O, heat
CH₂
OCHCH3
ཝསི། ཡིཀྑཱམུདྡྷནྟ
CH₂
OEt
The reaction of a carboxylic acid with an alcohol in the presence of acid is termed Fischer esterification.
OH + CH₂OH
На
B C
A. The nucleophile in this reaction is
B. Compound C functions as
a.
a base scavenger
b.
a solvent
C.
a catalyst
d.
a neutralizer
C. Fischer esterification is an example of: .
a. nucleophilic acyl addition
b. nucleophilic acyl substitution
c. nucleophilic acyl elimination
d. nucleophilic acyl rearrangement
in this reaction.
Chapter 5 Solutions
PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
Ch. 5 - 5.1. Can a battery that has a voltage be...Ch. 5 - 5.2. What is the difference between a static...Ch. 5 - Which system in each pair best represents...Ch. 5 -
5.4. Supersaturated solutions can be made in...Ch. 5 -
5.5. Following is a chemical reaction between...Ch. 5 - 5.6. The following is a reaction with its initial...Ch. 5 - The following is a reaction with initial amounts...Ch. 5 - 5.8. The hemoglobin in blood establishes an...Ch. 5 - Prob. 5.9ECh. 5 - 5.10. If and gases were contained in a system...
Ch. 5 - 5.11. Determine the numerical value of Q for the...Ch. 5 - 5.12. True or false: If all the partial pressures...Ch. 5 - For the reaction 2SO3(g)2SO2(g)+O2(g) when 2mol of...Ch. 5 - 5.14. Determine and for the following reaction at...Ch. 5 - 5.15. Consider the reaction
If the partial...Ch. 5 -
5.16. In atmospheric chemistry, the following...Ch. 5 - Prob. 5.17ECh. 5 - 5.18. Hydrogen cyanide can isomerize to hydrogen...Ch. 5 - 5.19. Assume that a reaction exists such that...Ch. 5 - Prob. 5.20ECh. 5 - 5.21. Show that if the coefficients of a balanced...Ch. 5 - 5.22. True or false: If for a gas-phase reaction,...Ch. 5 - 5.23. The balanced chemical reaction for the...Ch. 5 - The answers in exercise 5.23 should show that...Ch. 5 - At a high enough temperature, the equilibrium...Ch. 5 - Prob. 5.26ECh. 5 - 5.27. Nitrogen dioxide,, dimerizes easily to form...Ch. 5 - 5.28. Another nitrogen-oxygen reaction of some...Ch. 5 - Prob. 5.29ECh. 5 - Prob. 5.30ECh. 5 - Prob. 5.31ECh. 5 - 5.32. For the reaction
. (a) Using in Appendix...Ch. 5 - 5.33. Use the data in Appendix to calculate ...Ch. 5 - 5.34. The of diamond, a crystalline form of...Ch. 5 - 5.35. The densities of graphite and diamond are ...Ch. 5 - Buckminsterfullerene, C60, is a spherical molecule...Ch. 5 - Prob. 5.37ECh. 5 - At what pressure does H2O have an activity of...Ch. 5 - The bisulfate or hydrogen sulfate anion, HSO4, is...Ch. 5 - Prob. 5.40ECh. 5 - Write the equilibrium constant expression for each...Ch. 5 - Prob. 5.42ECh. 5 - For the given chemical equilibrium, these data are...Ch. 5 - Biological standard states include specifying a...Ch. 5 - a At 25.0C, Kw for the autoionization of water is...Ch. 5 - 5.46. For a reaction whose standard enthalpy...Ch. 5 - 5.47. For the reaction
and . Estimate for this...Ch. 5 - 5.48. The isotope exchange reaction
has an...Ch. 5 - 5.49. Consider the following equilibrium:
What...Ch. 5 - 5.50. For the equilibrium
Equilibrium partial...Ch. 5 - The decomposition of NaHCO3, used in kitchens to...Ch. 5 - 5.52. For the equilibrium
at,. In a flask, of...Ch. 5 - Prob. 5.53ECh. 5 - 5.54. For the reaction
The equilibrium...Ch. 5 - Prob. 5.55ECh. 5 - 5.56. Of the amino acids listed in Table , which...Ch. 5 - 5.57. Determine the concentration of the three...Ch. 5 - 5.58. The formation of zwitterionic glycine, ,...Ch. 5 - 5.59. Monosodium glutamate, or MSG, is the sodium...Ch. 5 - Prob. 5.60ECh. 5 - Consider the balanced chemical reaction...Ch. 5 - For the gas-phase reaction 2H2+O22H2O rxnG is...Ch. 5 - Prob. 5.63ECh. 5 - Prob. 5.64E
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- Give the major organic product(s) for each of the following reactions or sequences of reactions. Show all relevant stereochemistry [2 ONLY]. A -CH2COOH 1. LIAIH THF, heat 2 HO B. C. CH₂Br Br 1. NaCN, acetone 2 H₂O, heat 1. Mg ether 3 HO Z CO₂arrow_forwardWhat is the order of increasing acidity for the following compounds? (least to most) [2 ONLY] A. COOH COOH COOH COOH 6666 a. IV, I, III, II b. III, II, I, IV с. II, III, I, IV d. III, II, IV, I slingoros CH3 IV woled noise bizarrow_forwardWith this, please answer the following questions: 1.) draw the structure of the electrophilic intermediate in this reaction. 2.) what is the role of the AlCl3 in the reaction 3.) write the complete stepwise mechanism for this reaction. Show all electron flow with arrows and include all intermediate structuresarrow_forward
- Consider the data below to answer the following questions. Cyanohydrins are important intermediates in the synthesis of a-hydroxycarboxylic acids from ketones and aldehydes. The nitrile functional group can be hydrolyzed by aqueous acid to yield a carboxylic acid. Nitriles can also be hydrolyzed to carboxylic acids using aqueous base. Unfortunately, when a cyanohydrin is treated with aqueous base the original carbonyl compound is isolated. HO H HCEN H-3- HO' NaOH HO cyanohychin a. a nucleophilic substitution b. an electrophilic addition C10 OH CH-COOH A. The reaction of an aldehyde with hydrogen cyanide is an example of + NaCN + H₂O reaction. H- C. an electrophilic substitution d. a nucleophilic addition B. Identify the electrophile in the reaction of benzaldehyde with hydrogen cyanide.arrow_forwardRefer to the data below to answer the following questions: The octapeptide saralasin is a specific antagonist of angiotensin II. A derivative of saralasin is used therapeutically as an antihypertensive. Amino acid analysis of saralasin show the presence of the following amino acids: Ala, Arg, His, Pro, Sar, Tyr, Val, Val A. Sar is the abbreviation for sarcosine, N-methyl aminoethanoic acid. Draw the structure of sarcosine. B. N-Terminal analysis by the Edman method shows saralasin contains sarcosine at the N-terminus. Partial hydrolysis of saralasin with dilute hydrochloric acid yields the following fragments: Tyr-Val-His Sar-Arg-Val His-Pro-Ala Val-Tyr-Val Arg-Val-Tyr What is the structure of saralasin?arrow_forwardGive the major organic product(s) of each of the following reactions or sequences of reactions. Show all relevant stereochemistry.[4 only] CH3 A. B. HNO H₂Pt H₂SO4 hano NaN 1. LIAH ether Br 4 2 H₂O C. D. E. CH3CH2-CH2CH3 + HCl Br NH₂ CH3 ON CH-CH3 Br HNOZ CUCI 11,504 HC) 1. HNO H SO NH₂ 2 UMarrow_forward
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