The structural formula of at least one bromoalkene having the molecular formula is C 5 H 9 B r has to be drawn where the compound does not show E, Z isomerism and chirality. Concept Introduction: Alkene: Unsaturated hydrocarbons having at least one double bond between two carbon atoms are known as alkenes . Geometric isomers: Two compounds are considered as geometric isomers of each other if both contains same number of atoms but different in their arrangement. E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond. Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond. Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

Question

Benzene-toluene equilibrium is often approximated as αBT = 2.34. Generate the y-x diagram for this relative volatility. Also, generate the equilibrium data using Raoult’s law, and compare your results to these.

Answer 1

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 5, Problem 5.20P

(a)

Interpretation Introduction

Interpretation:

The structural formula of at least one bromoalkene having the molecular formula is C5H9Br has to be drawn where the compound does not show E, Z isomerism and chirality.

Concept Introduction:

Alkene: Unsaturated hydrocarbons having at least one double bond between two carbon atoms are known as alkenes.

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contains same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

(b)

Interpretation Introduction

Interpretation:

The structural formula of at least one bromoalkene having the molecular formula is C5H9Br has to be drawn where the compound must show E, Z isomerism but not chirality.

Concept Introduction:

Alkene: Unsaturated hydrocarbons having at least one double bond between two carbon atoms are known as alkenes.

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contain same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

(c)

Interpretation Introduction

Interpretation:

The structural formula of at least one bromoalkene having the molecular formula is C5H9Br has to be drawn where the compound shows chirality but not E, Z isomerism.

Concept Introduction:

Alkene: Unsaturated hydrocarbons having at least one double bond between two carbon atoms are known as alkenes.

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contains same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

(d)

Interpretation Introduction

Interpretation:

The structural formula of at least one bromoalkene having the molecular formula is C5H9Br has to be drawn where the compound shows both E, Z isomerism and chirality.

Concept Introduction:

Alkene: Unsaturated hydrocarbons having at least one double bond between two carbon atoms are known as alkenes.

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contains same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

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Benzene-toluene equilibrium is often approximated as αBT = 2.34. Generate the y-x diagram for this relative volatility. Also, generate the equilibrium data using Raoult’s law, and compare your results to these.

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Rank the following components in order of decreasing volatility: butane, n-pentane, iso-pentene (e.g., 3-methyl-1-butene), isoprene, pentanol? Briefly explain your answer.

Answer 2

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 5, Problem 5.20P

(a)

Interpretation Introduction

Interpretation:

The structural formula of at least one bromoalkene having the molecular formula is C5H9Br has to be drawn where the compound does not show E, Z isomerism and chirality.

Concept Introduction:

Alkene: Unsaturated hydrocarbons having at least one double bond between two carbon atoms are known as alkenes.

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contains same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

(b)

Interpretation Introduction

Interpretation:

The structural formula of at least one bromoalkene having the molecular formula is C5H9Br has to be drawn where the compound must show E, Z isomerism but not chirality.

Concept Introduction:

Alkene: Unsaturated hydrocarbons having at least one double bond between two carbon atoms are known as alkenes.

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contain same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

(c)

Interpretation Introduction

Interpretation:

The structural formula of at least one bromoalkene having the molecular formula is C5H9Br has to be drawn where the compound shows chirality but not E, Z isomerism.

Concept Introduction:

Alkene: Unsaturated hydrocarbons having at least one double bond between two carbon atoms are known as alkenes.

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contains same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

(d)

Interpretation Introduction

Interpretation:

The structural formula of at least one bromoalkene having the molecular formula is C5H9Br has to be drawn where the compound shows both E, Z isomerism and chirality.

Concept Introduction:

Alkene: Unsaturated hydrocarbons having at least one double bond between two carbon atoms are known as alkenes.

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contains same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

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Answer 3

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 5, Problem 5.20P

(a)

Interpretation Introduction

Interpretation:

The structural formula of at least one bromoalkene having the molecular formula is C5H9Br has to be drawn where the compound does not show E, Z isomerism and chirality.

Concept Introduction:

Alkene: Unsaturated hydrocarbons having at least one double bond between two carbon atoms are known as alkenes.

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contains same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

(b)

Interpretation Introduction

Interpretation:

The structural formula of at least one bromoalkene having the molecular formula is C5H9Br has to be drawn where the compound must show E, Z isomerism but not chirality.

Concept Introduction:

Alkene: Unsaturated hydrocarbons having at least one double bond between two carbon atoms are known as alkenes.

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contain same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

(c)

Interpretation Introduction

Interpretation:

The structural formula of at least one bromoalkene having the molecular formula is C5H9Br has to be drawn where the compound shows chirality but not E, Z isomerism.

Concept Introduction:

Alkene: Unsaturated hydrocarbons having at least one double bond between two carbon atoms are known as alkenes.

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contains same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

(d)

Interpretation Introduction

Interpretation:

The structural formula of at least one bromoalkene having the molecular formula is C5H9Br has to be drawn where the compound shows both E, Z isomerism and chirality.

Concept Introduction:

Alkene: Unsaturated hydrocarbons having at least one double bond between two carbon atoms are known as alkenes.

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contains same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

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Answer 4

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 5, Problem 5.20P

(a)

Interpretation Introduction

Interpretation:

The structural formula of at least one bromoalkene having the molecular formula is C5H9Br has to be drawn where the compound does not show E, Z isomerism and chirality.

Concept Introduction:

Alkene: Unsaturated hydrocarbons having at least one double bond between two carbon atoms are known as alkenes.

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contains same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

(b)

Interpretation Introduction

Interpretation:

The structural formula of at least one bromoalkene having the molecular formula is C5H9Br has to be drawn where the compound must show E, Z isomerism but not chirality.

Concept Introduction:

Alkene: Unsaturated hydrocarbons having at least one double bond between two carbon atoms are known as alkenes.

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contain same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

(c)

Interpretation Introduction

Interpretation:

The structural formula of at least one bromoalkene having the molecular formula is C5H9Br has to be drawn where the compound shows chirality but not E, Z isomerism.

Concept Introduction:

Alkene: Unsaturated hydrocarbons having at least one double bond between two carbon atoms are known as alkenes.

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contains same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

(d)

Interpretation Introduction

Interpretation:

The structural formula of at least one bromoalkene having the molecular formula is C5H9Br has to be drawn where the compound shows both E, Z isomerism and chirality.

Concept Introduction:

Alkene: Unsaturated hydrocarbons having at least one double bond between two carbon atoms are known as alkenes.

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contains same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

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Answer 5

Chapter 5, Problem 5.20P

(a)

Interpretation Introduction

Interpretation:

The structural formula of at least one bromoalkene having the molecular formula is C5H9Br has to be drawn where the compound does not show E, Z isomerism and chirality.

Concept Introduction:

Alkene: Unsaturated hydrocarbons having at least one double bond between two carbon atoms are known as alkenes.

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contains same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

(b)

Interpretation Introduction

Interpretation:

The structural formula of at least one bromoalkene having the molecular formula is C5H9Br has to be drawn where the compound must show E, Z isomerism but not chirality.

Concept Introduction:

Alkene: Unsaturated hydrocarbons having at least one double bond between two carbon atoms are known as alkenes.

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contain same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

(c)

Interpretation Introduction

Interpretation:

The structural formula of at least one bromoalkene having the molecular formula is C5H9Br has to be drawn where the compound shows chirality but not E, Z isomerism.

Concept Introduction:

Alkene: Unsaturated hydrocarbons having at least one double bond between two carbon atoms are known as alkenes.

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contains same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

(d)

Interpretation Introduction

Interpretation:

The structural formula of at least one bromoalkene having the molecular formula is C5H9Br has to be drawn where the compound shows both E, Z isomerism and chirality.

Concept Introduction:

Alkene: Unsaturated hydrocarbons having at least one double bond between two carbon atoms are known as alkenes.

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contains same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

Answer 6

Chapter 5, Problem 5.20P

(a)

Interpretation Introduction

Interpretation:

The structural formula of at least one bromoalkene having the molecular formula is C5H9Br has to be drawn where the compound does not show E, Z isomerism and chirality.

Concept Introduction:

Alkene: Unsaturated hydrocarbons having at least one double bond between two carbon atoms are known as alkenes.

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contains same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

Answer 7

Chapter 5, Problem 5.20P

(a)

Interpretation Introduction

Interpretation:

The structural formula of at least one bromoalkene having the molecular formula is C5H9Br has to be drawn where the compound does not show E, Z isomerism and chirality.

Concept Introduction:

Alkene: Unsaturated hydrocarbons having at least one double bond between two carbon atoms are known as alkenes.

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contains same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The structural formula of at least one bromoalkene having the molecular formula is C5H9Br has to be drawn where the compound must show E, Z isomerism but not chirality.

Concept Introduction:

Alkene: Unsaturated hydrocarbons having at least one double bond between two carbon atoms are known as alkenes.

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contain same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The structural formula of at least one bromoalkene having the molecular formula is C5H9Br has to be drawn where the compound must show E, Z isomerism but not chirality.

Concept Introduction:

Alkene: Unsaturated hydrocarbons having at least one double bond between two carbon atoms are known as alkenes.

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contain same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The structural formula of at least one bromoalkene having the molecular formula is C5H9Br has to be drawn where the compound shows chirality but not E, Z isomerism.

Concept Introduction:

Alkene: Unsaturated hydrocarbons having at least one double bond between two carbon atoms are known as alkenes.

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contains same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The structural formula of at least one bromoalkene having the molecular formula is C5H9Br has to be drawn where the compound shows chirality but not E, Z isomerism.

Concept Introduction:

Alkene: Unsaturated hydrocarbons having at least one double bond between two carbon atoms are known as alkenes.

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contains same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The structural formula of at least one bromoalkene having the molecular formula is C5H9Br has to be drawn where the compound shows both E, Z isomerism and chirality.

Concept Introduction:

Alkene: Unsaturated hydrocarbons having at least one double bond between two carbon atoms are known as alkenes.

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contains same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The structural formula of at least one bromoalkene having the molecular formula is C5H9Br has to be drawn where the compound shows both E, Z isomerism and chirality.

Concept Introduction:

Alkene: Unsaturated hydrocarbons having at least one double bond between two carbon atoms are known as alkenes.

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contains same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

Answer 14

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Ch. 5.1 - Calculate the index of hydrogen deficiency for...Ch. 5.1 - Prob. 5.2P Ch. 5.2 - Write the IUPAC name of each alkene. (a) (b)Ch. 5.2 - Prob. 5.4P Ch. 5.2 - Prob. 5.5P Ch. 5.2 - Prob. 5.6P Ch. 5.2 - Prob. 5.7P Ch. 5.2 - Prob. 5.8P Ch. 5 - Predict all approximate bond angles about each...Ch. 5 - Prob. 5.10P

Solution Summary: The author explains that unsaturated hydrocarbons having at least one double bond between two carbon atoms are known as alkenes. Geometric isomers are given E configuration if high priority groups are placed on

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