Concept explainers
(a)
Interpretation:
The partial pressure of oxygen needs to be determined.
Concept introduction:
Dalton’s law of partial pressure will be used, which can be calculated by; that, partial pressure of any substance is equal to the mole fraction of that substance multiplied by the total pressure. It can be given as-
(b)
Interpretation:
The number of moles of dry gas needs to be determined.
Concept introduction:
Ideal gas equation which holds the characteristic of ideal gas will be used, which can be given as-
Number of moles of a gas can be calculated by dividing mass of substance by mass of one mole or molar mass.
(c)
Interpretation:
The number of moles of wet gas needs to be determined.
Concept introduction:
Ideal gas will be used to calculate the no. of moles of wet gas. It is given as-
(d)
Interpretation:
The partial pressure of nitrogen in the flask needs to be determined.
Concept introduction:
To calculate the partial pressure mass and molar mass relation and
Mass and molar mass relation is given as-
Ideal gas equation for pressure is given as-
(e)
Interpretation:
The total pressure in the flask after addition of nitrogen needs to be determined.
Concept introduction:
Ideal gas equation for pressure is given as-
With the help of ideal gas equation pressure of both gases will be calculated which is added later to calculate total pressure.
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Chapter 5 Solutions
Student Solutions Manual For Masterton/hurley's Chemistry: Principles And Reactions, 8th
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- You have two pressure-proof steel cylinders of equal volume, one containing 1.0 kg of CO and the other containing 1.0 kg of acetylene, C2H2. (a) In which cylinder is the pressure greater at 25 C? (b) Which cylinder contains the greater number of molecules?arrow_forwardRaoul Pictet, the Swiss physicist who first liquefied oxygen, attempted to liquefy hydrogen. He heated potassium formate, KCHO2, with KOH in a closed 2.50-Lvessel. KCHO2(s)+KOH(s)K2CO3(s)+H2(g) If 75.0 g of potassium formate reacts in a 2.50-L vessel, which was initially evacuated, what pressure of hydrogen will be attained when the temperature is finally cooled to 25C? Use the preceding chemical equation and ignore the volume of solid product.arrow_forwardA person exhales about 5.8 102 L of carbon dioxide per day (at STP). The carbon dioxide exhaled by an astronaut is absorbed from the air of a space capsule by reaction with lithium hydroxide, LiOH. 2LiOH(s)+CO2(g)Li2CO3(s)+H2O(l) How many grams of lithium hydroxide are required per astronaut per day?arrow_forward
- A study of climbers who reached the summit of Mount Everest without supplemental oxygen showed that the partial pressures of O2 and CO2 in their lungs were 35 mm Mg and 7.5 mm Hg, respectively. The barometric pressure at the summit was 253 mm Hg. Assume the lung gases are saturated with moisture at a body temperature of 37 C [which means the partial pressure of water vapor in the lungs is P(H2O) = 47.1 mm Hg]. If you assume the lung gases consist of only O2, N2, CO2, and H2O, what is the partial pressure of N2?arrow_forward5-107 If 60.0 g of NH3 occupies 35.1 L under a pressure of 77.2 in. Hg, what is the temperature of the gas, in °C?arrow_forwardLiquid oxygen was first prepared by heating potassium chlorate, KClO3, in a closed vessel to obtain oxygen at high pressure. The oxygen was cooled until it liquefied. 2KClO3(s)2KCl(s)+3O2(g) If 171 g of potassium chlorate reacts in a 2.70-L vessel, which was initially evacuated, what pressure of oxygen will be attained when the temperature is finally cooled to 25C? Use the preceding chemical equation and ignore the volume of solid product.arrow_forward
- How does hydraulic fracturing differ from previously used techniques for the recovery of natural gas from the earth?arrow_forwardA 21.4-mL volume of hydrochloric acid reacts completely with a solid sample of MgCO3. The reaction is 2HCl(aq)+MgCO3(s)CO2(g)+H2O(l)+MgCl2(aq) The volume of CO2 formed is 159 mL at 23C and 731 mmHg. What is the molarity of the HCl solution?arrow_forwardA 2.0 L soda bottle is pressurized with 4.5 atm of CO2 at 298 K. If the temperature is increased to 317 K, what is the pressure of the CO2?arrow_forward
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