(a) Interpretation: Whether the compound trans1, 2-difluorocyclohexane , by using the molecular model, is chiral is to be determined. Concept introduction: Chiral molecules are molecules in which carbon atom contain four different groups on it. The carbon atom which contains four different groups is known as the chiral center of the molecule.

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Answer 1

Question

Chapter 5, Problem 5.11YT

Interpretation Introduction

(a)

Interpretation:

Whether the compound trans1, 2-difluorocyclohexane, by using the molecular model, is chiral is to be determined.

Concept introduction:

Chiral molecules are molecules in which carbon atom contain four different groups on it. The carbon atom which contains four different groups is known as the chiral center of the molecule.

Interpretation Introduction

(b)

Interpretation:

The compound trans1, 2-difluorocyclohexane shows diastereomerism by rotation is to be determined.

Concept introduction:

When two compounds are superimposable mirror images, then the compound is same but if they are not superimposable and mirror images of each other, then they are diastereomers of each other. These diastereomers are stereoisomers which are not mirror images of each other. To be stereoisomers, they must contain the same molecular formula, be different molecules, and have same connectivity.

Interpretation Introduction

(c)

Interpretation:

Chair flipping of trans1, 2-difluorocyclohexane and its mirror image are non-superimposable is to be determined.

Concept introduction:

When two compounds are superimposable mirror images, then the compound is same but if they are not superimposable mirror images of each other, then they are diastereomers of each other. These diastereomers are stereoisomers which are not mirror images of each other. To be stereoisomers, they must contain same molecular formula, be different molecules, and have same connectivity.

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2. 200 LOD For an unknown compound with a molecular ion of 101 m/z: a. Use the molecular ion to propose at least two molecular formulas. (show your work) b. What is the DU for each of your possible formulas? (show your work) C. Solve the structure and assign each of the following spectra. 8 6 4 2 (ppm) 150 100 50 ō (ppm) 4000 3000 2000 1500 1000 500 HAVENUMBERI-11

Answer 2

Question

Chapter 5, Problem 5.11YT

Interpretation Introduction

(a)

Interpretation:

Whether the compound trans1, 2-difluorocyclohexane, by using the molecular model, is chiral is to be determined.

Concept introduction:

Chiral molecules are molecules in which carbon atom contain four different groups on it. The carbon atom which contains four different groups is known as the chiral center of the molecule.

Interpretation Introduction

(b)

Interpretation:

The compound trans1, 2-difluorocyclohexane shows diastereomerism by rotation is to be determined.

Concept introduction:

When two compounds are superimposable mirror images, then the compound is same but if they are not superimposable and mirror images of each other, then they are diastereomers of each other. These diastereomers are stereoisomers which are not mirror images of each other. To be stereoisomers, they must contain the same molecular formula, be different molecules, and have same connectivity.

Interpretation Introduction

(c)

Interpretation:

Chair flipping of trans1, 2-difluorocyclohexane and its mirror image are non-superimposable is to be determined.

Concept introduction:

When two compounds are superimposable mirror images, then the compound is same but if they are not superimposable mirror images of each other, then they are diastereomers of each other. These diastereomers are stereoisomers which are not mirror images of each other. To be stereoisomers, they must contain same molecular formula, be different molecules, and have same connectivity.

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Answer 3

Question

Chapter 5, Problem 5.11YT

Interpretation Introduction

(a)

Interpretation:

Whether the compound trans1, 2-difluorocyclohexane, by using the molecular model, is chiral is to be determined.

Concept introduction:

Chiral molecules are molecules in which carbon atom contain four different groups on it. The carbon atom which contains four different groups is known as the chiral center of the molecule.

Interpretation Introduction

(b)

Interpretation:

The compound trans1, 2-difluorocyclohexane shows diastereomerism by rotation is to be determined.

Concept introduction:

When two compounds are superimposable mirror images, then the compound is same but if they are not superimposable and mirror images of each other, then they are diastereomers of each other. These diastereomers are stereoisomers which are not mirror images of each other. To be stereoisomers, they must contain the same molecular formula, be different molecules, and have same connectivity.

Interpretation Introduction

(c)

Interpretation:

Chair flipping of trans1, 2-difluorocyclohexane and its mirror image are non-superimposable is to be determined.

Concept introduction:

When two compounds are superimposable mirror images, then the compound is same but if they are not superimposable mirror images of each other, then they are diastereomers of each other. These diastereomers are stereoisomers which are not mirror images of each other. To be stereoisomers, they must contain same molecular formula, be different molecules, and have same connectivity.

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Answer 4

Question

Chapter 5, Problem 5.11YT

Interpretation Introduction

(a)

Interpretation:

Whether the compound trans1, 2-difluorocyclohexane, by using the molecular model, is chiral is to be determined.

Concept introduction:

Chiral molecules are molecules in which carbon atom contain four different groups on it. The carbon atom which contains four different groups is known as the chiral center of the molecule.

Interpretation Introduction

(b)

Interpretation:

The compound trans1, 2-difluorocyclohexane shows diastereomerism by rotation is to be determined.

Concept introduction:

When two compounds are superimposable mirror images, then the compound is same but if they are not superimposable and mirror images of each other, then they are diastereomers of each other. These diastereomers are stereoisomers which are not mirror images of each other. To be stereoisomers, they must contain the same molecular formula, be different molecules, and have same connectivity.

Interpretation Introduction

(c)

Interpretation:

Chair flipping of trans1, 2-difluorocyclohexane and its mirror image are non-superimposable is to be determined.

Concept introduction:

When two compounds are superimposable mirror images, then the compound is same but if they are not superimposable mirror images of each other, then they are diastereomers of each other. These diastereomers are stereoisomers which are not mirror images of each other. To be stereoisomers, they must contain same molecular formula, be different molecules, and have same connectivity.

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Answer 5

Chapter 5, Problem 5.11YT

Interpretation Introduction

(a)

Interpretation:

Whether the compound trans1, 2-difluorocyclohexane, by using the molecular model, is chiral is to be determined.

Concept introduction:

Chiral molecules are molecules in which carbon atom contain four different groups on it. The carbon atom which contains four different groups is known as the chiral center of the molecule.

Interpretation Introduction

(b)

Interpretation:

The compound trans1, 2-difluorocyclohexane shows diastereomerism by rotation is to be determined.

Concept introduction:

When two compounds are superimposable mirror images, then the compound is same but if they are not superimposable and mirror images of each other, then they are diastereomers of each other. These diastereomers are stereoisomers which are not mirror images of each other. To be stereoisomers, they must contain the same molecular formula, be different molecules, and have same connectivity.

Interpretation Introduction

(c)

Interpretation:

Chair flipping of trans1, 2-difluorocyclohexane and its mirror image are non-superimposable is to be determined.

Concept introduction:

When two compounds are superimposable mirror images, then the compound is same but if they are not superimposable mirror images of each other, then they are diastereomers of each other. These diastereomers are stereoisomers which are not mirror images of each other. To be stereoisomers, they must contain same molecular formula, be different molecules, and have same connectivity.

Answer 6

Chapter 5, Problem 5.11YT

Interpretation Introduction

(a)

Interpretation:

Whether the compound trans1, 2-difluorocyclohexane, by using the molecular model, is chiral is to be determined.

Concept introduction:

Chiral molecules are molecules in which carbon atom contain four different groups on it. The carbon atom which contains four different groups is known as the chiral center of the molecule.

Answer 7

Chapter 5, Problem 5.11YT

Interpretation Introduction

(a)

Interpretation:

Whether the compound trans1, 2-difluorocyclohexane, by using the molecular model, is chiral is to be determined.

Concept introduction:

Chiral molecules are molecules in which carbon atom contain four different groups on it. The carbon atom which contains four different groups is known as the chiral center of the molecule.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The compound trans1, 2-difluorocyclohexane shows diastereomerism by rotation is to be determined.

Concept introduction:

When two compounds are superimposable mirror images, then the compound is same but if they are not superimposable and mirror images of each other, then they are diastereomers of each other. These diastereomers are stereoisomers which are not mirror images of each other. To be stereoisomers, they must contain the same molecular formula, be different molecules, and have same connectivity.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The compound trans1, 2-difluorocyclohexane shows diastereomerism by rotation is to be determined.

Concept introduction:

When two compounds are superimposable mirror images, then the compound is same but if they are not superimposable and mirror images of each other, then they are diastereomers of each other. These diastereomers are stereoisomers which are not mirror images of each other. To be stereoisomers, they must contain the same molecular formula, be different molecules, and have same connectivity.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Chair flipping of trans1, 2-difluorocyclohexane and its mirror image are non-superimposable is to be determined.

Concept introduction:

When two compounds are superimposable mirror images, then the compound is same but if they are not superimposable mirror images of each other, then they are diastereomers of each other. These diastereomers are stereoisomers which are not mirror images of each other. To be stereoisomers, they must contain same molecular formula, be different molecules, and have same connectivity.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Chair flipping of trans1, 2-difluorocyclohexane and its mirror image are non-superimposable is to be determined.

Concept introduction:

When two compounds are superimposable mirror images, then the compound is same but if they are not superimposable mirror images of each other, then they are diastereomers of each other. These diastereomers are stereoisomers which are not mirror images of each other. To be stereoisomers, they must contain same molecular formula, be different molecules, and have same connectivity.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 5 - Prob. 5.1P Ch. 5 - Prob. 5.2P Ch. 5 - Prob. 5.3P Ch. 5 - Prob. 5.4P Ch. 5 - Prob. 5.5P Ch. 5 - Prob. 5.6P Ch. 5 - Prob. 5.7P Ch. 5 - Prob. 5.8P Ch. 5 - Prob. 5.9P Ch. 5 - Prob. 5.10P

Solution Summary: The author explains that the compound trans1, 2-difluorocyclohexane is chiral by using the molecular model.

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