Bundle: Introductory Chemistry: An Active Learning Approach, 6th + OWLv2, 1 term (6 months) Printed Access Card
6th Edition
ISBN: 9781305717367
Author: Mark S. Cracolice, Ed Peters
Publisher: Cengage Learning
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Chapter 5, Problem 47E
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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an
organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the
compound. Find the structure. Show complete solutions.
Predicted 1H NMR Spectrum
4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1
f1 (ppm)
Predicted 13C NMR Spectrum
100
f1 (ppm)
30
220 210 200 190 180
170
160 150 140 130 120
110
90
80
70
-26
60
50
40
46
30
20
115
10
1.0 0.9 0.8
0
-10
Q: Arrange BCC and Fec
metals, in sequence from the
Fable (Dr. R's slides) and
Calculate Volume and Density.
Aa
BCC
V
52 5
SFCC
None
Chapter 5 Solutions
Bundle: Introductory Chemistry: An Active Learning Approach, 6th + OWLv2, 1 term (6 months) Printed Access Card
Ch. 5 - Prob. 1ECh. 5 - List the major points in Daltons atomic theory.Ch. 5 - Show that the Daltons atomic theory explains the...Ch. 5 - How does Daltons atomic theory account for the Law...Ch. 5 - The chemical name for limestone, a compound of...Ch. 5 - The brilliance with which magnesium burns makes it...Ch. 5 - Sulfur and fluorine form at least two compounds...Ch. 5 - Prob. 8ECh. 5 - Advances in technology and science often progress...Ch. 5 - When J. J. Thomson measured the deflection of a...
Ch. 5 - Prob. 11ECh. 5 - What is meant by stating that the charge of an...Ch. 5 - How can we account for the fact that, in the...Ch. 5 - How can we account for the fact that most of the...Ch. 5 - What do we call the central part of an atom?Ch. 5 - What major conclusions were drawn from the...Ch. 5 - Describe the activity of electrons according to...Ch. 5 - The Rutherford experiment was performed and its...Ch. 5 - Compare the three major parts of an atom in charge...Ch. 5 - Prob. 20ECh. 5 - Can two different elements have the same atomic...Ch. 5 - Compare the number of protons and electrons in an...Ch. 5 - Explain why isotopes of different elements can...Ch. 5 - How many protons, neutrons and electrons are there...Ch. 5 - Prob. 25ECh. 5 - What advantage does the atomic mass unit have over...Ch. 5 - What is an atomic mass unit?Ch. 5 - The mass of an average atom of a certain element...Ch. 5 - The average mass of boron atoms is 10.81u. How...Ch. 5 - The atomic masses of the natural isotopes of neon...Ch. 5 - A certain element consists of two stable isotopes....Ch. 5 - The mass of 60.4 of the atoms of an element is...Ch. 5 - Isotopic data for boron allow the calculation of...Ch. 5 - Questions 31 through 36: Percentage abundances and...Ch. 5 - Questions 31 through 36: Percentage abundances and...Ch. 5 - Questions 31 through 36: Percentage abundances and...Ch. 5 - Questions 31 through 36: Percentage abundances and...Ch. 5 - Questions 31 through 36: Percentage abundances and...Ch. 5 - Prob. 40ECh. 5 - How many elements are in Period 5 of the periodic...Ch. 5 - Write the symbol of the element in each given...Ch. 5 - Prob. 43ECh. 5 - List the symbols of the elements of each of the...Ch. 5 - Using only a periodic table for reference, list...Ch. 5 - Prob. 46ECh. 5 - Write the atomic masses of helium and aluminum.Ch. 5 - Prob. 48ECh. 5 - Prob. 49ECh. 5 - Prob. 50ECh. 5 - Prob. 51ECh. 5 - Determine whether each statement that follows is...Ch. 5 - Prob. 53ECh. 5 - Sodium oxide and sodium peroxide are two compounds...Ch. 5 - Prob. 55ECh. 5 - The CRC Handbook, a large reference book of...Ch. 5 - The element lanthanum has two stable isotopes,...Ch. 5 - The atomic mass of lithium on a periodic table is...Ch. 5 - Prob. 59ECh. 5 - Prob. 60ECh. 5 - Prob. 61ECh. 5 - Prob. 62ECh. 5 - Prob. 5.1TCCh. 5 - Prob. 5.2TCCh. 5 - Prob. 5.3TCCh. 5 - Prob. 5.4TCCh. 5 - Prob. 5.5TCCh. 5 - Write a brief description of the relationships...Ch. 5 - Prob. 2CLECh. 5 - Prob. 3CLECh. 5 - Prob. 4CLECh. 5 - Prob. 5CLECh. 5 - Prob. 6CLECh. 5 - Prob. 7CLECh. 5 - What is the number of each type of subatomic...Ch. 5 - Naturally occurring lithium is composed of two...Ch. 5 - Prob. 3PECh. 5 - Prob. 4PECh. 5 - Prob. 5PE
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- The emission data in cps displayed in Table 1 is reported to two decimal places by the chemist. However, the instrument output is shown in Table 2. Table 2. Iron emission from ICP-AES Sample Blank Standard Emission, cps 579.503252562 9308340.13122 Unknown Sample 343.232365741 Did the chemist make the correct choice in how they choose to display the data up in Table 1? Choose the best explanation from the choices below. No. Since the instrument calculates 12 digits for all values, they should all be kept and not truncated. Doing so would eliminate significant information. No. Since the instrument calculates 5 decimal places for the standard, all of the values should be limited to the same number. The other decimal places are not significant for the blank and unknown sample. Yes. The way Saman made the standards was limited by the 250-mL volumetric flask. This glassware can report values to 2 decimal places, and this establishes our number of significant figures. Yes. Instrumental data…arrow_forwardSteps and explanation pleasearrow_forwardSteps and explanation to undertand concepts.arrow_forward
- Nonearrow_forward7. Draw a curved arrow mechanism for the following reaction. HO cat. HCI OH in dioxane with 4A molecular sievesarrow_forwardTry: Convert the given 3D perspective structure to Newman projection about C2 - C3 bond (C2 carbon in the front). Also, show Newman projection of other possible staggered conformers and circle the most stable conformation. Use the template shown. F H3C Br Harrow_forward
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