Chemistry: Structure and Properties Custom Edition for Rutgers University General Chemistry
15th Edition
ISBN: 9781269935678
Author: Nivaldo J. Tro
Publisher: Pearson Education
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Chapter 5, Problem 45E
The lattice energy of CsF is -744 kJ/mol, whereas that of BaO is -3029 kJ/mol. Explain this large difference in lattice energy.
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The lattice energy of CsF is -744 kJ/mol, whereas that of BaO is -3029 kJ/mol. Explain this large difference in lattice energy.
9. Given the information below, determine the lattice energy of MgCl2.
Mg(s) - Mg(g)
DH°f = +147.1 kJ/mol
½ Cl2(g) – CI(g)
DH2°f =
+122 kJ/mol
Mg(g) – Mg*(g) DH3°t = +738 kJ/mol
Mg*(g)
Mg* (g)
DH4°F = +1450
kJ/mol
Cl(g) - Cl (g) DH5°f = -349 kJ/mol
Mg(s) + Cl2(g) – MgCl2(s) DH6°r = -641 kJ/mol
Cyanamide is a compound containing two hydrogen atoms and some amount of C and N. There are a total of 5 atoms in the compound. The products of combustion were found to be CO2, NO2, and H2O. If the enthalpy of combustion for cyanamide is – 671.9 kJ/mol and the enthalpy of formation is 58.8 kJ/mol, what is the chemical formula for cyanamide? ( ΔfH (CO2) = - 393.51 kJ/mole; ΔfH (NO2) = + 33.10 kJ/mole; ΔfH (H2O) = - 241.826 kJ/mole)
Chapter 5 Solutions
Chemistry: Structure and Properties Custom Edition for Rutgers University General Chemistry
Ch. 5 - What is the empirical formula of the compound with...Ch. 5 - Which substance is an ionic compound? He N2O4 CCl4...Ch. 5 - Prob. 3SAQCh. 5 - Prob. 4SAQCh. 5 - Prob. 5SAQCh. 5 - Prob. 6SAQCh. 5 - Prob. 7SAQCh. 5 - What is the correct Lewis symbol for S?Ch. 5 - How many CH2Cl2 molecules are there in 25.0 g of...Ch. 5 - List the elements in the compound CF2Cl2 in order...
Ch. 5 - Determine the mass of potassium in 35.5 g of KBr....Ch. 5 - A compound is 52.14% C, 13.13% H, and 34.73% O by...Ch. 5 - A compound has the empirical formula CH2O and a...Ch. 5 - Combustion of 30.42 g of a compound containing...Ch. 5 - How do the properties of compounds compare to the...Ch. 5 - What is a chemical bond? 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Why is it...Ch. 5 - Which kinds of conversion factors are inherent in...Ch. 5 - Which kind of chemical formula can be obtained...Ch. 5 - Prob. 26ECh. 5 - Prob. 27ECh. 5 - Prob. 28ECh. 5 - Prob. 29ECh. 5 - Prob. 30ECh. 5 - Prob. 31ECh. 5 - Determine the empirical formula for the compound...Ch. 5 - Determine the number of each type of atom in each...Ch. 5 - Determine the number of each type of atom in each...Ch. 5 - Write a chemical formula for each molecular model....Ch. 5 - Prob. 36ECh. 5 - Prob. 37ECh. 5 - Write an electron configuration for Ne. Then write...Ch. 5 - Prob. 39ECh. 5 - Write a Lewis symbol for each atom or ion. a. S2-...Ch. 5 - Prob. 41ECh. 5 - Write the Lewis symbols that represent the ions in...Ch. 5 - Prob. 43ECh. 5 - Prob. 44ECh. 5 - The lattice energy of CsF is -744 kJ/mol, whereas...Ch. 5 - Rubidium iodide has a lattice energy of-617...Ch. 5 - Prob. 47ECh. 5 - Prob. 48ECh. 5 - Prob. 49ECh. 5 - Prob. 50ECh. 5 - Prob. 51ECh. 5 - Prob. 52ECh. 5 - Prob. 53ECh. 5 - Prob. 54ECh. 5 - Prob. 55ECh. 5 - Prob. 56ECh. 5 - Prob. 57ECh. 5 - Prob. 58ECh. 5 - Prob. 59ECh. 5 - Prob. 60ECh. 5 - Use covalent Lewis structures to explain why each...Ch. 5 - Use covalent Lewis structures to explain why the...Ch. 5 - Prob. 63ECh. 5 - Prob. 64ECh. 5 - Prob. 65ECh. 5 - Prob. 66ECh. 5 - Name each compound. (Refer to the nomenclature...Ch. 5 - Prob. 68ECh. 5 - Prob. 69ECh. 5 - Prob. 70ECh. 5 - Calculate the formula mass for each compound. NO2...Ch. 5 - Prob. 72ECh. 5 - Calculate the number of moles in each sample 72.5...Ch. 5 - Calculate the mass of each sample 15.7 mol HNO3...Ch. 5 - Determine the number of moles (of molecules or...Ch. 5 - Determine the number of moles (of molecules or...Ch. 5 - How many molecules are in each sample? 6.5 g H2O...Ch. 5 - Prob. 78ECh. 5 - Calculate the mass (in g) of each sample. 5.94 x...Ch. 5 - Calculate the mass (in g) of each sample 4.5 x...Ch. 5 - A sugar crystal contains approximately 1.8 x 1017...Ch. 5 - A salt crystal has a mass of 0.12 mg. How many...Ch. 5 - Calculate the mass percent composition of carbon...Ch. 5 - Calculate the mass percent composition of nitrogen...Ch. 5 - Most fertilizers consist of nitrogen-containing...Ch. 5 - Iron in the earth is in the form of iron ore....Ch. 5 - Copper(ll) fluoride contains 37.42% F by mass....Ch. 5 - Silver chloride, often used in silver plating,...Ch. 5 - The iodide ion is a dietary mineral essential to...Ch. 5 - The American Dental Association recommends that an...Ch. 5 - Write a ratio showing the relationship between the...Ch. 5 - Write a ratio showing the relationship between the...Ch. 5 - Determine the number of moles of hydrogen atoms in...Ch. 5 - Determine the number of moles of oxygen atoms in...Ch. 5 - Calculate mass (in grams) of sodium in 8.5 g of...Ch. 5 - Calculate the mass (in kilograms) of chlorine in...Ch. 5 - A chemist decomposes samples of several compounds;...Ch. 5 - A chemist decomposes samples of several compounds;...Ch. 5 - Calculate the empirical formula for each stimulant...Ch. 5 - Calculate the empirical formula for each natural...Ch. 5 - The elemental mass percent composition of...Ch. 5 - The elemental mass percent composition of ascorbic...Ch. 5 - A 0.77-mg sample of nitrogen reacts with chlorine...Ch. 5 - A 45.2-mg sample of phosphorus reacts with...Ch. 5 - The empirical formula and molar mass of several...Ch. 5 - The malar mass and empirical formula of several...Ch. 5 - Combustion analysis of a hydrocarbon produced...Ch. 5 - Combustion analysis of naphthalene, a hydrocarbon...Ch. 5 - The foul odor of rancid butter is due largely to...Ch. 5 - Tartaric acid is the white, powdery substance that...Ch. 5 - Prob. 111ECh. 5 - Prob. 112ECh. 5 - Prob. 113ECh. 5 - Prob. 114ECh. 5 - How many molecules of ethanol (C2H5OH) (the...Ch. 5 - A drop of water has a volume of approximately 0.05...Ch. 5 - Determine the chemical formula of each compound...Ch. 5 - Determine the chemical formula of each compound...Ch. 5 - A Freon™ leak in the air conditioning system of an...Ch. 5 - Prob. 120ECh. 5 - A metal (M) forms a compound with the formula...Ch. 5 - A metal (M) forms an oxide with the formula M2O....Ch. 5 - Estradiol is a female sexual hormone that causes...Ch. 5 - Fructose is a common sugar found in fruit....Ch. 5 - Combustion analysis of a 13.42-g sample of equilin...Ch. 5 - Prob. 126ECh. 5 - Epsom salts is a hydrated ionic compound with the...Ch. 5 - A hydrate of copper(ll) chloride has the following...Ch. 5 - A compound of molar mass 177 g/mol contains only...Ch. 5 - Researchers obtain the following data from...Ch. 5 - Find the total number of atoms in a sample of...Ch. 5 - Vanadium forms four different oxides in which the...Ch. 5 - The chloride of an unknown metal is believed to...Ch. 5 - Prob. 134ECh. 5 - A chromium-containing compound has the formula...Ch. 5 - Prob. 136ECh. 5 - Prob. 137ECh. 5 - Prob. 138ECh. 5 - A mixture of NaCI and NaBr has a mass of 2.00 g...Ch. 5 - Three pure compounds form when 1.00-g samples of...Ch. 5 - A mixture of CaCO3 and (NH4)2CO3is 61.9% CO3 by...Ch. 5 - A mixture of 50.0 g of S and 1.00 x 102 g of CI2...Ch. 5 - Because of increasing evidence of damage to the...Ch. 5 - A particular coal contains 2.55% sulfur by mass....Ch. 5 - Lead is found in Earth’s crust as several...Ch. 5 - A 2.52-g sample of a compound containing only...Ch. 5 - Prob. 147ECh. 5 - The elements X and Y form a compound that is 40% X...Ch. 5 - A compound of X and Y is 13 X by mass. 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- What main factors control the magnitude of lattice energies? Give a specific example of a compound that should have a high lattice energy, and explain why its lattice energy is high.arrow_forwardUsing the standard enthalpy of formation data in Appendix G, calculate the bond energy of the carbon-sulfur double bond in CS2.arrow_forwardhat does temperature measure? Are the molecules in a beaker of warm water moving at the same speed as the molecules in a beaker of cold water? Explain? What is heat? Is heat the same as temperature?arrow_forward
- A compound with a molar mass of about 42 g/mol contains 85.7% carbon and 14.3% hydrogen. What is its molecular structure?arrow_forwardFor each of the following, write an equation that corresponds to the energy given. a. lattice energy of NaCl b. lattice energy of NH4Br c. lattice energy of MgS d. O9O double bond energy beginning with O2(g) as a reactantarrow_forwardUsing the bond energies in Table 7.2, determine the approximate enthalpy change for each of the following reactions: (a) Cl2(g)+3F2(g)2ClF3(g) (b) H2C=CH2(g)+H2(g)H3CCH3(g) (c) 2C2H6(g)+7O2(g)4CO2(g)+6H2O(g) .arrow_forward
- Use data in this chapter (and Chapter 2) to discuss why MgO is an ionic compound but CO is not an ionic compound.arrow_forwardArrange the following series of compounds in order of increasing lattice energies. (a) NaBr, NaCl, KBr (b) MgO, CaO, CaCl2 (c) LiF, BeF2, BeOarrow_forwardFor which of the following substances is the least energy required to convert one mole of the solid into separate ions? (a) MgO (b) SrO (c) KF (d) CsF (e) MgF2arrow_forward
- List the following ionic compounds in order of increasing lattice energy. CaO, MgO, KF, and RbFarrow_forwardLattice Energy is the energy released when propane gas is burned in oxygen. true or false.arrow_forwardThe lattice energy of NaCl is 769 kJ/mole. Which of the following is a correct statement about NaCl? When one mole each of gaseous Nat and CI- ions form solid NaCl, 769 kJ of heat is consumed. It requires 769 kJ to separate one mole of solid NaCl into one mole of each gaseous Na* and CI- ions. It requires 769 kJ to separate one mole of solid NaCl into gaseous one mole of Na* and two moles of CI- ions.arrow_forward
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