Chemistry: Structure and Properties Custom Edition for Rutgers University General Chemistry
15th Edition
ISBN: 9781269935678
Author: Nivaldo J. Tro
Publisher: Pearson Education
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Chapter 5, Problem 138E
Interpretation Introduction
To determine:
The amount of ore to obtain 1.00 kg phosphorus
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that NH3 is a weak base.
acids: ☐
1.8 mol of HCl is added to
1.0 L of a 1.0M NH3
bases: ☐
solution.
other: ☐
0.18 mol of HNO3 is added
to 1.0 L of a solution that is
1.4M in both NH3 and
NH₁Br.
acids:
bases: ☐
other: ☐
0,0,...
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18
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NH3 (g) = N2 (g) +3H₂
—N2 (g) AGº = 34. kJ
Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this
system:
rise
Under these conditions, will the pressure of NH 3 tend to rise or fall?
☐ x10
fall
Х
Is it possible to reverse this tendency by adding H₂?
In other words, if you said the pressure of NH 3 will tend to rise, can that
be changed to a tendency to fall by adding H₂? Similarly, if you said the
pressure of NH3 will tend to fall, can that be changed to a tendency to
rise by adding H₂?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of H₂ needed to reverse it.
Round your answer to 2 significant digits.
yes
no
atm
00.
18
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HF is a weak acid.
2.2 mol of NaOH is added to
1.0 L of a 1.4M HF
solution.
acids:
П
bases:
Х
other: ☐
ப
acids:
0.51 mol of KOH is added to
1.0 L of a solution that is
bases:
1.3M in both HF and NaF.
other: ☐
00.
18
Ar
Chapter 5 Solutions
Chemistry: Structure and Properties Custom Edition for Rutgers University General Chemistry
Ch. 5 - What is the empirical formula of the compound with...Ch. 5 - Which substance is an ionic compound? He N2O4 CCl4...Ch. 5 - Prob. 3SAQCh. 5 - Prob. 4SAQCh. 5 - Prob. 5SAQCh. 5 - Prob. 6SAQCh. 5 - Prob. 7SAQCh. 5 - What is the correct Lewis symbol for S?Ch. 5 - How many CH2Cl2 molecules are there in 25.0 g of...Ch. 5 - List the elements in the compound CF2Cl2 in order...
Ch. 5 - Determine the mass of potassium in 35.5 g of KBr....Ch. 5 - A compound is 52.14% C, 13.13% H, and 34.73% O by...Ch. 5 - A compound has the empirical formula CH2O and a...Ch. 5 - Combustion of 30.42 g of a compound containing...Ch. 5 - How do the properties of compounds compare to the...Ch. 5 - What is a chemical bond? Why do chemical bonds...Ch. 5 - Explain the difference between an ionic bond and a...Ch. 5 - List and describe the different ways to represent...Ch. 5 - What is the difference between an empirical...Ch. 5 - Prob. 6ECh. 5 - Prob. 7ECh. 5 - Prob. 8ECh. 5 - How can you use Lewis structures to determine the...Ch. 5 - What is lattice energy?Ch. 5 - Why is the formation of solid sodium chloride from...Ch. 5 - Prob. 12ECh. 5 - Prob. 13ECh. 5 - Prob. 14ECh. 5 - Prob. 15ECh. 5 - Prob. 16ECh. 5 - Prob. 17ECh. 5 - How does the Lewis model for covalent bonding...Ch. 5 - Explain howto nans molecular inorganic compounds.Ch. 5 - Prob. 20ECh. 5 - What is the formula mass for a compound? Why is it...Ch. 5 - Explain how the information in a chemical formula...Ch. 5 - What is mass percent composition? Why is it...Ch. 5 - Which kinds of conversion factors are inherent in...Ch. 5 - Which kind of chemical formula can be obtained...Ch. 5 - Prob. 26ECh. 5 - Prob. 27ECh. 5 - Prob. 28ECh. 5 - Prob. 29ECh. 5 - Prob. 30ECh. 5 - Prob. 31ECh. 5 - Determine the empirical formula for the compound...Ch. 5 - Determine the number of each type of atom in each...Ch. 5 - Determine the number of each type of atom in each...Ch. 5 - Write a chemical formula for each molecular model....Ch. 5 - Prob. 36ECh. 5 - Prob. 37ECh. 5 - Write an electron configuration for Ne. Then write...Ch. 5 - Prob. 39ECh. 5 - Write a Lewis symbol for each atom or ion. a. S2-...Ch. 5 - Prob. 41ECh. 5 - Write the Lewis symbols that represent the ions in...Ch. 5 - Prob. 43ECh. 5 - Prob. 44ECh. 5 - The lattice energy of CsF is -744 kJ/mol, whereas...Ch. 5 - Rubidium iodide has a lattice energy of-617...Ch. 5 - Prob. 47ECh. 5 - Prob. 48ECh. 5 - Prob. 49ECh. 5 - Prob. 50ECh. 5 - Prob. 51ECh. 5 - Prob. 52ECh. 5 - Prob. 53ECh. 5 - Prob. 54ECh. 5 - Prob. 55ECh. 5 - Prob. 56ECh. 5 - Prob. 57ECh. 5 - Prob. 58ECh. 5 - Prob. 59ECh. 5 - Prob. 60ECh. 5 - Use covalent Lewis structures to explain why each...Ch. 5 - Use covalent Lewis structures to explain why the...Ch. 5 - Prob. 63ECh. 5 - Prob. 64ECh. 5 - Prob. 65ECh. 5 - Prob. 66ECh. 5 - Name each compound. (Refer to the nomenclature...Ch. 5 - Prob. 68ECh. 5 - Prob. 69ECh. 5 - Prob. 70ECh. 5 - Calculate the formula mass for each compound. NO2...Ch. 5 - Prob. 72ECh. 5 - Calculate the number of moles in each sample 72.5...Ch. 5 - Calculate the mass of each sample 15.7 mol HNO3...Ch. 5 - Determine the number of moles (of molecules or...Ch. 5 - Determine the number of moles (of molecules or...Ch. 5 - How many molecules are in each sample? 6.5 g H2O...Ch. 5 - Prob. 78ECh. 5 - Calculate the mass (in g) of each sample. 5.94 x...Ch. 5 - Calculate the mass (in g) of each sample 4.5 x...Ch. 5 - A sugar crystal contains approximately 1.8 x 1017...Ch. 5 - A salt crystal has a mass of 0.12 mg. 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