Introduction to General, Organic and Biochemistry
12th Edition
ISBN: 9780357391594
Author: Frederick A. Bettelheim; William H. Brown; Mary K. Campbell
Publisher: Cengage Learning US
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Chapter 5, Problem 44P
5-54 Automobile air bags are inflated by nitrogen gas. When a significant collision occurs, an electronic sensor triggers the decomposition of sodium azide to form nitrogen gas and sodium metal. The nitrogen gas then inflates nylon bags, which protect the driver and front-seat passenger from impact with the dashboard and windshield.
What volume of nitrogen gas measured at 1 atm and 27°C is formed by the decomposition of 100. g of sodium azide?
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(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to
glucose, C6H12O6, and fructose C6H12O6, in acidic solution:
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[sucrose]/mol dm³
t/min
0
0.316
14
0.300
39
0.274
60
0.256
80
0.238
110
0.211
(i) Graphically prove the order of the reaction and determine the rate constant of the
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(ii) Determine the half-life, t½ for the hydrolysis of sucrose.
(III) adsorbent
(b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous
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isotherm, yielding the following values of Kat pH = 6.5:
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T/K
10-10 K
280
2.505
295
1.819
310
1.364
325
1.050
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Chapter 5 Solutions
Introduction to General, Organic and Biochemistry
Ch. 5.3 - Prob. 5.1QCCh. 5.3 - Prob. 5.2QCCh. 5.3 - Prob. 5.3QCCh. 5.4 - Prob. 5.4QCCh. 5.4 - Prob. 5.5QCCh. 5.4 - Prob. 5.6QCCh. 5.5 - Prob. 5.7QCCh. 5.7 - Problem 5-8 Will the molecules in each set form a...Ch. 5 - Prob. 1PCh. 5 - Prob. 2P
Ch. 5 - Prob. 3PCh. 5 - Prob. 4PCh. 5 - Prob. 5PCh. 5 - 5-16 Answer true or false. (a) For a sample of gas...Ch. 5 - Prob. 7PCh. 5 - Prob. 8PCh. 5 - Prob. 9PCh. 5 - Prob. 10PCh. 5 - Prob. 11PCh. 5 - Prob. 12PCh. 5 - Prob. 13PCh. 5 - Prob. 14PCh. 5 - 5-25 A gas in a bulb as in Figure 5-3 registers a...Ch. 5 - Prob. 16PCh. 5 - 5-27 A sample of the inhalation anesthetic gas...Ch. 5 - Prob. 18PCh. 5 - Prob. 19PCh. 5 - Prob. 20PCh. 5 - 5-31 A balloon used for atmospheric research has a...Ch. 5 - Prob. 22PCh. 5 - 5-33 A certain quantity of helium gas is at a...Ch. 5 - 5-34 A sample of 30.0 mL of krypton gas, Kr, is at...Ch. 5 - 5-35 A 26.4-mL sample of ethylene gas, C2H4, has a...Ch. 5 - Prob. 26PCh. 5 - 5-37 A sample of a gas at 77°C and 1.33 atm...Ch. 5 - 5-38 What is the volume in liters occupied by 1.21...Ch. 5 - 5-39 An 8.00-g sample of a gas occupies 22.4 L at...Ch. 5 - Prob. 30PCh. 5 - 5-41 Does the density of a gas increase, decrease,...Ch. 5 - Prob. 32PCh. 5 - Prob. 33PCh. 5 - Prob. 34PCh. 5 - Prob. 35PCh. 5 - 5-46 Calculate the molar mass of a gas if 3.30 g...Ch. 5 - Prob. 37PCh. 5 - Prob. 38PCh. 5 - Prob. 39PCh. 5 - 5-50 How many molecules of CO are in 100. L of CO...Ch. 5 - Prob. 41PCh. 5 - Prob. 42PCh. 5 - Prob. 43PCh. 5 - 5-54 Automobile air bags are inflated by nitrogen...Ch. 5 - Prob. 45PCh. 5 - 5-56 The three main components of dry air and the...Ch. 5 - Prob. 47PCh. 5 - Prob. 48PCh. 5 - Prob. 49PCh. 5 - Prob. 50PCh. 5 - Prob. 51PCh. 5 - Prob. 52PCh. 5 - Prob. 53PCh. 5 - Prob. 54PCh. 5 - Prob. 55PCh. 5 - Prob. 56PCh. 5 - Prob. 57PCh. 5 - Prob. 58PCh. 5 - Prob. 59PCh. 5 - Prob. 60PCh. 5 - Prob. 61PCh. 5 - Prob. 62PCh. 5 - 5-89 (Chemical Connections 5C) In a...Ch. 5 - Prob. 64PCh. 5 - Prob. 65PCh. 5 - Prob. 66PCh. 5 - Prob. 67PCh. 5 - Prob. 68PCh. 5 - Prob. 69PCh. 5 - Prob. 70PCh. 5 - Prob. 71PCh. 5 - Prob. 72PCh. 5 - Prob. 73PCh. 5 - Prob. 74PCh. 5 - Prob. 75PCh. 5 - Prob. 76PCh. 5 - Prob. 77PCh. 5 - 5-106 The normal boiling point of hexane, C6H14,...Ch. 5 - 5-107 If 60.0 g of NH3 occupies 35.1 L under a...Ch. 5 - Prob. 80PCh. 5 - Prob. 81PCh. 5 - Prob. 82PCh. 5 - 5-111 Diving, particularly SCUBA (Self-Contained...Ch. 5 - Prob. 84PCh. 5 - 5-113 Ammonia and gaseous hydrogen chloride react...Ch. 5 - 5-114 Carbon dioxide gas, saturated with water...Ch. 5 - 5-115 Ammonium nitrite decomposes upon heating to...Ch. 5 - 5-118 Isooctane, which has a chemical formula...Ch. 5 - Prob. 89PCh. 5 - Prob. 90PCh. 5 - Prob. 91PCh. 5 - Prob. 92P
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