Introduction to General, Organic and Biochemistry
12th Edition
ISBN: 9780357391594
Author: Frederick A. Bettelheim; William H. Brown; Mary K. Campbell
Publisher: Cengage Learning US
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Question
Chapter 5, Problem 80P
Interpretation Introduction
Interpretation:
Why hydrogen sulfite, a heavier molecule than water is gas at STP should be explained?
Concept Introduction:
The state of the matter depends on the intermolecular forces of attraction in between the molecules. There are three state of matter namely, solid, liquid and gases. The order of intermolecular forces within the particles in these states is as follows:
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter 5 Solutions
Introduction to General, Organic and Biochemistry
Ch. 5.3 - Prob. 5.1QCCh. 5.3 - Prob. 5.2QCCh. 5.3 - Prob. 5.3QCCh. 5.4 - Prob. 5.4QCCh. 5.4 - Prob. 5.5QCCh. 5.4 - Prob. 5.6QCCh. 5.5 - Prob. 5.7QCCh. 5.7 - Problem 5-8 Will the molecules in each set form a...Ch. 5 - Prob. 1PCh. 5 - Prob. 2P
Ch. 5 - Prob. 3PCh. 5 - Prob. 4PCh. 5 - Prob. 5PCh. 5 - 5-16 Answer true or false. (a) For a sample of gas...Ch. 5 - Prob. 7PCh. 5 - Prob. 8PCh. 5 - Prob. 9PCh. 5 - Prob. 10PCh. 5 - Prob. 11PCh. 5 - Prob. 12PCh. 5 - Prob. 13PCh. 5 - Prob. 14PCh. 5 - 5-25 A gas in a bulb as in Figure 5-3 registers a...Ch. 5 - Prob. 16PCh. 5 - 5-27 A sample of the inhalation anesthetic gas...Ch. 5 - Prob. 18PCh. 5 - Prob. 19PCh. 5 - Prob. 20PCh. 5 - 5-31 A balloon used for atmospheric research has a...Ch. 5 - Prob. 22PCh. 5 - 5-33 A certain quantity of helium gas is at a...Ch. 5 - 5-34 A sample of 30.0 mL of krypton gas, Kr, is at...Ch. 5 - 5-35 A 26.4-mL sample of ethylene gas, C2H4, has a...Ch. 5 - Prob. 26PCh. 5 - 5-37 A sample of a gas at 77°C and 1.33 atm...Ch. 5 - 5-38 What is the volume in liters occupied by 1.21...Ch. 5 - 5-39 An 8.00-g sample of a gas occupies 22.4 L at...Ch. 5 - Prob. 30PCh. 5 - 5-41 Does the density of a gas increase, decrease,...Ch. 5 - Prob. 32PCh. 5 - Prob. 33PCh. 5 - Prob. 34PCh. 5 - Prob. 35PCh. 5 - 5-46 Calculate the molar mass of a gas if 3.30 g...Ch. 5 - Prob. 37PCh. 5 - Prob. 38PCh. 5 - Prob. 39PCh. 5 - 5-50 How many molecules of CO are in 100. L of CO...Ch. 5 - Prob. 41PCh. 5 - Prob. 42PCh. 5 - Prob. 43PCh. 5 - 5-54 Automobile air bags are inflated by nitrogen...Ch. 5 - Prob. 45PCh. 5 - 5-56 The three main components of dry air and the...Ch. 5 - Prob. 47PCh. 5 - Prob. 48PCh. 5 - Prob. 49PCh. 5 - Prob. 50PCh. 5 - Prob. 51PCh. 5 - Prob. 52PCh. 5 - Prob. 53PCh. 5 - Prob. 54PCh. 5 - Prob. 55PCh. 5 - Prob. 56PCh. 5 - Prob. 57PCh. 5 - Prob. 58PCh. 5 - Prob. 59PCh. 5 - Prob. 60PCh. 5 - Prob. 61PCh. 5 - Prob. 62PCh. 5 - 5-89 (Chemical Connections 5C) In a...Ch. 5 - Prob. 64PCh. 5 - Prob. 65PCh. 5 - Prob. 66PCh. 5 - Prob. 67PCh. 5 - Prob. 68PCh. 5 - Prob. 69PCh. 5 - Prob. 70PCh. 5 - Prob. 71PCh. 5 - Prob. 72PCh. 5 - Prob. 73PCh. 5 - Prob. 74PCh. 5 - Prob. 75PCh. 5 - Prob. 76PCh. 5 - Prob. 77PCh. 5 - 5-106 The normal boiling point of hexane, C6H14,...Ch. 5 - 5-107 If 60.0 g of NH3 occupies 35.1 L under a...Ch. 5 - Prob. 80PCh. 5 - Prob. 81PCh. 5 - Prob. 82PCh. 5 - 5-111 Diving, particularly SCUBA (Self-Contained...Ch. 5 - Prob. 84PCh. 5 - 5-113 Ammonia and gaseous hydrogen chloride react...Ch. 5 - 5-114 Carbon dioxide gas, saturated with water...Ch. 5 - 5-115 Ammonium nitrite decomposes upon heating to...Ch. 5 - 5-118 Isooctane, which has a chemical formula...Ch. 5 - Prob. 89PCh. 5 - Prob. 90PCh. 5 - Prob. 91PCh. 5 - Prob. 92P
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