ORGANIC CHEMISTRY BOOK& SG/SM
ORGANIC CHEMISTRY BOOK& SG/SM
6th Edition
ISBN: 9781264094493
Author: SMITH
Publisher: MCG
Question
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Chapter 5, Problem 41P
Interpretation Introduction

(a)

Interpretation: The classification of the given pair of compounds as constitutional isomers, stereoisomers, or not isomers is to be done.

Concept introduction: Isomers are the compounds with similar formula and different structures. Stereoisomers are a type of isomers in which arrangement of atoms differ in space. Or the compounds that have same molecular formula but they differ in the arrangement of atoms or groups in the space are known as stereoisomers.

Constitutional isomers are having the same molecular formula and different bond connectivity between the atoms.

Interpretation Introduction

(b)

Interpretation: The classification of the given pair of compounds as constitutional isomers, stereoisomers, or not isomers is to be done.

Concept introduction: Isomers are the compounds with similar formula and different structures. Stereoisomers are a type of isomers in which arrangement of atoms differ in space. Or the compounds that have same molecular formula but they differ in the arrangement of atoms or groups in the space are known as stereoisomers.

Constitutional isomers are having the same molecular formula and different bond connectivity between the atoms.

Interpretation Introduction

(c)

Interpretation: The classification of the given pair of compounds as constitutional isomers, stereoisomers, or not isomers is to be done.

Concept introduction: Isomers are the compounds with similar formula and different structures. Stereoisomers are a type of isomers in which arrangement of atoms differ in space. Or the compounds that have same molecular formula but they differ in the arrangement of atoms or groups in the space are known as stereoisomers.

Constitutional isomers are having the same molecular formula and different bond connectivity between the atoms.

Interpretation Introduction

(d)

Interpretation: The classification of the given pair of compounds as constitutional isomers, stereoisomers, or not isomers is to be done.

Concept introduction: Isomers are the compounds with similar formula and different structures. Stereoisomers are a type of isomers in which arrangement of atoms differ in space. Or the compounds that have same molecular formula but they differ in the arrangement of atoms or groups in the space are known as stereoisomers.

Constitutional isomers are having the same molecular formula and different bond connectivity between the atoms.

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10
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