The larger ion among the pair S − 2 and Cl − should be determined. Concept introduction: Atomic radii of atoms of elements down the group increase as Z increases because new shells are introduced and therefore the distance between nucleus and valence shell increases. Along a period, size or radii decreases as the electrons are introduced into the same shell and are pulled by higher nuclear charge.

Question

6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?

Answer 1

Question

Chapter 5, Problem 36P

a)

Interpretation Introduction

Interpretation: The larger ion among the pair S−2 and Cl− should be determined.

Concept introduction: Atomic radii of atoms of elements down the group increase as Z increases because new shells are introduced and therefore the distance between nucleus and valence shell increases. Along a period, size or radii decreases as the electrons are introduced into the same shell and are pulled by higher nuclear charge.

b)

Interpretation Introduction

Interpretation: The larger ions among the pair Tl+ and Tl+3 should be determined.

Concept introduction: Atomic radii of atoms of elements down the group increase as Z increases because new shells are introduced and therefore the distance between nucleus and valence shell increases. Along a period, size or radii decreases as the electrons are introduced into the same shell and are pulled by higher nuclear charge.

c)

Interpretation Introduction

Interpretation: The larger ion among the pair Ce+3 and Dy+3 should be determined.

Concept introduction: Atomic radii of atoms of elements down the group increase as Z increases because new shells are introduced and therefore the distance between nucleus and valence shell increases. Along a period, size or radii decreases as the electrons are introduced into the same shell and are pulled by higher nuclear charge.

d)

Interpretation Introduction

Interpretation: The larger ions among the pair S−2 and I− should be determined.

Concept introduction: Atomic radii of atoms of elements down the group increases as Z increases because new shells are introduced and therefore the distance between nucleus and valence shell increases. Along a period, size or radii decreases as the electrons are introduced into the same shell and are pulled by higher nuclear charge.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?

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Answer 2

Question

Chapter 5, Problem 36P

a)

Interpretation Introduction

Interpretation: The larger ion among the pair S−2 and Cl− should be determined.

Concept introduction: Atomic radii of atoms of elements down the group increase as Z increases because new shells are introduced and therefore the distance between nucleus and valence shell increases. Along a period, size or radii decreases as the electrons are introduced into the same shell and are pulled by higher nuclear charge.

b)

Interpretation Introduction

Interpretation: The larger ions among the pair Tl+ and Tl+3 should be determined.

Concept introduction: Atomic radii of atoms of elements down the group increase as Z increases because new shells are introduced and therefore the distance between nucleus and valence shell increases. Along a period, size or radii decreases as the electrons are introduced into the same shell and are pulled by higher nuclear charge.

c)

Interpretation Introduction

Interpretation: The larger ion among the pair Ce+3 and Dy+3 should be determined.

Concept introduction: Atomic radii of atoms of elements down the group increase as Z increases because new shells are introduced and therefore the distance between nucleus and valence shell increases. Along a period, size or radii decreases as the electrons are introduced into the same shell and are pulled by higher nuclear charge.

d)

Interpretation Introduction

Interpretation: The larger ions among the pair S−2 and I− should be determined.

Concept introduction: Atomic radii of atoms of elements down the group increases as Z increases because new shells are introduced and therefore the distance between nucleus and valence shell increases. Along a period, size or radii decreases as the electrons are introduced into the same shell and are pulled by higher nuclear charge.

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Answer 3

Question

Chapter 5, Problem 36P

a)

Interpretation Introduction

Interpretation: The larger ion among the pair S−2 and Cl− should be determined.

Concept introduction: Atomic radii of atoms of elements down the group increase as Z increases because new shells are introduced and therefore the distance between nucleus and valence shell increases. Along a period, size or radii decreases as the electrons are introduced into the same shell and are pulled by higher nuclear charge.

b)

Interpretation Introduction

Interpretation: The larger ions among the pair Tl+ and Tl+3 should be determined.

Concept introduction: Atomic radii of atoms of elements down the group increase as Z increases because new shells are introduced and therefore the distance between nucleus and valence shell increases. Along a period, size or radii decreases as the electrons are introduced into the same shell and are pulled by higher nuclear charge.

c)

Interpretation Introduction

Interpretation: The larger ion among the pair Ce+3 and Dy+3 should be determined.

Concept introduction: Atomic radii of atoms of elements down the group increase as Z increases because new shells are introduced and therefore the distance between nucleus and valence shell increases. Along a period, size or radii decreases as the electrons are introduced into the same shell and are pulled by higher nuclear charge.

d)

Interpretation Introduction

Interpretation: The larger ions among the pair S−2 and I− should be determined.

Concept introduction: Atomic radii of atoms of elements down the group increases as Z increases because new shells are introduced and therefore the distance between nucleus and valence shell increases. Along a period, size or radii decreases as the electrons are introduced into the same shell and are pulled by higher nuclear charge.

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Answer 4

Question

Chapter 5, Problem 36P

a)

Interpretation Introduction

Interpretation: The larger ion among the pair S−2 and Cl− should be determined.

Concept introduction: Atomic radii of atoms of elements down the group increase as Z increases because new shells are introduced and therefore the distance between nucleus and valence shell increases. Along a period, size or radii decreases as the electrons are introduced into the same shell and are pulled by higher nuclear charge.

b)

Interpretation Introduction

Interpretation: The larger ions among the pair Tl+ and Tl+3 should be determined.

Concept introduction: Atomic radii of atoms of elements down the group increase as Z increases because new shells are introduced and therefore the distance between nucleus and valence shell increases. Along a period, size or radii decreases as the electrons are introduced into the same shell and are pulled by higher nuclear charge.

c)

Interpretation Introduction

Interpretation: The larger ion among the pair Ce+3 and Dy+3 should be determined.

Concept introduction: Atomic radii of atoms of elements down the group increase as Z increases because new shells are introduced and therefore the distance between nucleus and valence shell increases. Along a period, size or radii decreases as the electrons are introduced into the same shell and are pulled by higher nuclear charge.

d)

Interpretation Introduction

Interpretation: The larger ions among the pair S−2 and I− should be determined.

Concept introduction: Atomic radii of atoms of elements down the group increases as Z increases because new shells are introduced and therefore the distance between nucleus and valence shell increases. Along a period, size or radii decreases as the electrons are introduced into the same shell and are pulled by higher nuclear charge.

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Answer 5

Chapter 5, Problem 36P

a)

Interpretation Introduction

Interpretation: The larger ion among the pair S−2 and Cl− should be determined.

Concept introduction: Atomic radii of atoms of elements down the group increase as Z increases because new shells are introduced and therefore the distance between nucleus and valence shell increases. Along a period, size or radii decreases as the electrons are introduced into the same shell and are pulled by higher nuclear charge.

b)

Interpretation Introduction

Interpretation: The larger ions among the pair Tl+ and Tl+3 should be determined.

Concept introduction: Atomic radii of atoms of elements down the group increase as Z increases because new shells are introduced and therefore the distance between nucleus and valence shell increases. Along a period, size or radii decreases as the electrons are introduced into the same shell and are pulled by higher nuclear charge.

c)

Interpretation Introduction

Interpretation: The larger ion among the pair Ce+3 and Dy+3 should be determined.

Concept introduction: Atomic radii of atoms of elements down the group increase as Z increases because new shells are introduced and therefore the distance between nucleus and valence shell increases. Along a period, size or radii decreases as the electrons are introduced into the same shell and are pulled by higher nuclear charge.

d)

Interpretation Introduction

Interpretation: The larger ions among the pair S−2 and I− should be determined.

Concept introduction: Atomic radii of atoms of elements down the group increases as Z increases because new shells are introduced and therefore the distance between nucleus and valence shell increases. Along a period, size or radii decreases as the electrons are introduced into the same shell and are pulled by higher nuclear charge.

Answer 6

Chapter 5, Problem 36P

a)

Interpretation Introduction

Interpretation: The larger ion among the pair S−2 and Cl− should be determined.

Concept introduction: Atomic radii of atoms of elements down the group increase as Z increases because new shells are introduced and therefore the distance between nucleus and valence shell increases. Along a period, size or radii decreases as the electrons are introduced into the same shell and are pulled by higher nuclear charge.

Answer 7

Chapter 5, Problem 36P

a)

Interpretation Introduction

Interpretation: The larger ion among the pair S−2 and Cl− should be determined.

Concept introduction: Atomic radii of atoms of elements down the group increase as Z increases because new shells are introduced and therefore the distance between nucleus and valence shell increases. Along a period, size or radii decreases as the electrons are introduced into the same shell and are pulled by higher nuclear charge.

Answer 8

b)

Interpretation Introduction

Interpretation: The larger ions among the pair Tl+ and Tl+3 should be determined.

Concept introduction: Atomic radii of atoms of elements down the group increase as Z increases because new shells are introduced and therefore the distance between nucleus and valence shell increases. Along a period, size or radii decreases as the electrons are introduced into the same shell and are pulled by higher nuclear charge.

Answer 9

b)

Interpretation Introduction

Interpretation: The larger ions among the pair Tl+ and Tl+3 should be determined.

Concept introduction: Atomic radii of atoms of elements down the group increase as Z increases because new shells are introduced and therefore the distance between nucleus and valence shell increases. Along a period, size or radii decreases as the electrons are introduced into the same shell and are pulled by higher nuclear charge.

Answer 10

c)

Interpretation Introduction

Interpretation: The larger ion among the pair Ce+3 and Dy+3 should be determined.

Concept introduction: Atomic radii of atoms of elements down the group increase as Z increases because new shells are introduced and therefore the distance between nucleus and valence shell increases. Along a period, size or radii decreases as the electrons are introduced into the same shell and are pulled by higher nuclear charge.

Answer 11

c)

Interpretation Introduction

Interpretation: The larger ion among the pair Ce+3 and Dy+3 should be determined.

Concept introduction: Atomic radii of atoms of elements down the group increase as Z increases because new shells are introduced and therefore the distance between nucleus and valence shell increases. Along a period, size or radii decreases as the electrons are introduced into the same shell and are pulled by higher nuclear charge.

Answer 12

d)

Interpretation Introduction

Interpretation: The larger ions among the pair S−2 and I− should be determined.

Concept introduction: Atomic radii of atoms of elements down the group increases as Z increases because new shells are introduced and therefore the distance between nucleus and valence shell increases. Along a period, size or radii decreases as the electrons are introduced into the same shell and are pulled by higher nuclear charge.

Answer 13

d)

Interpretation Introduction

Interpretation: The larger ions among the pair S−2 and I− should be determined.

Concept introduction: Atomic radii of atoms of elements down the group increases as Z increases because new shells are introduced and therefore the distance between nucleus and valence shell increases. Along a period, size or radii decreases as the electrons are introduced into the same shell and are pulled by higher nuclear charge.

Answer 14

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