The number of alkenes used to prepare methylcyclopentane by hydrogenation process has to be predicted. Concept introduction: The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation ( Δ H 0 ) . The most stable alkene has the smallest heat of hydrogenation. The stability of an alkene increases as the number of alkyl substituents bonded to its s p 2 carbon increases. The stability of an alkene increases as the number of hydrogen bonded to its s p 2 carbon decreases. Catalytic hydrogenation is the process of addition of hydrogen to a compound in the presence of a catalyst. The most common metal catalyst is palladium, which is used as a powder absorbed on charcoal to maximize its surface area. The metal catalyst is required to weaken the very strong H − H bond. A meso compound is a molecule with multiple stereocentres that is super imposable on its mirror image.

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Answer 1

Question

Chapter 5, Problem 34P

(a)

Interpretation Introduction

Interpretation:

The number of alkenes used to prepare methylcyclopentane by hydrogenation process has to be predicted.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

Catalytic hydrogenation is the process of addition of hydrogen to a compound in the presence of a catalyst. The most common metal catalyst is palladium, which is used as a powder absorbed on charcoal to maximize its surface area. The metal catalyst is required to weaken the very strong H−H bond.

A meso compound is a molecule with multiple stereocentres that is super imposable on its mirror image.

(b)

Interpretation Introduction

Interpretation:

Most stable alkene has to be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene decreases as the number of hydrogen bonded to its sp2 carbon decreases.

(c)

Interpretation Introduction

Interpretation:

The alkene which has the smallest heat of hydrogenation has to be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene decreases as the number of hydrogen bonded to its sp2 carbon decreases.

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MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10 Consider the following reaction: CH3OH(g) CO(g) + 2H2(g) (Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.) Part A Calculate AG for this reaction at 25 °C under the following conditions: PCH₂OH Pco PH2 0.815 atm = 0.140 atm 0.170 atm Express your answer in kilojoules to three significant figures. Ο ΑΣΦ AG = -150 Submit Previous Answers Request Answer □? kJ × Incorrect; Try Again; 2 attempts remaining Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship: AGrxn = AGrxn + RTInQ, AGxn+RTInQ, where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a is the reaction quotient. Provide Feedback Next >

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Answer 2

Question

Chapter 5, Problem 34P

(a)

Interpretation Introduction

Interpretation:

The number of alkenes used to prepare methylcyclopentane by hydrogenation process has to be predicted.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

Catalytic hydrogenation is the process of addition of hydrogen to a compound in the presence of a catalyst. The most common metal catalyst is palladium, which is used as a powder absorbed on charcoal to maximize its surface area. The metal catalyst is required to weaken the very strong H−H bond.

A meso compound is a molecule with multiple stereocentres that is super imposable on its mirror image.

(b)

Interpretation Introduction

Interpretation:

Most stable alkene has to be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene decreases as the number of hydrogen bonded to its sp2 carbon decreases.

(c)

Interpretation Introduction

Interpretation:

The alkene which has the smallest heat of hydrogenation has to be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene decreases as the number of hydrogen bonded to its sp2 carbon decreases.

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Answer 3

Question

Chapter 5, Problem 34P

(a)

Interpretation Introduction

Interpretation:

The number of alkenes used to prepare methylcyclopentane by hydrogenation process has to be predicted.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

Catalytic hydrogenation is the process of addition of hydrogen to a compound in the presence of a catalyst. The most common metal catalyst is palladium, which is used as a powder absorbed on charcoal to maximize its surface area. The metal catalyst is required to weaken the very strong H−H bond.

A meso compound is a molecule with multiple stereocentres that is super imposable on its mirror image.

(b)

Interpretation Introduction

Interpretation:

Most stable alkene has to be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene decreases as the number of hydrogen bonded to its sp2 carbon decreases.

(c)

Interpretation Introduction

Interpretation:

The alkene which has the smallest heat of hydrogenation has to be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene decreases as the number of hydrogen bonded to its sp2 carbon decreases.

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Answer 4

Question

Chapter 5, Problem 34P

(a)

Interpretation Introduction

Interpretation:

The number of alkenes used to prepare methylcyclopentane by hydrogenation process has to be predicted.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

Catalytic hydrogenation is the process of addition of hydrogen to a compound in the presence of a catalyst. The most common metal catalyst is palladium, which is used as a powder absorbed on charcoal to maximize its surface area. The metal catalyst is required to weaken the very strong H−H bond.

A meso compound is a molecule with multiple stereocentres that is super imposable on its mirror image.

(b)

Interpretation Introduction

Interpretation:

Most stable alkene has to be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene decreases as the number of hydrogen bonded to its sp2 carbon decreases.

(c)

Interpretation Introduction

Interpretation:

The alkene which has the smallest heat of hydrogenation has to be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene decreases as the number of hydrogen bonded to its sp2 carbon decreases.

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Answer 5

Chapter 5, Problem 34P

(a)

Interpretation Introduction

Interpretation:

The number of alkenes used to prepare methylcyclopentane by hydrogenation process has to be predicted.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

Catalytic hydrogenation is the process of addition of hydrogen to a compound in the presence of a catalyst. The most common metal catalyst is palladium, which is used as a powder absorbed on charcoal to maximize its surface area. The metal catalyst is required to weaken the very strong H−H bond.

A meso compound is a molecule with multiple stereocentres that is super imposable on its mirror image.

(b)

Interpretation Introduction

Interpretation:

Most stable alkene has to be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene decreases as the number of hydrogen bonded to its sp2 carbon decreases.

(c)

Interpretation Introduction

Interpretation:

The alkene which has the smallest heat of hydrogenation has to be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene decreases as the number of hydrogen bonded to its sp2 carbon decreases.

Answer 6

Chapter 5, Problem 34P

(a)

Interpretation Introduction

Interpretation:

The number of alkenes used to prepare methylcyclopentane by hydrogenation process has to be predicted.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

Catalytic hydrogenation is the process of addition of hydrogen to a compound in the presence of a catalyst. The most common metal catalyst is palladium, which is used as a powder absorbed on charcoal to maximize its surface area. The metal catalyst is required to weaken the very strong H−H bond.

A meso compound is a molecule with multiple stereocentres that is super imposable on its mirror image.

Answer 7

Chapter 5, Problem 34P

(a)

Interpretation Introduction

Interpretation:

The number of alkenes used to prepare methylcyclopentane by hydrogenation process has to be predicted.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

Catalytic hydrogenation is the process of addition of hydrogen to a compound in the presence of a catalyst. The most common metal catalyst is palladium, which is used as a powder absorbed on charcoal to maximize its surface area. The metal catalyst is required to weaken the very strong H−H bond.

A meso compound is a molecule with multiple stereocentres that is super imposable on its mirror image.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Most stable alkene has to be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene decreases as the number of hydrogen bonded to its sp2 carbon decreases.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Most stable alkene has to be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene decreases as the number of hydrogen bonded to its sp2 carbon decreases.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The alkene which has the smallest heat of hydrogenation has to be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene decreases as the number of hydrogen bonded to its sp2 carbon decreases.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The alkene which has the smallest heat of hydrogenation has to be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene decreases as the number of hydrogen bonded to its sp2 carbon decreases.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 5.1 - Prob. 1P Ch. 5.1 - Draw the structure for each of the following: a....Ch. 5.1 - What is each compounds systematic name?Ch. 5.3 - Prob. 4P Ch. 5.3 - Prob. 5P Ch. 5.3 - Prob. 7P Ch. 5.4 - a. For which reaction in each set below will S be...Ch. 5.6 - Prob. 9P Ch. 5.6 - How many different alkenes can be hydrogenated to...Ch. 5.6 - The same alkane is obtained from the catalytic...

Solution Summary: The author explains that the number of alkenes used to prepare methylcyclopentane by hydrogenation process has to be predicted.

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