ORGANIC CHEMISTRY (LL)-W/SOLN.>CUSTOM<
10th Edition
ISBN: 9781259972348
Author: Carey
Publisher: MCG CUSTOM
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Question
Chapter 5, Problem 33P
Interpretation Introduction
Interpretation:
The chemical equation of primary alcoholwith each of the given reagents is to be written.
Concept Introduction:
When alcohol treated with hydrogen halide typically undergoes nucleophilic substitution reaction to yield
Primary alcohol proceeds via
Alcohol reacts with sodium azide to yield sodium alkonate.
Alcohol reacts with sodium bromide in the presence of sulfuric acid and heat to yield alkyl halide.
When three moles of alcohol reacts with phosphorus tribromide to yield alkyl halide with phosphorous acid and hydrogen bromide.
When alcohols treated with thionyl chlorides react to yield alkyl chloride with sulfur dioxide and hydrogen chloride.
When alcohols treated with methyl sulfonyl chloride in the presence of pyridine react to yield butyl methanesulfonate.
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H
1) OsO4, pyridine
2) Na2SO3 or
NaHSO3 in H₂O
2 products
● Biological Macromolecules
Naming and drawing cyclic monosaccharides
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0/5
Give the complete common name, including anomer and stereochemistry labels, of the following molecules. You will find helpful information in the ALEKS
resource.
CH2OH
OH
OH
H
H
I
H
OH
OH
H]
H
CH2OH
H
OH
ẞ-L-sorbose
HOCH2
OH
OH H
HOCH2
H
OH OH
H
OH
H
H
CH2OH
OH
H
H
OH
H
I-
H
OH
H
OH
Explanation
Recheck
W
E
R
%
25
α
B
Y
X
&
5
D
F
G
H
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P
What is the missing reactant in this organic reaction?
+ R -A
HO
IN
+ H₂O
Specifically, in the drawing area below draw the skeletal ("line") structure of R.
If there is more than one reasonable answer, you can draw any one of them. If there is no reasonable answer, check the No answer
box under the drawing area.
Note for advanced students: you may assume no products other than those shown above are formed.
Explanation
Check
Click and drag to start drawing a
structure.
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Chapter 5 Solutions
ORGANIC CHEMISTRY (LL)-W/SOLN.>CUSTOM<
Ch. 5.1 - Prob. 1PCh. 5.1 - Prob. 2PCh. 5.1 - Many compounds contain more than one functional...Ch. 5.2 - Prob. 4PCh. 5.3 - Prob. 5PCh. 5.4 - Classify the isomeric C4H10O alcohols as being...Ch. 5.5 - Bromine is less electronegative than chlorine, yet...Ch. 5.6 - Prob. 8PCh. 5.7 - Prob. 9PCh. 5.8 - Prob. 10P
Ch. 5.8 - Prob. 11PCh. 5.9 - Carbocations are key intermediates in petroleum...Ch. 5.9 - Prob. 13PCh. 5.9 - Prob. 14PCh. 5.11 - Prob. 15PCh. 5.13 - Prob. 16PCh. 5.14 - For the reaction of a primary alcohol RCH2OH with...Ch. 5.15 - Prob. 18PCh. 5 - Write structural formulas for each of the...Ch. 5 - Prob. 20PCh. 5 - Prob. 21PCh. 5 - Write structural formulas for all the...Ch. 5 - Prob. 23PCh. 5 - Prob. 24PCh. 5 - Epichlorohydrin is the common name of an...Ch. 5 - Prob. 26PCh. 5 - Prob. 27PCh. 5 - Prob. 28PCh. 5 - Some of the most important organic compounds in...Ch. 5 - Prob. 30PCh. 5 - Prob. 31PCh. 5 - Prob. 32PCh. 5 - Prob. 33PCh. 5 - Prob. 34PCh. 5 - Prob. 35PCh. 5 - Prob. 36PCh. 5 - Prob. 37PCh. 5 - Prob. 38PCh. 5 - Prob. 39PCh. 5 - Prob. 40PCh. 5 - The reaction of 2,2-dimethyl-1-propanol...Ch. 5 - (a) Assuming that the rate-determining elementary...Ch. 5 - The reaction of 3-tert-butyl-3-pentanol with...Ch. 5 - Prob. 44PCh. 5 - Prob. 45PCh. 5 - Prob. 46DSPCh. 5 - Prob. 47DSPCh. 5 - Prob. 48DSPCh. 5 - Prob. 49DSPCh. 5 - Prob. 50DSPCh. 5 - Prob. 51DSPCh. 5 - Prob. 52DSP
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