BURDGE CHEMISTRY VALUE ED (LL)
4th Edition
ISBN: 9781259995958
Author: VALUE EDITION
Publisher: MCG CUSTOM
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Chapter 5, Problem 14QP
Interpretation Introduction
Interpretation:
The amount of work done on the system is to be calculated.
Concept introduction:
The first law of
The equation for the first law is as follows:
Here, U is the internal energy of the system, q is the heat given to or removed from the system, and w is the work done by or to the system.
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Draw the stepwise mechanism for the reactions
Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
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2
CH3
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NO2
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H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Chapter 5 Solutions
BURDGE CHEMISTRY VALUE ED (LL)
Ch. 5.1 - Practice Problem ATTEMPT
(a) Calculate the energy...Ch. 5.1 - Practice Problem BUILD
(a) Calculate the velocity...Ch. 5.1 - Prob. 1PPCCh. 5.1 - Prob. 1CPCh. 5.1 - How much greater is the electrostatic potential...Ch. 5.1 - Prob. 3CPCh. 5.1 - 5.1.4 The label on packaged food indicates that it...Ch. 5.1 - 5.1.5 Arrange the following pairs of charged...Ch. 5.1 - Prob. 6CPCh. 5.2 - Practice Problem ATTEMPT
Calculate the change in...
Ch. 5.2 - Practice ProblemBUILD Calculate the magnitude of q...Ch. 5.2 - Prob. 1PPCCh. 5.2 - Calculate the overall change in internal energy...Ch. 5.2 - Calculate w, and determine whether work is done by...Ch. 5.2 - Prob. 3CPCh. 5.2 - Prob. 4CPCh. 5.3 - Prob. 1PPACh. 5.3 - Prob. 1PPBCh. 5.3 - Prob. 1PPCCh. 5.3 - Given the thermochemical equation: H 2 ( g ) + Br...Ch. 5.3 - Given the thermochemical equation: 2Cu 2 O ( s ) →...Ch. 5.4 - Prob. 1PPACh. 5.4 - Prob. 1PPBCh. 5.4 - Prob. 1PPCCh. 5.4 - Prob. 1CPCh. 5.4 - Prob. 2CPCh. 5.4 - Prob. 3CPCh. 5.4 - 5.4.4 Quantities of 50.0 mL of 1.00 M HCl and 50.0...Ch. 5.5 - Prob. 1PPACh. 5.5 - Prob. 1PPBCh. 5.5 - Prob. 1PPCCh. 5.5 - Prob. 1CPCh. 5.5 - Prob. 2CPCh. 5.5 - 5.5.3 Each diagram shows a systems before and...Ch. 5.5 - Prob. 4CPCh. 5.6 - Prob. 1PPACh. 5.6 - Prob. 1PPBCh. 5.6 - Prob. 1PPCCh. 5.6 - Prob. 1CPCh. 5.6 - Prob. 2CPCh. 5.6 - Prob. 3CPCh. 5.6 - Prob. 4CPCh. 5.7 - Prob. 1PPACh. 5.7 - Prob. 1PPBCh. 5.7 - Prob. 1PPCCh. 5.8 - Prob. 1PPACh. 5.8 - Prob. 1PPBCh. 5.8 - Practice ProblemCONCEPTUALIZE The diagrams...Ch. 5.9 - Practice ProblemATTEMPT Use the following data to...Ch. 5.9 - Prob. 1PPBCh. 5.9 - Prob. 1PPCCh. 5 - Using data from Appendix 2, calculate the standard...Ch. 5 - Prob. 2KSPCh. 5 - Prob. 3KSPCh. 5 - Using only whole-number coefficients, the...Ch. 5 - Prob. 1QPCh. 5 - Prob. 2QPCh. 5 - Prob. 3QPCh. 5 - 5.4 A truck initially trawling at 60 km/h is...Ch. 5 - These are various forms of energy: chemical, heat,...Ch. 5 - 5.6 Define these terms: thermochemistry,...Ch. 5 - 5.7 Stoichiometry is based on the law of...Ch. 5 - Prob. 8QPCh. 5 - Decomposition reactions are usually endothermic,...Ch. 5 - Prob. 10QPCh. 5 - Prob. 11QPCh. 5 - Prob. 12QPCh. 5 - Prob. 13QPCh. 5 - Prob. 14QPCh. 5 - Prob. 15QPCh. 5 - Prob. 16QPCh. 5 - Prob. 17QPCh. 5 - Use the following diagrams for Problems 5.17 and...Ch. 5 - Consider these changes. (a) Hg ( t ) → Hg ( g )...Ch. 5 - Prob. 20QPCh. 5 - Prob. 21QPCh. 5 - 5.22 Explain the meaning of this thermochemical...Ch. 5 - Consider this reaction: 2 CH 3 OH ( l ) + 3 O 2 (...Ch. 5 - Prob. 24QPCh. 5 - Prob. 25QPCh. 5 - Prob. 26QPCh. 5 - Prob. 27QPCh. 5 - Prob. 28QPCh. 5 - Prob. 29QPCh. 5 - Prob. 30QPCh. 5 - Prob. 31QPCh. 5 - For most biological processes, the changes in...Ch. 5 - Prob. 33QPCh. 5 - 5.34 Define calorimetry and describe two commonly...Ch. 5 - A 6.22-kg piece of copper metal is heated from 20...Ch. 5 - Prob. 36QPCh. 5 - Prob. 37QPCh. 5 - A 0.1375-g sample of solid magnesium is burned in...Ch. 5 - A quantity of 2 .00 × 10 2 mL of 0 .862 M HCl is...Ch. 5 - 5.40 A 50.75 g sample of water at is added to a...Ch. 5 - A 25.95-g sample of methanol at 35 .6°C is added...Ch. 5 - Prob. 42QPCh. 5 - Prob. 43QPCh. 5 - Consider the following data: Metal Al Cu Mass(g)...Ch. 5 - Prob. 45QPCh. 5 - Prob. 46QPCh. 5 - Prob. 47QPCh. 5 - Prob. 48QPCh. 5 - Prob. 49QPCh. 5 - Prob. 50QPCh. 5 - Prob. 51QPCh. 5 - Prob. 52QPCh. 5 - Prob. 53QPCh. 5 - Prob. 54QPCh. 5 - 5.55 Each diagram shows a system before and after...Ch. 5 - Prob. 56QPCh. 5 - 5.57 Determine the value of for the following...Ch. 5 - Prob. 58QPCh. 5 - Prob. 59QPCh. 5 - Prob. 60QPCh. 5 - Prob. 61QPCh. 5 - Prob. 62QPCh. 5 - Prob. 63QPCh. 5 - Prob. 64QPCh. 5 - Prob. 65QPCh. 5 - Prob. 66QPCh. 5 - Prob. 67QPCh. 5 - Prob. 68QPCh. 5 - Prob. 69QPCh. 5 - Prob. 70QPCh. 5 - Prob. 71QPCh. 5 - Prob. 72QPCh. 5 - Prob. 73QPCh. 5 - Prob. 74QPCh. 5 - Pentaborane - 9 ( B 5 H 9 ) is a colorless, highly...Ch. 5 - Prob. 76QPCh. 5 - Prob. 77QPCh. 5 - Prob. 78QPCh. 5 - Prob. 79QPCh. 5 - Prob. 80QPCh. 5 - Prob. 81APCh. 5 - Prob. 82APCh. 5 - Prob. 83APCh. 5 - Prob. 84APCh. 5 - Prob. 85APCh. 5 - Prob. 86APCh. 5 - Prob. 87APCh. 5 - Prob. 88APCh. 5 - Ethanol ( C 2 H 5 OH ) and gasoline (assumed to be...Ch. 5 - Prob. 90APCh. 5 - The heat of vaporization of a liquid ( Δ H vap )...Ch. 5 - Prob. 92APCh. 5 - Prob. 93APCh. 5 - Prob. 94APCh. 5 - Prob. 95APCh. 5 - Prob. 96APCh. 5 - 5.97 The enthalpy of combustion of benzoic add is...Ch. 5 - 5.98 At , the standard enthalpy of formation of...Ch. 5 - From the enthalpy of formation for CO, and the...Ch. 5 - In the nineteenth century, two scientists named...Ch. 5 - Prob. 101APCh. 5 - Prob. 102APCh. 5 - Prob. 103APCh. 5 - A quantity of 85 .0 mL of 0 .600 M HCl is mixed...Ch. 5 - Prob. 105APCh. 5 - Prob. 106APCh. 5 - A 4.117-g impure sample of glucose (C 4 H 12 O 6 )...Ch. 5 - Prob. 108APCh. 5 - In a constant-pressure calorimetry experiment, a...Ch. 5 - Prob. 110APCh. 5 - Give an example for each of the following...Ch. 5 - Prob. 112APCh. 5 - Prob. 113APCh. 5 - 5.114 A 3.52-g sample of ammonium nitrate was...Ch. 5 - 5.115 A quantity of is mixed with in a...Ch. 5 - Prob. 116APCh. 5 - Prob. 117APCh. 5 - Prob. 118APCh. 5 - Prob. 119APCh. 5 - Prob. 120APCh. 5 - 5.121 A gas company in Massachusetts charges 27...Ch. 5 - Prob. 122APCh. 5 - For reactions in condensed phases ( liquids and...Ch. 5 - Prob. 124APCh. 5 - Prob. 125APCh. 5 - The so-called hydrogen economy is based on...Ch. 5 - Prob. 127APCh. 5 - 5.128 Calculate the standard enthalpy change for...Ch. 5 - Prob. 129APCh. 5 - Prob. 130APCh. 5 - Why are cold, damp air and hot, humid air more...Ch. 5 - A woman expends 95 kJ of energy walking a...Ch. 5 - The carbon dioxide exhaled by sailors in a...Ch. 5 - Prob. 134APCh. 5 - Acetylene ( C 2 H 2 ) can be made by combining...Ch. 5 - (a) A person drinks four glasses of cold water ( 3...Ch. 5 - Both glucose and fructose are simple sugars with...Ch. 5 - Prob. 138APCh. 5 - Prob. 139APCh. 5 - Prob. 140APCh. 5 - Prob. 141APCh. 5 - Prob. 142APCh. 5 - 5.143 Hydrazine decomposes to form ammonia and...Ch. 5 - Prob. 144APCh. 5 - Prob. 145APCh. 5 - Prob. 1SEPPCh. 5 - What is the heat capacity ( C v ) of the...Ch. 5 - What is the energy content of the food? a) 22 .8...Ch. 5 - 4. What would be the effect on the result if the...
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- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forward
- Draw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forwardWhat are the IUPAC Names of all the compounds in the picture?arrow_forward
- 1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forward
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