BURDGE CHEMISTRY VALUE ED (LL)
4th Edition
ISBN: 9781259995958
Author: VALUE EDITION
Publisher: MCG CUSTOM
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Question
Chapter 5, Problem 129AP
Interpretation Introduction
Interpretation:
The height that a person can climb with the given energy intake is to be determined.
Concept introduction:
The work done in ascendingis calculated as
Here, m is the mass, g is the gravitational constant, h is the height, and w is the work done.
One kilojoule is equal to 1000 joules.
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1. Consider the following molecular-level diagrams of a titration.
O-HA molecule
-Aion
°°
о
°
(a)
о
(b)
(c)
(d)
a. Which diagram best illustrates the microscopic representation for the
EQUIVALENCE POINT in a titration of a weak acid (HA) with sodium.
hydroxide?
(e)
Answers to the remaining 6 questions will be hand-drawn on paper and submitted as a single
file upload below:
Review of this week's reaction:
H₂NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H₂O --->
H₂NC(=NH)N(CH3)CH2COOH (creatine)
Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing
the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts)
Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts)
Q9. Explain with drawing why the C-N bond shown in creatine structure below can or cannot rotate. (3
pts)
NH2(C=NH)-N(CH)CH2COOH
This bond
Q10. Draw two tautomers of creatine using line structures. (Note: this question is valid because problem
Q9 is valid). (4 pts)
Q11. Mechanism. After seeing and understanding the mechanism of creatine synthesis, students should
be ready to understand the first half of one of the Grignard reactions presented in a past…
Propose a synthesis pathway for the
following transformations. b) c) d)
Chapter 5 Solutions
BURDGE CHEMISTRY VALUE ED (LL)
Ch. 5.1 - Practice Problem ATTEMPT
(a) Calculate the energy...Ch. 5.1 - Practice Problem BUILD
(a) Calculate the velocity...Ch. 5.1 - Prob. 1PPCCh. 5.1 - Prob. 1CPCh. 5.1 - How much greater is the electrostatic potential...Ch. 5.1 - Prob. 3CPCh. 5.1 - 5.1.4 The label on packaged food indicates that it...Ch. 5.1 - 5.1.5 Arrange the following pairs of charged...Ch. 5.1 - Prob. 6CPCh. 5.2 - Practice Problem ATTEMPT
Calculate the change in...
Ch. 5.2 - Practice ProblemBUILD Calculate the magnitude of q...Ch. 5.2 - Prob. 1PPCCh. 5.2 - Calculate the overall change in internal energy...Ch. 5.2 - Calculate w, and determine whether work is done by...Ch. 5.2 - Prob. 3CPCh. 5.2 - Prob. 4CPCh. 5.3 - Prob. 1PPACh. 5.3 - Prob. 1PPBCh. 5.3 - Prob. 1PPCCh. 5.3 - Given the thermochemical equation: H 2 ( g ) + Br...Ch. 5.3 - Given the thermochemical equation: 2Cu 2 O ( s ) →...Ch. 5.4 - Prob. 1PPACh. 5.4 - Prob. 1PPBCh. 5.4 - Prob. 1PPCCh. 5.4 - Prob. 1CPCh. 5.4 - Prob. 2CPCh. 5.4 - Prob. 3CPCh. 5.4 - 5.4.4 Quantities of 50.0 mL of 1.00 M HCl and 50.0...Ch. 5.5 - Prob. 1PPACh. 5.5 - Prob. 1PPBCh. 5.5 - Prob. 1PPCCh. 5.5 - Prob. 1CPCh. 5.5 - Prob. 2CPCh. 5.5 - 5.5.3 Each diagram shows a systems before and...Ch. 5.5 - Prob. 4CPCh. 5.6 - Prob. 1PPACh. 5.6 - Prob. 1PPBCh. 5.6 - Prob. 1PPCCh. 5.6 - Prob. 1CPCh. 5.6 - Prob. 2CPCh. 5.6 - Prob. 3CPCh. 5.6 - Prob. 4CPCh. 5.7 - Prob. 1PPACh. 5.7 - Prob. 1PPBCh. 5.7 - Prob. 1PPCCh. 5.8 - Prob. 1PPACh. 5.8 - Prob. 1PPBCh. 5.8 - Practice ProblemCONCEPTUALIZE The diagrams...Ch. 5.9 - Practice ProblemATTEMPT Use the following data to...Ch. 5.9 - Prob. 1PPBCh. 5.9 - Prob. 1PPCCh. 5 - Using data from Appendix 2, calculate the standard...Ch. 5 - Prob. 2KSPCh. 5 - Prob. 3KSPCh. 5 - Using only whole-number coefficients, the...Ch. 5 - Prob. 1QPCh. 5 - Prob. 2QPCh. 5 - Prob. 3QPCh. 5 - 5.4 A truck initially trawling at 60 km/h is...Ch. 5 - These are various forms of energy: chemical, heat,...Ch. 5 - 5.6 Define these terms: thermochemistry,...Ch. 5 - 5.7 Stoichiometry is based on the law of...Ch. 5 - Prob. 8QPCh. 5 - Decomposition reactions are usually endothermic,...Ch. 5 - Prob. 10QPCh. 5 - Prob. 11QPCh. 5 - Prob. 12QPCh. 5 - Prob. 13QPCh. 5 - Prob. 14QPCh. 5 - Prob. 15QPCh. 5 - Prob. 16QPCh. 5 - Prob. 17QPCh. 5 - Use the following diagrams for Problems 5.17 and...Ch. 5 - Consider these changes. (a) Hg ( t ) → Hg ( g )...Ch. 5 - Prob. 20QPCh. 5 - Prob. 21QPCh. 5 - 5.22 Explain the meaning of this thermochemical...Ch. 5 - Consider this reaction: 2 CH 3 OH ( l ) + 3 O 2 (...Ch. 5 - Prob. 24QPCh. 5 - Prob. 25QPCh. 5 - Prob. 26QPCh. 5 - Prob. 27QPCh. 5 - Prob. 28QPCh. 5 - Prob. 29QPCh. 5 - Prob. 30QPCh. 5 - Prob. 31QPCh. 5 - For most biological processes, the changes in...Ch. 5 - Prob. 33QPCh. 5 - 5.34 Define calorimetry and describe two commonly...Ch. 5 - A 6.22-kg piece of copper metal is heated from 20...Ch. 5 - Prob. 36QPCh. 5 - Prob. 37QPCh. 5 - A 0.1375-g sample of solid magnesium is burned in...Ch. 5 - A quantity of 2 .00 × 10 2 mL of 0 .862 M HCl is...Ch. 5 - 5.40 A 50.75 g sample of water at is added to a...Ch. 5 - A 25.95-g sample of methanol at 35 .6°C is added...Ch. 5 - Prob. 42QPCh. 5 - Prob. 43QPCh. 5 - Consider the following data: Metal Al Cu Mass(g)...Ch. 5 - Prob. 45QPCh. 5 - Prob. 46QPCh. 5 - Prob. 47QPCh. 5 - Prob. 48QPCh. 5 - Prob. 49QPCh. 5 - Prob. 50QPCh. 5 - Prob. 51QPCh. 5 - Prob. 52QPCh. 5 - Prob. 53QPCh. 5 - Prob. 54QPCh. 5 - 5.55 Each diagram shows a system before and after...Ch. 5 - Prob. 56QPCh. 5 - 5.57 Determine the value of for the following...Ch. 5 - Prob. 58QPCh. 5 - Prob. 59QPCh. 5 - Prob. 60QPCh. 5 - Prob. 61QPCh. 5 - Prob. 62QPCh. 5 - Prob. 63QPCh. 5 - Prob. 64QPCh. 5 - Prob. 65QPCh. 5 - Prob. 66QPCh. 5 - Prob. 67QPCh. 5 - Prob. 68QPCh. 5 - Prob. 69QPCh. 5 - Prob. 70QPCh. 5 - Prob. 71QPCh. 5 - Prob. 72QPCh. 5 - Prob. 73QPCh. 5 - Prob. 74QPCh. 5 - Pentaborane - 9 ( B 5 H 9 ) is a colorless, highly...Ch. 5 - Prob. 76QPCh. 5 - Prob. 77QPCh. 5 - Prob. 78QPCh. 5 - Prob. 79QPCh. 5 - Prob. 80QPCh. 5 - Prob. 81APCh. 5 - Prob. 82APCh. 5 - Prob. 83APCh. 5 - Prob. 84APCh. 5 - Prob. 85APCh. 5 - Prob. 86APCh. 5 - Prob. 87APCh. 5 - Prob. 88APCh. 5 - Ethanol ( C 2 H 5 OH ) and gasoline (assumed to be...Ch. 5 - Prob. 90APCh. 5 - The heat of vaporization of a liquid ( Δ H vap )...Ch. 5 - Prob. 92APCh. 5 - Prob. 93APCh. 5 - Prob. 94APCh. 5 - Prob. 95APCh. 5 - Prob. 96APCh. 5 - 5.97 The enthalpy of combustion of benzoic add is...Ch. 5 - 5.98 At , the standard enthalpy of formation of...Ch. 5 - From the enthalpy of formation for CO, and the...Ch. 5 - In the nineteenth century, two scientists named...Ch. 5 - Prob. 101APCh. 5 - Prob. 102APCh. 5 - Prob. 103APCh. 5 - A quantity of 85 .0 mL of 0 .600 M HCl is mixed...Ch. 5 - Prob. 105APCh. 5 - Prob. 106APCh. 5 - A 4.117-g impure sample of glucose (C 4 H 12 O 6 )...Ch. 5 - Prob. 108APCh. 5 - In a constant-pressure calorimetry experiment, a...Ch. 5 - Prob. 110APCh. 5 - Give an example for each of the following...Ch. 5 - Prob. 112APCh. 5 - Prob. 113APCh. 5 - 5.114 A 3.52-g sample of ammonium nitrate was...Ch. 5 - 5.115 A quantity of is mixed with in a...Ch. 5 - Prob. 116APCh. 5 - Prob. 117APCh. 5 - Prob. 118APCh. 5 - Prob. 119APCh. 5 - Prob. 120APCh. 5 - 5.121 A gas company in Massachusetts charges 27...Ch. 5 - Prob. 122APCh. 5 - For reactions in condensed phases ( liquids and...Ch. 5 - Prob. 124APCh. 5 - Prob. 125APCh. 5 - The so-called hydrogen economy is based on...Ch. 5 - Prob. 127APCh. 5 - 5.128 Calculate the standard enthalpy change for...Ch. 5 - Prob. 129APCh. 5 - Prob. 130APCh. 5 - Why are cold, damp air and hot, humid air more...Ch. 5 - A woman expends 95 kJ of energy walking a...Ch. 5 - The carbon dioxide exhaled by sailors in a...Ch. 5 - Prob. 134APCh. 5 - Acetylene ( C 2 H 2 ) can be made by combining...Ch. 5 - (a) A person drinks four glasses of cold water ( 3...Ch. 5 - Both glucose and fructose are simple sugars with...Ch. 5 - Prob. 138APCh. 5 - Prob. 139APCh. 5 - Prob. 140APCh. 5 - Prob. 141APCh. 5 - Prob. 142APCh. 5 - 5.143 Hydrazine decomposes to form ammonia and...Ch. 5 - Prob. 144APCh. 5 - Prob. 145APCh. 5 - Prob. 1SEPPCh. 5 - What is the heat capacity ( C v ) of the...Ch. 5 - What is the energy content of the food? a) 22 .8...Ch. 5 - 4. What would be the effect on the result if the...
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