Biodiesel is formed from the reaction of oils with methanol or ethanol. One of the products is methyl octanoate, C 9 H 18 O 2 , which burns completely in a diesel engine. Give a balanced equation for this reaction. If the density of methyl octanoate is 0.877 g/mL, how many grams of CO 2 will be formed from the burning of 1 gallon of methyl octanoate? Assuming that you drive a diesel-powered car that gets 32 miles per gallon of biodiesel fuel and you drive 14,525 miles per year, what is the carbon footprint of this activity in terms of pounds of CO 2 per year?
Biodiesel is formed from the reaction of oils with methanol or ethanol. One of the products is methyl octanoate, C 9 H 18 O 2 , which burns completely in a diesel engine. Give a balanced equation for this reaction. If the density of methyl octanoate is 0.877 g/mL, how many grams of CO 2 will be formed from the burning of 1 gallon of methyl octanoate? Assuming that you drive a diesel-powered car that gets 32 miles per gallon of biodiesel fuel and you drive 14,525 miles per year, what is the carbon footprint of this activity in terms of pounds of CO 2 per year?
Biodiesel is formed from the reaction of oils with methanol or ethanol. One of the products is methyl octanoate,
C
9
H
18
O
2
, which burns completely in a diesel engine. Give a balanced equation for this reaction. If the density of methyl octanoate is 0.877 g/mL, how many grams of
CO
2
will be formed from the burning of 1 gallon of methyl octanoate? Assuming that you drive a diesel-powered car that gets 32 miles per gallon of biodiesel fuel and you drive 14,525 miles per year, what is the carbon footprint of this activity in terms of pounds of
CO
2
per year?
Q4: Rank the relative nucleophilicity of halide ions in water solution and DMF solution,
respectively.
F CI
Br |
Q5: Determine which of the substrates will and will not react with NaSCH3 in an SN2 reaction to
have a reasonable yield of product.
NH2
Br
Br
Br
OH
Br
Q7: Rank the following groups in order of basicity, nucleophilicity, and leaving group ability.
a) H₂O, OH, CH3COOT
b) NH3, H₂O, H₂S
Q8: Rank the following compounds in order of increasing reactivity in a nucleophilic substitution
reaction with CN as the nucleophile.
Br
A
B
NH2
LL
F
C
D
OH
CI
LLI
E
Q9: Complete the missing entities for following reactions (e.g., major product(s), reactants,
and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for
reactions a) to d).
a)
H
"Cl
D
+
-OCH 3
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